Carboxonium-ionen-reaktionen V. synthese von 1,3-oxathiolen und deren fragmentierung zu β-thia-γ,δ-enonen

doi:10.1016/S0040-4039(00)97528-2

Tetrahedron Letters

Volume 23, Issue 1, 1982, Pages 47-50

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Abstract

1,3-Oxathioles 5 are formed in high yields upon treatment of 5-chloromethyl-1,3-oxathiolanes 3 with potassium t-butoxide in dimethyl sulfoxide at room temperature. The protoncatalyzed fragmentation of 5 leads in good yields to the new β-thia-γ,δ-enones 6.

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Tetrahedron Letters

Carboxonium-ionen-reaktionen V. synthese von 1,3-oxathiolen und deren fragmentierung zu β-thia-γ,δ-enonen

Abstract

Liebigs Ann. Chem.

Chem. Ber.

Chem. Ber.

J. Heterocycl. Chem.

J. Org. Chem.

J. Chem. Soc. Perkin Trans. I

Tetrahedron Lett.

J. Am. Chem. Soc.