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Reactivity of Mo3PdS4+ 4 Cluster: Evidence for New Ligands PhP(OH)2 and Ph2P(OH) and Structural Characterization of [Mo3(Pd(PPh3))S4(H2O)5Cl4]⋅0.5CH3OH⋅3H2O

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Abstract

Cuboidal cluster aqua complex [Mo3(PdCl)S4(H2O)9]3+ in 4M HCl causes isomerization of (HO)2P(O)(H), (HO)P(O)(H)2, PhP(O)(OH)(H), and Ph2P(O)(H) into hydroxo tautomers P(OH)3, HP(OH)2, PhP(OH)2, and Ph2P(OH) which are stabilized by P coordination to the Pd atom in the cluster. The reactions were followed by 31P NMR and UV/Vis spectroscopy. Hypophosphorous acid H2P(O)(OH) in the presence of the cluster is rapidly oxidized into phosphorous acid; the reaction can be made catalytic. Coordination of PPh3 also takes place, giving [Mo3(Pd(PPh3))S4(H2O)5Cl4]⋅0.5CH3OH⋅3H2O, whose crystal structure was determined.

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References

  1. M. N. Sokolov, A. V. Virovets, D. N. Dybtsev, E. V. Chubarova, V. P. Fedin, and D. Fenske (2001). Inorg. Chem. 40, 4816.

    PubMed  Google Scholar 

  2. M. N. Sokolov, R. Hernandez-Molina, W. Clegg, V. P. Fedin, and A. Mederos (2003). Chem. Comm., 140.

  3. W. Henderson, M. T. Leach, B. K. Nickolson, and M. Sabat (1995). J. Chem. Soc. Dalton Trans., 2109.

  4. J. E. Griffiths and A. B. Burg (1962). J. Am. Chem. Soc. 84, 3442.

    Google Scholar 

  5. T. Murata, Y. Mizobe, H. Gao, Y. Ishii, T. Wakabayashi, F. Nakano, T. Tamase, S. Yano, M. Hidai, Y. Echizen, H. Nanikawa, and S. Motomura (1994). J. Am. Chem. Soc. 116, 3389.

    Google Scholar 

  6. G. M. Sheldrick, SADABS Empirical Absorption Program, (Universität Göttingen, 1996).

  7. G. M. Sheldrick, SHELXTL (Madison, WI, 1997).

  8. K. Herbst, B. Rink, L. Dahlenburg, and M. Brorson (2001). Organometallics 20, 3655.

    Google Scholar 

  9. C. S. Kraihanzel (1974). J. Organomet. Chem. 73, 137.

    Google Scholar 

  10. C. S. Kraihanzel and C. M. Bartisch (1972). J. Am. Chem. Soc. 94, 1972.

    Google Scholar 

  11. H. Vahrenkamp (1972). Chem. Ber. 105, 3574.

    Google Scholar 

  12. H. Nöth, H. Reith, and V. Thorn (1979). Z. Anorg. Allg. Chem. 458, 219.

    Google Scholar 

  13. R. L. Sernaglia and D. W. Franco (1989). Inorg. Chem. 28, 3485.

    Google Scholar 

Download references

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Authors and Affiliations

  1. Russian Academy of Sciences, Institute of Inorganic Chemistry, Novosibirsk, Russia

    Maxim N. Sokolov, Elena V. Chubarova, Alexandr V. Virovets & Vladimir P. Fedin

  2. Department of Experimental Sciences, University Jaume I, Castellon, Spain

    Rosa Llusar

Authors
  1. Maxim N. Sokolov
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  2. Elena V. Chubarova
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  3. Alexandr V. Virovets
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  4. Rosa Llusar
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  5. Vladimir P. Fedin
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Correspondence to Elena V. Chubarova.

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Sokolov, M.N., Chubarova, E.V., Virovets, A.V. et al. Reactivity of Mo3PdS4+ 4 Cluster: Evidence for New Ligands PhP(OH)2 and Ph2P(OH) and Structural Characterization of [Mo3(Pd(PPh3))S4(H2O)5Cl4]⋅0.5CH3OH⋅3H2O. Journal of Cluster Science 14, 227–235 (2003). https://doi.org/10.1023/B:JOCL.0000005060.12513.23

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  • DOI: https://doi.org/10.1023/B:JOCL.0000005060.12513.23

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