Effects of cetyltrimethylammonium bromide on the morphology of green synthesized Fe3O4 nanoparticles used to remove phosphate

https://doi.org/10.1016/j.msec.2017.08.073Get rights and content

Highlights

  • Fe3O4 nanoparticles were synthesized by Eucalyptus leaf extract.

  • Cationic surfactant CTAB was used as a stabilizing and capping agent.

  • Fe3O4 nanoparticles size of decreased from 180 to 90 nm.

  • The efficiency in removing phosphate improved from 71% to 93%.

Abstract

In this paper, iron oxide nanoparticles (IONPs) are successfully synthesized using Eucalyptus leaf extract in the presence of cetyltrimethylammonium bromide (CTAB) to enhance the dispersion and reduce aggregation of IONPs. CTAB was used as a stabilizing and capping agent in biosynthesis of IONP was observed. The particle size decreased from 183.9 ± 30.1 nm to 89.8 ± 17.1 nm as the concentration of CTAB increased from 0 to 0.4 mM CTAB, indicating that CTAB reduce the aggregation of IONPs and enhance the reactivity. In addition, the removal efficiency of phosphate declined from 95.13% to 89.58% when the CTAB concentration increased from 0.4 to 10 mM, indicating that a CTAB impacted on micelles and lipophilic biomolecules in Eucalyptus leaf extract, and hence affected the formation of IONPs. Furthermore, SEM image showed that the smaller spherical with some irregularly shaped CTAB-IONPs having a diameter of 80–90 nm in the presence of 0.4 mM CTAB were observed. The date from EDS, FTIR and TGA suggested that the CTAB capped on the surface of CTAB-IONPs, while XRD showed that zero-valent iron and iron oxide were formed. Finally, the formation mechanism of IONPs was proposed.

Keywords

Green synthesis
Iron oxide nanoparticles
Cetyltrimethylammonium bromide
Phosphate removal

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