Preparation and structure of an enantiomeric water-bridged dinuclear indium complex containing two homochiral N atoms and its performance as an initiator in polymerization of rac-lactide
Graphical abstract
An enantiomeric water-bridged dinuclear indium complex (1) containing two homochiral N atoms was prepared and structurally characterized. The racemate of 1 is catalytically active for the ring-opening polymerization of rac-LA, giving heterotactic-rich polylactide with narrow polydispersities.
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Acknowledgements
This work was supported by the National Natural Science Foundation of China (Grant no. 20973032), the Program for Changjiang Scholars and Innovative Research Team in University (IRT0711), and the K & A Wallenberg Foundation of Sweden.
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