Skip to main content
Log in

Monomeric monooxomolybdenum(VI) complexes of arylazophenolates with one bidentate arylthiol ligand

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

Reaction of an excess of 2-aminobenzenethiol or thiosalicylic acid (H2T) with cis-[MoO2L] (H2L=tridentate 2,2′-dihydroxyarylazo compound) causes elimination of one oxo ligand to give a monomeric monooxomolybdenum(VI) product [MoOL(T)]. These deep red complexes have been characterized by elemental analyses and spectroscopic techniques.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. T. G. Spiro (Ed.), Molybdenum Enzymes, Wiley-Interscience, New York, 1985.

    Google Scholar 

  2. M. P. Coughlan (Ed.), Molybdenum and Molybdenum-Containing Enzymes, Pergamon, Oxford, 1980.

    Google Scholar 

  3. S. P. Cramer, Adv. Inorg. Bioinorg. Mech., 2, 259 (1983).

    CAS  Google Scholar 

  4. S. P. Cramer, L. P. Solomonson, M. W. W. Adams and L. E. Mortenson, J. Am. Chem. Soc., 106, 1467 (1984).

    Article  CAS  Google Scholar 

  5. J. Bordas, R. C. Bray, C. D. Garner, S. Gutteridge and S. S. Hasnain, Biochem. J., 199, 499 (1980); S. P. Cramer, R. Wahl and V. Rajagopalan, J. Am. Chem. Soc., 103, 7721 (1981).

    Article  Google Scholar 

  6. S. Purohit, A. P. Koley and S. Ghosh, Polyhedron, 9, 881 (1990).

    Article  CAS  Google Scholar 

  7. J. K. Gardner, N. Priyadath, J. L. Corbin and E. I. Stiefel, Inorg. Chem., 17, 897 (1978).

    Article  CAS  Google Scholar 

  8. W. E. Newton, G. J. J. Chen, and J. L. McDonald, J. Am. Chem. Soc., 98, 5387 (1976).

    Article  CAS  PubMed  Google Scholar 

  9. S. Mitra, H. Biswas and P. Bandyopadhyay, Polyhedron, 14, 1581 (1995).

    Article  CAS  Google Scholar 

  10. M. E. Bodini and M. A. del-Valle, Polyhedron, 9, 1181 (1990).

    Article  CAS  Google Scholar 

  11. B. Kamenar, B. Korpar-Colig, M. Cindric, M. Penavic and N. Strukan, J. Chem. Soc., Dalton Trans., 2093 (1992).

  12. F. A. Cotton, J. L. Eglin and K. J. Wiesinger, Inorg. Chim. Acta, 195, 11 (1992).

    Article  CAS  Google Scholar 

  13. W. E. Newton, D. C. Bravard and J. W. McDonald, Inorg. Nucl. Chem. Lett., 11, 553 (1975).

    Article  CAS  Google Scholar 

  14. K. Ueno, J. Am. Chem. Soc., 79, 3066 (1957); O. A. Rajan and A. Chakravorty, Inorg. Chem., 20, 660 (1981); O. A. Rajan, Ph.D. Thesis, Indian Institute of Technology, Kanpur, India, 1979; R. N. Mohanty, V. Chakravortty and K. C. Dash, Polyhedron, 10, 33 (1991).

    Article  CAS  Google Scholar 

  15. A. Samotus, A. Kanas, M. Dudek, R. Grybos and E. Hadorowicz, Transition Met. Chem., 16, 495 (1991).

    Article  CAS  Google Scholar 

  16. K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds, Wiley, New York, 1963.

    Google Scholar 

  17. N. B. Colthup, L. H. Daly and S. E. Wiberley, Introduction to Infrared and Raman Spectroscopy, Academic Press, New York, 1964.

    Google Scholar 

  18. M. Chaudhury, Inorg. Chem., 24, 3011 (1985).

    Article  CAS  Google Scholar 

  19. K. Dey, R. K. Maiti and J. K. Bhar, Transition Met. Chem., 6, 346 (1981).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mitra, S., Bandyopadhyay, P. Monomeric monooxomolybdenum(VI) complexes of arylazophenolates with one bidentate arylthiol ligand. Transition Metal Chemistry 22, 270–272 (1997). https://doi.org/10.1023/A:1018468609021

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1018468609021

Keywords

Navigation