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Crystal structure and spectroscopy of the high-spin compound: Tris-(2,2′-bipyridine-1,1′-dioxide)Iron(III) tris(perchlorate) bis(acetonitrile), [Fe(bpdo)3](ClO4)3(CH3CN)2

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Abstract

The first high-spin iron(III) compound with the ligand 2,2′-bipyridine-1,1′-dioxide (abbreviated as bpdo) is reported. The compound [Fe(bpdo)3](ClO4)3(CH3CN)2 crystallizes in the space group P \(\overline 1\), with a = 11.767(3), b = 13.166(4), c = 15.951(4) Å, α = 104.62(3), β = 101.66(3), γ = 112.14(3)°, and Z = 2. The Fe(III) atom is octahedrally surrounded by six oxygen atoms of three bpdo ligands. In the far-infrared region the Fe—O vibration is observed at 411 cm−1. The magnetic susceptibility reveals a μ of 6.04 ± 0.04 BM in the 10–280 K region, typical of high-spin Fe(III).

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Authors and Affiliations

  1. Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, P.O. Box 9502, 2300 RA, Leiden, The Netherlands

    Gerard A. van Albada & Jan Reedijk

  2. Laboratory of Inorganic Chemistry, Department of Chemistry, University of Helsinki, P.O. Box 55 (A.I.Virtasen aukio 1), 00014, Finland

    Ilpo Mutikainen & Urho Turpeinen

Authors
  1. Gerard A. van Albada
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  2. Ilpo Mutikainen
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  3. Urho Turpeinen
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  4. Jan Reedijk
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van Albada, G.A., Mutikainen, I., Turpeinen, U. et al. Crystal structure and spectroscopy of the high-spin compound: Tris-(2,2′-bipyridine-1,1′-dioxide)Iron(III) tris(perchlorate) bis(acetonitrile), [Fe(bpdo)3](ClO4)3(CH3CN)2. Journal of Chemical Crystallography 31, 75–79 (2001). https://doi.org/10.1023/A:1013786805781

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