H-abstraction prevails over α-cleavage in the solution and solid state photochemistry of cis-2,6-di(1-cyclohexenyl)cyclohexanone☆
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Acknowledgements
This work was supported by the NSF through grants CHE0242270 and CHE0116853 (Grant for the 600 MHz NMR). Graduate support to L.M.C. by the NSF and the Paul and Daisy Soros Fellowship for new Americans are also gratefully acknowledged.
References (22)
Chem. Rev.
(1976)- et al.
J. Am. Chem. Soc.
(1975) Org. Photochem.
(1981)- et al.
J. Org. Chem.
(2002) - et al.
J. Chem. Soc., Perkin Trans. 2
(1999) - et al.
J. Am. Chem. Soc.
(1995)et al.J. Am. Chem. Soc.
(1996) - et al.
J. Am. Chem. Soc.
(1998) - et al.
J. Org. Chem.
(2001)et al.Org. Lett.
(2000) - Ellison, M. E., M.S. Thesis, University of California, Los Angeles,...
- et al.
Tetrahedron Lett.
(2002)
J. Org. Chem.
(1998)
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Supplementary data associated with this article can be found at doi:10.1016/S0040-4039(03)01450-3
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