Modification of the photochemical behaviour of organic molecules by cyclodextrin: Geometric isomerization of stilbenes and alkyl cinnamates
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2008, Chemical Physics LettersCitation Excerpt :The fact that the fluorescence decays become single-exponential at 9 mM α-CD, which is a concentration at which 1:2 complexes predominate (Fig. 3), indicates a total suppression of photoisomerization in the very rigid microenvironment provided by these complexes. It may be noted that such differences in the effect of α- and β-cyclodextrins on photoisomerization processed have been reported for other compounds [11–15]. Various explanations have been offered for such behavior.
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