Synthesis of self-doped conducting polyaniline bearing phosphonic acid
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Acknowledgments
We thank Dr. T. Suenobu and Prof. S. Fukuzumi at Osaka University for the ESR measurements, Dr. R. Tsuji at Osaka University for the conductivity measurements by the four-point probe method, and Dr. H. Yamamoto and Prof. T. Kozawa at Osaka University for the film thickness measurements. We also thank Comprehensive Analysis Center of the Institute of Scientific and Industrial Research, Osaka University for the ICP-MS measurements and SEM analysis.
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2016, Polymer Degradation and StabilityCitation Excerpt :The substituted derivatives of phosphonic acid, when hydrogen atom is replaced with an organic substituent such as n-decyl [24], tert-butyl [40] or phenyl [41], have been successfully used for the protonation of polyaniline. Self-protonated poly(2-methoxyaniline-5-phosphonic acid) was also synthesized [42–44]. The phosphites are diesters of phosphorous acid (H3PO3) [45].