Preliminary communication
Dimethylsulfoxoniummethylid als ligand in metallcarbonylkomplexen

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Abstract

From the reaction of (THF)M(CO)5 (M = Cr, Mo, W) with (CH3)2S(=O)CH2 in THF one obtains yellow complexes of the composition (CH3)2S(=O)CH2M(CO)5. Their chemical and spectroscopic properties are described.

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