Skip to main content
Log in

Sorption of uranium onto titanosilicate materials

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

The sorption properties of three titanosilicate materials, AM-4, ETS-4, and Na2Ti2O3SiO4 . 2H2O of different framework structure and cation exchange capacity were studied towards the uptake of uranium from aqueous systems. Selectivity factors were estimated by determining batch distribution coefficient (Kd) and uranium removal (mg) per gram of the exchanger as a function of contact time, uranium concentration and batch factor (solution volume to exchanger mass ratio). The difference in their ability to take up uranium was discussed by in terms of their framework structure and the determination of their cation exchange capacity. Comparisons to ETS-10 have been made.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

References

  1. S. Amini,A. Dyer,S. K. Durrani, J. Radioanal. Nucl. Chem., 173 (1993) 331.

    Article  CAS  Google Scholar 

  2. S. Alkyil,M. A. A. Aslani,S. Aytas, J. Alloys Comp., 271/273 (1998) 769.

    Article  Google Scholar 

  3. L. V. C. Rees,C. J. Williams, Trans. Farad. Soc., 61 (1965) 1481.

    Article  CAS  Google Scholar 

  4. L. L. Ames,J. E.McGarrah,B. A. Walker, Clays Clay Miner., 31 (1983) 321.

    Article  CAS  Google Scholar 

  5. N. R. Andreeva,N. B. Chernyavskaya, Radiokhimiya, 24 (1982) 9.

    CAS  Google Scholar 

  6. M. T. Olguin,M. Solache-Rios,M. Asomoza,P. Bosch,S. Bulbulian, in: Extended Abstracts and Program of the 19th Intern. Zeolite Conf., Montreal, Canada, July 1992, RP19.

  7. A. Godelitsas,P. Misaelides,A. Filippidis,D. Charistos,I. Anousis, J. Radioanal. Nucl. Chem., 208 (1996) 393.

    Article  CAS  Google Scholar 

  8. Y. Liu,H. Du,F. Zhou,W. Pang, Chem. Commun., (1997) 1467.

  9. S. Amini,A. Dyer, J. Radioanal. Nucl. Chem., 178 (1994) 273.

    Article  CAS  Google Scholar 

  10. A. Dyer,M. Pillinger, in: Advance in Ion Exchange for Industry and Research, P. A. Williams,A. Dyer (Eds), Royal Society of Chemistry, Cambridge, 1999, p. 261.

    Google Scholar 

  11. A. Dyer, M. Pillinger, S. Amini, Final Report, Contract No. F14W-CT95–0016, EUC.

  12. E. A. Behrens,A. Clearfield, Microporous Mater., 11 (1997) 65.

    Article  CAS  Google Scholar 

  13. V. Valtchev,J. L. Paillaud,S. Mintova,H. Kessler, Micro. Meso. Mater., 32 (1999) 287.

    Article  CAS  Google Scholar 

  14. Z. Lin,J. Rocha,P. Brandao,A. Ferreira,A. P. Esculcas,J. D. P. de Jesus,A. Philippou,M. W. Anderson, J. Phys. Chem. B, 101 (1997) 7114.

    Article  CAS  Google Scholar 

  15. M. S. Dadachov,J. Rocha,A. Ferreira,Z. Lin,M. W. Anderson, Chem. Commun., (1997) 2371.

  16. Xinsheng Liu,J. Kerry Thomas, Chem. Commun., (1996) 1435.

  17. D. M. Poojary,R. A. Cahill,A. Clearfield, Chem. Mater., 6 (1994) 2368.

    Google Scholar 

  18. R. Harjula,A. Dyer,S. D. Pearson,R. P. Townsend, J. Chem. Soc., Faraday Trans., 89 (1993) 1491.

    Google Scholar 

  19. E. A. Behrens,A. Clearfield, Microporous Mater., 11 (1997) 65.

    Article  CAS  Google Scholar 

  20. E. A. Behrens,D. M. Poojary,A. Clearfield, Chem. Mater., 8 (1996) 1236.

    Article  CAS  Google Scholar 

  21. M. W. Anderson,O. Terasaki,T. Ohsuna,A. Phillipou,S. P. McKay,A. Ferreira,J. Rocha,S. Lidin, Nature, 367 (1994) 347.

    Article  CAS  Google Scholar 

  22. M. W. Anderson,J. Rocha,Z. Lin,A. Philippou,I. Orion,A. Ferreira, Microporous Mater., 6 (1996) 195.

    Article  CAS  Google Scholar 

  23. M. W. Anderson,O. Terasaki,T. Ohsuna,P. J. O. Mulley,A. Philippou,S. P. Mackay,A. Ferreira,J. Rocha,S. Lidin, Phil. Mag., B 71 (1995) 813.

    Article  CAS  Google Scholar 

  24. D. M. Chapman,A. L. Roe, Zeolites, 10 (1990) 730.

    Article  CAS  Google Scholar 

  25. A. Philippou,M. W. Anderson, Zeolites, 16 (1996) 98.

    Article  CAS  Google Scholar 

  26. Hongbin Du,Fengqi Zhou,Wenqin Pang,Yong Yue, Microporous Mater., 7 (1996) 73.

    Article  CAS  Google Scholar 

  27. R. N. Sylva,M. R. Davidson, J. Chem. Soc., Dalton, 1979, 465.

  28. M. T. Olguin,M. Solache-Rios,D. Acosta,P. Bosch,S. Bulbulian, Micro. Meso. Mater., 28 (1999) 377.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Al Attar, L., Dyer, A. Sorption of uranium onto titanosilicate materials. Journal of Radioanalytical and Nuclear Chemistry 247, 121–128 (2001). https://doi.org/10.1023/A:1006758929946

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1006758929946

Navigation