IX. Metal surfaces III: Adsorption of complex moleculesAdsorption of nitrobenzene and some simple derivatives on the Cu(110) surface
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Fabrication of palladium-copper nanoparticles with controllable size and chemical composition
2018, Journal of Colloid and Interface ScienceCitation Excerpt :As determined by XPS analysis, the surface Pd/Cu atomic ratio increased up to 84/16, which means that the Pd80Cu20 nanoparticles possessed the highest number of surface Pd that facilitated the adsorption and activation of hydrogen molecule, which is essential to achieve an excellent activity and selectivity for hydrogenation of nitrobenzene [34–36]. Meanwhile, the surface copper atoms promoted the adsorption of nitrobenzene perhaps through the formation of charge-transfer complexes [37,38], resulting in a syngeneic manner for the hydrogenation reaction. This is further supported by the catalytic performance of the pure Pd100 nanoparticles, which only gave a nitrobenzene conversion of 67% and an aniline selectivity of 80% under identical conditions.
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