Abstract
The study aims to use asphaltene particles (As) extracted from natural bitumen to synthesize activated carbon (ACAs). The asphaltene particles were mixed with a fixed weight of potassium hydroxide (KOH) as an activating agent, preheated to 600 °C, and then treated with 15% hydrofluoric acid (HF). The methylene blue (MB) 20 mg/l was used to determine the adsorption capacity of ACAs and reactivated carbon (RACAs). The morphology of ACAs and its components were characterized using scanning electron microscopy–energy dispersive X-ray (SEM–EDX) and Fourier-transform infrared spectroscopy (FTIR). The study included the application of adsorption isotherms Freundlich and Langmuir on the experimental data of the studied systems. The yield of ACAs was 92% of the raw material. The activated carbon displayed high adsorption capacity and can be reprocessed after reactivation using microwave radiation. The active surface area of ACAs is found to be 970 m2/g. The effectiveness and adsorption ability of ACAs and RACAs, as proven by its adsorption capacity (218.15 and 217.907 mg/g) for MB, demonstrate that ACAs and RACAs have a large external surface area and an extensive array of pores. The ACAs are most sensitive at 30 °C and neutral pH. The results also showed that the isotherms have a good fit to the experimented data.
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Bhuvan S, Govinda P (2018) The threat of ambient air pollution in Kathmandu, Nepal. J Environ Public Health. https://doi.org/10.1155/2018/1504591(Article ID 1504591)
Kumar A, Mohan HJ (2016) Preparation and characterization of high surface area activated carbon from Fox nut (Euryale ferox) shell by chemical activation with H3PO4. Results Phys 6:651
Ying L, Xiaohui L, Wenping D et al (2017) Efficient adsorption of sulfamethazine onto modified activated carbon: a plausible adsorption mechanism. Sci Rep 7:12437
Kim Y, Kim JH, Lee KG, Kang SG (2005) Adsorption behavior of heavy metal ions in the solution of clay minerals under various conditions. J Ceram Process Res 6:25
Simone C, Marco C (2018) Modeling the adsorption equilibrium of small-molecule gases on graphene: effect of the volume to surface ratio. Phys Chem Chem Phys 20:9770
Dąbrowski A (2001) Adsorption—from theory to practice. Adv Coll Interface Sci 93:135
Sara D, Tushar S (2014) Review on dye removal from its aqueous solution into alternative cost effective and non-conventional adsorbents. J Chem Process Eng 1:1–11
George T, Simona M, Katerina S, Peter T, Tony S (2016) Mechanochemical and chemical activation of lignocellulosic material to prepare powdered activated carbons for adsorption applications. Powder Technol 299:41
Ali HJ, Ramlah AR, Mohd AM, Lee DW (2016) Adsorption of methylene blue onto activated carbon developed from biomass waste by H2SO4 activation: kinetic, equilibrium and thermodynamic studies. Desalin Water Treat 57:1
Guliyev NG, Ibrahimov HJ, Alekperov JA et al (2018) Investigation of activated carbon obtained from the liquid products of pyrolysis in sunflower oil bleaching process. Int J Ind Chem 9:277. https://doi.org/10.1007/s40090-018-0156-1
Hai NT, You SJ, Huan-Ping C (2017) Fast and efficient adsorption of methylene green 5 on activated carbon prepared from new chemical activation method. J Environ Manag 188:322
Dı´az-Tera´n J, Nevskaia DM, Lo´pez-Peinado AJ (2001) Porosity and absorption properties of an activated charcoal. Colloids Surface A Physiochem Eng Aspects 187:167
Fu K, Yue Q, Gao B et al (2017) Activated carbon from tomato stem by chemical activation with FeCl2. Colloids Surf A 529:842
Teng HS, Yeh TS, Hsu LY (1998) Preparation of activated carbon from bituminous coal with phosphoric acid activation. J Carbon 36:1387
