A novel intramolecular decarboxylative glycosylation via mixed carbonate

doi:10.1016/0040-4039(96)00272-9

Tetrahedron Letters

Volume 37, Issue 13, 25 March 1996, Pages 2267-2270

https://doi.org/10.1016/0040-4039(96)00272-9 Get rights and content

Abstract

A two-step glycosylation procedure, which involves (1) linking two sugars by using carbonate as a connector, (2) removing carbon dioxide to form a glycosidic bond by the aid of Lewis acid, has been developed. This glycosylation procedure was based on the opposite mode of connection, where a glycosyl acceptor was activated to link sugars.

An intramolecular glycosidic bond formation was achieved by removing internal carbon dioxide from mixed carbonate by the aid of Lewis acid.

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A novel intramolecular decarboxylative glycosylation via mixed carbonate

Abstract

Tetrahedron Lett.

Angew. Chem., Int. Ed. Engl.

Chem. Rev.

Angew. Chem., Int. Ed. Engl.

Angew. Chem., Int. Ed. Engl.

Chem. Ber.

J. Org. Chem.