Abstract
Supercritical fluids (SCFs) differ from liquid solvents in a number of important properties, any of which could potentially alter the performance of a chemical reaction performed in a supercritical medium. Although rate, yield and selectivity improvements as well as environmental, health and engineering benefits are all possible, little research has been reported on homogeneously-catalyzed syntheses in SCFs. Several notable successes plus new techniques for solubilizing hydrophilic reagents in SCFs are encouraging further research in this growing field.
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Jessop, P.G. Homogeneously-catalyzed syntheses in supercritical fluids. Topics in Catalysis 5, 95–103 (1998). https://doi.org/10.1023/A:1019189600768
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DOI: https://doi.org/10.1023/A:1019189600768