Munther IK, Reyad S, Mahmoud A (2006) Synthesis and characterization of activated carbon from asphalt. Appl Surf Sci 253:821
Muwafaq AR, Rasim FM, Atyaf AY (2017) Preparation activated carbon from Biji refinery asphalt treated with sulfur and waste polymers. Int J Appl Eng Res 12:14783
Rasim FM, Muwafaq AR, Thsin AZ (2019) Properties improvement of activated carbon prepared from Hit natural asphalt by phenol formaldehyde polymer waste. Res J Pharm Technol 12(6):2955–2958
Simon IA, James GS (2001) Petroleum resins: separation, character, and role in petroleum. Pet Sci Technol 19:1–2. https://doi.org/10.1081/LFT-100001223
James GS (2004) Petroleum asphaltenes—part 1: asphaltenes, resins and the structure of petroleum. Oil Gas Sci Technol 59:467
Zhen B, Ali Q, Atena S et al (2018) Asphaltene deposition during bitumen extraction with natural gas condensate and naphtha. Energy Fuels 32:1433
Hesas RH, Arami-Niya et al (2013) Preparation and characterization of activated carbon from apple waste by microwave –assisted phosphoric acid activation: application methylene blue adsorption. Bio Resour 8:2950
Al-Hyali OM, Ramadhan SA (2005) Effect of substantiates types on the adsorption of aromatic carboxylic acid and their relation to concentration, temperature and pH. Raf J Sci 16:68
Marsh H, Rodriguez-Reinoso F (2006) Activated carbon, 1st edn. Elsevier Science and Technology Books, New York, p 27 (183-186, 243-251)
Kim JH, Hwang SY, Park JE et al (2019) Impact of the oxygen functional group of nitric acid-treated activated carbon on KOH activation reaction. Carbon Lett 29:281. https://doi.org/10.1007/s42823-019-00024-0
Steenberg B (1944) Adsorption and Exchange of Ions by Activated Charcoal. Uppsala, Almquist and Wiksells, Stockholm
Mistry B (2009) Handbook of spectroscopic data CHEMISTRY (UV, JR, PMR, JJCNMR and Mass Spectroscopy). Oxford Book Company, Oxford, pp 26–56
Lee SM, Bae BS, Park HW et al (2015) Characterization of Korean Red Ginseng (Panax ginseng Meyer): History, preparation method, and chemical composition. J Ginseng Res 39:384
Robert S, Francis W, David K (2005) Spectrometric identification of organic compounds, 7th edn. Wiley, Hoboken, pp 72–126
Kazuo N (2009) Infrared and raman spectra of inorganic and coordination compounds part A: theory and applications in inorganic chemistry, 6th edn. Wiley, Hoboken
Sev S, Field L, John K (2008) Organic structures from spectra, 4th edn. Wiley, Hoboken, pp 15–20
Obaid A, Hiba T, Rasim FM (2017) Synthesis and characterization of novel 1,3-oxazepine-5(1H)-one derivatives via reaction of imine compounds with isobenzofuran-1(3H)-one. Acta Pharm Sci 55:43
Rasim FM, Hiba T, Mustafa O, Obaid A (2018) Synthesis, characterization and evaluation of antifungal activity of seven-membered heterocycles. Acta Pharm Sci 56:39
Simek J (2013) Organic chemistry, 8th edn. Pearson education, Inc, London, pp 412–414
Kent SK (2003) Adsorbent selection, Adsorption research. Inc. Dubiln, ohio 43016:1–23
Freundlich H (1906) Uber die adsorption Isoungen. Z Phys Chem 57:385
Radushkevich LV (1974) Potential theory of sorption and structure of carbons. Zh Fiz Khim 23:1410
Wang Q, Fu F (2011) Removal of heavy metal ions from wastewaters: a revlew. J Environ Manag 92:407
Bulut Y, Gozubenli N, Aydm H (2007) Equilibrium and kinetics studies of adsorption of direct blue 71 from aqueous solution by wheat shells. J Hazard Mater 144:303
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Rabeea, M.A., Zaidan, T.A., Ayfan, A.H. et al. High porosity activated carbon synthesis using asphaltene particles. Carbon Lett. 30, 199–205 (2020). https://doi.org/10.1007/s42823-019-00086-0
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DOI: https://doi.org/10.1007/s42823-019-00086-0