Abstract
Manganese 2,2'-bipyridine (bpy) complex cations, [Mn(bpy)2]2+, have been immobilized in mesoporous Al-MCM-41 (Si/Al=9) and used as a catalyst for the oxidation of styrene by iodosylbenzene, H2O2 and tert-butyl hydroperoxide (TBHP). The oxidation products included epoxide, diol and aldehyde. Al-MCM-41-immobilized [Mn(bpy)2]2+ exhibited a higher catalytic activity for styrene oxidation than the corresponding homogeneous catalyst and showed no significant loss of catalytic activity when recycled.
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Kim, SS., Zhang, W. & Pinnavaia, T. Catalytic oxidation of styrene by manganese(II) bipyridine complex cations immobilized in mesoporous Al-MCM-41. Catalysis Letters 43, 149–154 (1997). https://doi.org/10.1023/A:1018965900939
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DOI: https://doi.org/10.1023/A:1018965900939