Preliminary noteElectrocatalytic reduction of molecular oxygen using non-planar cobalt tetrakis-(4-sulfonatophenyl)-β-octabromoporphyrin
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The effect of polypyrrole-bound anthraquinonedisulphonate dianion on cathodic reduction of oxygen
2007, Reactive and Functional PolymersCyclohexane hydroxylation by iodosylbenzene and iodobenzene diacetate catalyzed by a new β-octahalogenated Mn-porphyrin complex: The effect of meso-3-pyridyl substituents
2007, Journal of Molecular Catalysis A: ChemicalCitation Excerpt :These observed anodic shifts following β-bromination could be ascribed to effects of the bulky and electron-withdrawing bromine substituents in the β-pyrrole positions of the porphyrin ring. In fact, several electrochemical studies have reported that the type and number of β-halogen atoms in a porphyrin ligand as well as the nature of the metal center crucially affect the redox behavior of these systems [21–24,26,46,47,51,53,55,57,58,111,126–131]. The hydroxylation of cyclohexane by PhIO or PhI(OAc)2 was carried out at room temperature, using Mn(III)T3PyPCl or Mn(II)Br8T3PyP as catalysts.
Partially and fully β-brominated Mn-porphyrins in P450 biomimetic systems: Effects of the degree of bromination on electrochemical and catalytic properties
2005, Journal of Inorganic BiochemistryApplication of multi-walled carbon nanotubes functionalized with hemin for oxygen detection in neutral solution
2004, Journal of Electroanalytical ChemistryReduction catalysis by metal complexes confined in a polymer matrix
2003, Progress in Polymer Science (Oxford)
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