Abstract
Superconducting carbides of the rare earth metals and the novel layered carbide halides of these metals, both containing C2 units, present model systems to study the origin of pairwise attraction between conduction electrons in terms of a tendency towards pairwise localization. The superconducting transition temperature scales with the effective charge of the C2 unit as well as with the size of the metal atom cage around C2. From a materials aspect superconductivity and giant magnetoresistance are related as indicated by the new GMR material GdI2 which structurally and in view of chemical bonding parallels the superconducting niobium and tantalum dichalcogenides.
Similar content being viewed by others
REFERENCES
A. Simon, Angew. Chem. Int. Ed. Engl. 36, 1788 (1997).
Hj. Mattausch, A. Simon, C. Felser, and R. Dronskowski, Angew. Chem. Int. Ed. Engl. 35, 1685 (1996).
S. Deng. A. Simon, and J. Köhler, Angew. Chem. Int. Ed. Engl. 37, 640 (1998).
A. Simon, Hj. Mattausch, R. Eger, and R. K. Kremer, Angew. Chem. Int. Ed. Engl. 30, 1188 (1991).
M. Bäcker, A. Simon, R. K. Kremer, Hj. Mattausch, R. Dronskowski, and J. Rouxel, Angew. Chem. Int. Ed. Engl. 35, 752 (1996).
K. Ahn, Hj. Mattausch, and A. Simon, Z. Anorg. Allg. Chem. 624, 175 (1998).
K. Ahn, B. J. Gibson, R. K. Kremer, Hj. Mattausch, A. Stolovits, and A. Simon, J. Phys. Chem. B 103, 5446 (1999).
R. W. Henn, W. Schnelle, R. K. Kremer, and A. Simon, Phys. Rev. Lett. 77, 374 (1996).
E. Herrling, E. Dormann, R. W. Henn, R. K. Kremer, and A. Simon, Synth. Metals 92, 13 (1998).
W. Schnelle, R. W. Henn, Th. Gulden, R. K. Kremer, and A. Simon, J. Appl. Phys. 83, 7321 (1998).
R. W. Henn, T. Strach, R. K. Kremer, and A. Simon, Phys. Rev. B 58, 14364 (1998).
Th. Gulden, R. W. Henn, O. Jepsen, R. K. Kremer, W. Schnelle, A. Simon, and C. Felser, Phys. Rev. B. 56, 9021 (1997).
C. Felser, K. Ahn, R. K. Kremer, R. Seshadri, and A. Simon, J. Solid State Chem. 147, 19 (1999).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Simon, A. Superconductivity and GMR Viewed from Chemistry. Journal of Superconductivity 13, 691–694 (2000). https://doi.org/10.1023/A:1007841510086
Issue Date:
DOI: https://doi.org/10.1023/A:1007841510086