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Role of B″ Ion (B″ = Nb, Ta) on perovskite development, lattice parameters and dielectric properties of (Ba,Pb)(Zn1/3B″2/3)O3 ceramics

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Abstract

Ceramic powders of Pb(Zn1/3B″2/3)O3 (where B″ is Nb or Ta ions) complex-perovskite compositions, with gradual replacements of Pb by Ba, were prepared by using a B-site precursor method. Phases developed in both systems were identified by X-ray diffraction and perovskite contents were evaluated as a function of the amount of Ba substitution. Variations of lattice parameters of the pyrochlore and perovskite structures with composition modifications are interpreted in terms of the 6- and 12-fold cation sizes. Weak-field dielectric properties of the two systems in the low-frequency range are compared.

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  1. Department of Inorganic Materials Engineering, Kyungpook National University, Taegu, 702–701, Korea

    Byung-Yong Ahn & Nam-Kyoung Kim

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  1. Byung-Yong Ahn
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  2. Nam-Kyoung Kim
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Ahn, BY., Kim, NK. Role of B″ Ion (B″ = Nb, Ta) on perovskite development, lattice parameters and dielectric properties of (Ba,Pb)(Zn1/3B″2/3)O3 ceramics. Journal of Materials Science 37, 4697–4701 (2002). https://doi.org/10.1023/A:1020629222680

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