Abstract
Arylation of ferrocene with substituted biphenyldiazonium tetrafluoroborates afforded 4-bromo-, 4-nitro-, and 4-cyano-4"-ferrocenylbiphenyls. 4-Nitro- and 4-cyano-4"-ferrocenylbiphenyls were studied by X-ray diffraction analysis. In the crystals of 4-nitro-4"-ferrocenylbiphenyl, the molecules are linked via stacking π-π interactions.
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Lemenovskii, D.A., Makarov, M.V., Dyadchenko, V.P. et al. Syntheses and crystal structures of ferrocenyl derivatives of biphenyl. Russian Chemical Bulletin 52, 607–615 (2003). https://doi.org/10.1023/A:1023998420937
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DOI: https://doi.org/10.1023/A:1023998420937