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Crystal structure and characterization of [Co(saccharinate)2(L1)(H2O)2] n solvate: A new microporous coordination polymer generated from 1,4-bis(3-pyridyl)-2,3-diaza-1,3-butadiene (L1) and [Co(saccharinate)2·4H2O]·2H2O

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Abstract

A new microporous coordination polymer, [Co(saccharinate)2(L1)(H2O)2] n solvate, has been prepared from the reaction of the N,N′ bidentate ligand 1,4-bis(3-pyridyl)-2,3-diaza-1,3-butadiene (L1) with [Co(saccharinate)2·4H2O]·2H2O in a methylene chloride/ethanol solvent mixture. The compound crystallizes in the triclinic system, space group P-1, with lattice parameters a = 7.6893(5) Å, b = 11.0169(7) Å, c = 11.2369(7) Å, α = 66.2610(10)°, β = 74.4160(10)°, γ = 74.6740(10)°. The structure consists of one-dimensional chains composed of octahedrally coordinated Co(II) centers linked by L1. The packing of these chains, along with intrachain and interchain hydrogen bonds, generates a 3-D framework with infinite channels that are occupied by disordered guest molecules. The compound was further characterized by IR spectroscopy and DTA/TGA.

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Authors and Affiliations

  1. Chemistry Department, Francis Marion University, Florence, South Carolina

    Harvey Davis & LeRoy Peterson Jr.

  2. Department of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina

    Andrea M. Goforth, Mark D. Smith, Paul Zhang & Hans-Conrad zur Loye

Authors
  1. Harvey Davis
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  2. LeRoy Peterson Jr.
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  3. Andrea M. Goforth
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  4. Mark D. Smith
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  5. Paul Zhang
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  6. Hans-Conrad zur Loye
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Correspondence to LeRoy Peterson Jr..

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Davis, H., Peterson, L., Goforth, A.M. et al. Crystal structure and characterization of [Co(saccharinate)2(L1)(H2O)2] n solvate: A new microporous coordination polymer generated from 1,4-bis(3-pyridyl)-2,3-diaza-1,3-butadiene (L1) and [Co(saccharinate)2·4H2O]·2H2O. Journal of Chemical Crystallography 34, 299–306 (2004). https://doi.org/10.1023/B:JOCC.0000026274.31401.7f

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  • DOI: https://doi.org/10.1023/B:JOCC.0000026274.31401.7f

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