Abstract
The solubilities of 1-pentene ice in liquid nitrogen at a temperature of 77.4 K and in liquid argon at 87.3 K have been measured by the filtration method. The 1-pentene content in solution was determined using gas chromatography. The experimental value of the mole fraction solubility of 1-pentene ice in liquid nitrogen at 77.4 K is: (1.28±0.25)×10−7 and (4.11±0.44)×10−7 in liquid argon at 87.3 K. The Preston–Prausnitz method was used for calculation of the solubilities of 1-pentene ice in liquid nitrogen in the temperature range 64.0–90.0 K and in liquid argon in the temperature range 84.0–90.0 K. The parameters l 12 were also calculated. At 90.0 K liquid argon is the better solvent for 1-pentene ice than is liquid nitrogen.
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Szczepaniec-Cieciak, E., Krzeczkowska, M. Solubility of 1-Pentene Ice in Liquid Nitrogen and Argon at the Standard Boiling Points of the Solvents. Journal of Solution Chemistry 27, 485–494 (1998). https://doi.org/10.1023/A:1022662020454
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DOI: https://doi.org/10.1023/A:1022662020454