Rotational structure of 16O2, 16O17O, and 16O18O (X3Σg−) from laser magnetic resonance spectra

doi:10.1016/0022-2852(84)90017-1

Journal of Molecular Spectroscopy

Volume 107, Issue 2, October 1984, Pages 395-404

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Abstract

Improved values of the rotational constants B and D of ¹⁶O¹⁷O(v = 0) and D of ¹⁶O₂(v = 1) were obtained from an analysis of the laser magnetic resonance spectra at 765 and 4252 GHz.

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Detection of cloud parameters from space-based spectrometers can employ the vibrational bands of O₂ in the b¹∑_g⁺ ← X³∑_g⁻ spin-forbidden electronic transition manifold, particularly the Δ_v = 0 A band. The European Space Agency's Global Ozone Monitoring Experiment (GOME), on board the European Remote Sensing 2 satellite, uses the A band in the Initial Cloud Fitting Algorithm (ICFA). The work reported here consists of making substantial improvements in the line-by-line spectral database for the A band, testing whether an additional correction to the line shape function is necessary in order to model correctly the atmospheric transmission in this band, and calculating prototype cloud and ground template spectra for comparison with satellite measurements.
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Journal of Molecular Spectroscopy

Abstract

References (11)

Chem. Phys. Lett.

J. Mol. Spectrosc.

Phys. Rev. Lett.

Phys. Rev. Lett.

Phys. Rev. A

Cited by (5)

Terahertz spectroscopy of oxygen, O<inf>2</inf>, in its <sup>3</sup>Σ<sup>-</sup><inf>g</inf> and <sup>1</sup>Δ electronic states THz Spectroscopy of O<inf>2</inf>

Improvement of the O<inf>2</inf> a band spectroscopic database for satellite-based cloud detection

[Formula Presented] (0,0) band of oxygen isotopomers in relation to tests of the symmetrization postulate in [Formula Presented]

On the use of O<inf>2</inf> spin-rotation lines for elevation angle calibration of atmospheric thermal emission spectra

Electron spin resonance of the oxygen molecule in blood