Short communicationFragmented limestone wastes as a constructed wetland substrate for phosphorus removal
Highlights
► A limestone rock (Moleanos) was verified suitable as a constructed wetland substrate. ► Phosphorous adsorption is well modelled by the Langmuir isotherm. ► The phosphorous removal efficiency of pilot wetland is higher than 60%. ► Wetland efficiency was well predicted by the tanks-in-serial model with N = 2. ► Moleanos limestone can be a promising low cost solution for phosphorous removal.
Introduction
The use of constructed wetlands (CW) for wastewater treatment has become common practice worldwide, including wastewater treatment in small agglomerations, treatment of specific industrial waste material or as a tertiary (advanced) treatment in urban wastewater treatment plants. As for the application of CW as an advanced treatment, the usual aim is to remove nutrients (phosphorus and nitrogen compounds) which are detrimental to the balance of more sensitive receiving media where such effects as euthrophication may occur. The processes of removing nutrients through CW include adsorption by the support matrix (bed filling), precipitation, sedimentation and stabilisation through plant and microbial growth (Kadlec and Wallace, 2008, Vohla et al., 2011, Vymazal, 2007). In the particular case of phosphorus compounds removal, the appropriate choice of filling material is a key factor, since the physical-chemical processes such as phosphate precipitation and adsorption of phosphorus compounds on its surface are pointed out as important phosphorus (P) removal mechanisms. The needs for high capital investment resulting from the cost of the filling material as well as the need for large installation areas have been the major obstacles against the development and use of this environment friendly technology (Guan et al., 2009, Valipour et al., 2009). The most cost-effective materials are usually found among industrial waste and by-products as well as among natural minerals. This investigation is thus pertinent as it involves evaluation of the sorption ability of fragmented Moleanos limestone (FML) and verification of its technical viability as a filling material to be used in constructed wetlands. The Moleanos limestone is used as a decorative material in civil construction, extraction and processing of this rock produce huge amounts of waste materials every year which are used in civil engineering works or deposited in landfills. The use of this material for CW filling, especially if CW are located in the neighbourhoods of extraction or processing sites, constitutes a valuation of debris and an economical advantage for the implementation of CW.
Section snippets
Analytical procedures
Total phosphorus was measured using the persulphate digestion method, and liberated orthophosphates was quantified by the ascorbic acid method (APHA et al., 2005).
Moleanos limestone
Moleanos limestone is a sedimentary mineral aggregate extracted in Moleanos, a limestone area located in central Portugal. The FML used is a waste material resulting from local quarries, mainly composed by CaCO3(Al2O3 [0.23–0.51], CaO [55.58–55.76], Fe2O3 [0.04–0.60], K2O [0.00–0.04], MgO [0.00–0.26], Na2O [0.05–0.07], CO2
P-sorption column tests
A linear form of the Langmuir adsorption isotherm was fitted to experimental data to obtain the adsorption maxima (Wmax) and the half saturation concentrations (1/K), these parameters and the correlation coefficients (r2) are shown in Table 1. The adsorption constants and correlation coefficient obtained from the fitting of Freundlich model to the data are also presented in Table 1. Based on the correlation coefficients experimental data was found to follow the Langmuir model better than the
Conclusions
This study is aimed at demonstrating the feasibility and efficiency of a CW integrating FML as the only substrate for enhanced phosphorus wastewater treatment. From isotherms studies it can be concluded that the capacity of FML as a P adsorbent can be exhausted in a matter of months, and the phosphorus removal due to adsorption should not be the only design goal. However, this material has been successfully used in tertiary treatment pilot scale CW for phosphorus removal during the monitored
Acknowledgements
The authors would like to acknowledge Isabel Silva and Alcino Serras for maintaining the treatment wetlands systems, and also thank Fátima Paiva for the English revision of this manuscript.
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