Synthesis of Δ7-1-methylbicyclo[5,4,0]undecene-2,9-dione and its condensation with acetylene
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2020, Tetrahedron LettersCitation Excerpt :Wieland-Miescher ketone 1a and its methyl analog 1b are useful synthons for the syntheses of pharmacologically important natural products, especially those possessing a decalin skeleton [1–3]. However, there has been little development toward the construction of new ring systems containing a 7-membered or larger carbocycle [4]. Pioneering studies aimed at the synthesis of 2a were carried out by Swaminathan and co-workers [4a,c].
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