Regular paperA kinetic study of the oxidation of L-ascorbic acid (vitamin C) in solution using an isothermal microcalorimeter
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2020, LWTCitation Excerpt :For instance, Hansen et al. (1990, 1989) showed that the shelf-life of Lovastatin formulations could be easily assessed from the heat-flow values recorded during the induction period of its autocatalytic decomposition (Hansen et al., 1990; Hansen, Lewis, Eatough, Bergstrom, & DeGraft-Johnson, 1989). Further studies have shown that isothermal calorimetry can be used as a relatively rapid method to determine the degradation kinetics of pharmaceutical actives such as paraben (Skaria et al., 2005), food antioxidants such as ascorbic acid (Willson, Beezer, & Mitchell, 1996; Wilson, Beezer, & Mitchell, 1995) or DL-a-tocopherol (Otsuka, Yoshioka, Aso, & Terao, 1994), with or without the presence of excipients (Murti Vemuri, Chrzan, & Cavatur, 2004; Schmitt, Peck, Sun, & Geoffroy, 2001; Selzer, Radau, & Kreuter, 1998). Such an approach has also been applied to study the degradation kinetics of vitamin A. Isothermal calorimetry was utilized to study the stability of solid formulations of retinoic acids in the presence or absence of oxygen (Tan, Meltzer, & Lindenbaum, 1992).