Synthesis and thermolysis of hexacoordinate 1,2-oxaphosphetanides
The titled compounds synthesized as a mixture of stereoisomers underwent two types of thermal reactions depending on the substituents.
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The chemistry and utility of hexafluoroisobutylene (HFIB) and hexafluoroisobutylene oxide (HFIBO)
2013, Journal of Fluorine ChemistryCitation Excerpt :Naganuma reported a quantitative yield of HFIB by the thermolyses of pentacoordinate 1,2-oxasiletanides [24] (Scheme 13). Similarly, HFIB was isolated in moderate yield by the thermal reaction of a hexacoordinate 1,2-oxaphosphetanide [25] (Scheme 14). The pyrolysis of four-membered cyclic oxyphosphoranes yielded HFIB among other products [26,27] (Scheme 15).
The stereospecific olefin formation reaction of 10-P-5 β-hydroxy- α,β-diphenylethylphosphoranes
1997, Tetrahedron LettersStereochemistry of nucleophilic substitution reactions of sterically rigid phosphoranes
1997, Tetrahedron LettersSynthesis, Structure and Reactivities of Pentacoordinated Phosphorus–Boron Bonded Compounds
2020, European Journal of Inorganic Chemistry
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