Abstract
Silica materials are synthesized by the sol–gel method including the deposition of tetraethoxysilane on various micro- and nanocarbon fibers. The use of nanofibrous carbon as a template makes it possible to prepare thermally stable mesoporous SiO2 samples with unusually high surface areas (up to 1255 m2/g) and high porosity (up to 5.6 cm3/g). These silica materials and aerogels prepared by supercritical drying have comparable pore volumes. It is found by high-resolution electron microscopy that a thin-wall matrix permeated by channels is a prevailing structure of silica materials. When some catalytic fibrous carbons are used as templates, silica nanotubes can be prepared.
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Ermakova, M.A., Ermakov, D.Y. & Kuvshinov, G.G. Morphology and Texture of Silica Prepared by Sol–Gel Synthesis on the Surface of Fibrous Carbon Materials. Kinetics and Catalysis 43, 427–432 (2002). https://doi.org/10.1023/A:1016074321915
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DOI: https://doi.org/10.1023/A:1016074321915