A new 1-D In–Sb–S chain based on the linkage of bow-like [Sb3S7] units and pseudosemicube [In2SbS4] clusters

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Abstract

The new thioindate–thioantimonate [Co(dien)2]2In2Sb4S11 (1, dien = diethylenetriamine) was prepared under solvothermal conditions and structurally characterized. 1 consists of 1-D inorganic [In2Sb4S114−]n chains constructed by bow-like trimeric [Sb3S7] units and heterometallic pseudosemicube [In2SbS4] clusters, and [Co(dien)2]2+ cations as counterions. The intermolecular H-bond interactions between 1-D inorganic [In2Sb4S114−]n anion and [Co(dien)2]2+ cation result in a 3-D supramolecular network.

Graphical Abstract

One new thioindate-thioantimonate [Co(dien)2]2In2Sb4S11 (1, dien = diethylenetriamine) was prepared under solvothermal conditions. 1-D inorganic [In2Sb4S11 4-]n chain of 1 is constructed by by nontetrahedra InS5 and SbS3 units. The intermolecular H-bond interactions between 1-D inorganic [In2Sb4S11 4-]n anion and [Co(dien)2]2+ cation result in a 3-D supramolecular network. 1 presents the rare example of a thioindate-thioantimonate combined with complex cation.

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Research Highlights

► Although the structures of reported thioindates are constructed by building units involving only both InS4 and other MS4 tetrahedra (M = group 13 (Ga), group 14 (Ge, Sn), and some transition metal elements), relatively little progress has been made on thioindates with other nontetrahedra. ► 1 presents the only example of a thioindate-thioantimonate built of the combination of nontetrahedra SbS3 and [InS5] units with complex cation.

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Acknowledgments

This work was supported by the NNSF of China (Grant 20961011), the NSF of Guangxi Province (Grant 2010GXNSFB013017) and the NSF of the Education Committee of Guangxi Province (201012MS182). The authors are also grateful to Yulin Normal University for financial support.

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