2. Titanium

doi:10.1016/0010-8545(82)85019-4

Coordination Chemistry Reviews

Volume 45, September 1982, Pages 9-40

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A novel class of hexanuclear titanoxanes: synthesis, structure and electronic configuration
1995, Journal of Organometallic Chemistry
Reduction of cyclopentadienyloxochloro complexes such as [R-cpTiCl(μ₂-O)]₄ (R = H (bd1), Me (bd2) or SiMe₃ (bd3))) with a variety of reducing agents (Zn, Na, Mg or LiN₃) in tetrahydroforum gave the hexanuclear titanoxanes [(R-cp)₆Ti₆O₆Cl₂] (RH (bd4), Me (5) or SiMe₃ (6)) with a good yield. Complexes 4–6 are soluble in organic solvents, are diamagnetic and contain four electrons more than are required for the existence of the hexanuclear skeleton. Complex 4 was equally satisfactorily obtained by reducing R-cpTiCl₂(μ₂-O)] (RH) (7) will Bu₃SnH. Reduction of 1 and 2 with Al powder gave $[R-cp_{6} Ti_{6} O_{4} Cl_{4}] (R  H (8) or Me (9))$ . They contain two unpaired electrons. Reaction of H₂O with 4 and 5 gave the diamagnetic titanoxane [R-cp₆Ti₆ or Me (12)). Complexes 4–6, 8, 9, 11 and 12 all contain an octahedron of titanium atoms faced bridging oxygen and chlorine in the reported ration. Molecular orbital calculations showed that a band of 12 non-bonding orbitals may accomodate electrons in excess of those needed for the existence of the Ti₆ skeleton and so the systems can be used in their intact form for storing and releasing electrons. The structures of complexes 4, 6, 9, and 12 were determined by single-crystal X-ray diffraction studies.
6. Titanium
1986, Coordination Chemistry Reviews
Synthesis and characterization of oxo zirconium (IV) complexes of polydentate ligands
2021, AIP Conference Proceedings
The reactions of TiCl<inf>3</inf>, and of UF<inf>4</inf> with TiCl<inf>3</inf> in liquid ammonia: Unusual coordination spheres in [Ti(NH<inf>3</inf>)<inf>8</inf>]Cl<inf>3</inf>·6NH<inf>3</inf> and [UF(NH<inf>3</inf>)<inf>8</inf>]Cl<inf>3</inf>·3.5NH<inf>3</inf>
2015, Chemical Communications

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2. Titanium

First page preview

J. Organomet. Chem.

J. Organomet. Chem.

J. Organomet. Chem.

J. Organomet. Chem.

Coord. Chem. Rev.

Survey Progr. Chem.

J. Inorg. Nucl. Chem.

J. Inorg. Nucl. Chem.

Inorg. Chim. Acta

Carbon

J. Less-Common Met.

Spectrochim. Acta Part A

J. Mol. Struct.

J. Mol. Struct.

J. Magn. Reson.

J. Organomet. Chem.

J. Organomet. Chem.

J. Organomet. Chem.

J. Less-Common Met.

Inorg. Chim. Acta

J. Organomet. Chem.

J. Inorg. Nucl. Chem.

Inorg. Chim. Acta

Inorg. Chim. Acta

Inorg. Chim. Acta

J. Inorg. Nucl. Chem.

Thermochim. Acta

J. Organomet. Chem.

J. Solid State Chem.

J. Solid State Chem.

J. Solid State Chem.

J. Less-Common Met.

J. Solid State Chem.

J. Solid State Chem.

J. Solid State Chem.

J. Solid State Chem.

J. Chem. Educ.

Z. Anorg. Allg. Chem.

Acta Crystallogr., Sect. B

Can. J. Chem.

Indian J. Chem. Sect. A

Z. Anorg. Allg. Chem.

Inorg. Chem.

Indian J. Chem. Sect. A

J. Gen. Chem. USSR

Russ. J. Phys. Chem.

Z. Anorg. Allg. Chem.

Indian J. Chem. Sect. A

Chem. Ind. (London)