Synthesis of silyloxides of gadolinium and erbium

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Abstract

Lanthanon compounds containing MOSi bonds have been prepared by the reactions between lanthanon isopropoxides and trimethylsilylacetate in different molar ratios in refluxing cyclohexane (MGd or Er). The mono- or di-isopropoxy silyloxides interchange their isopropoxy groups with tertiary butoxy groups on alcoholysis. Molecular weights and i.r. spectra studies indicate that they are polymeric.

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