Abstract
The formation of coordination polymeric chain structures in which silver ions alternate with dipyridylethylene (DPyEt) ligands was studied. In a homogeneous ethanol solution, complex formation of DPyEt with silver cations takes place. The outcome of this reaction depends on the ligand/cation molar ratio, the initial ligand concentration, and the counter-ion type. Conditions were identified under which the coordination polymer is formed as a microdispersed solid precipitating from the solution. The precipitates formed in the DPyEt—AgNO3 and DPyEt—AgClO4 systems were investigated by various experimental techniques. The counter-ion was found to be incorporated in the polymer and to influence the structure of the precipitate particles.
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Razumov, V.F., Brichkin, S.B., Pilugina, O.M. et al. Formation of coordination polymeric structures on the basis of 4,4"-dipyridylethylene and Ag+ in solutions. Russian Chemical Bulletin 51, 476–480 (2002). https://doi.org/10.1023/A:1015560302794
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DOI: https://doi.org/10.1023/A:1015560302794