Skip to main content
SpringerLink
Log in

A Review on 1,2,4-Triazole Derivatives as Corrosion Inhibitors

  • Published:
Journal of Bio- and Tribo-Corrosion Aims and scope Submit manuscript

Abstract

Numerous organic inhibitors have been reported for the corrosion inhibition of various metals. It is found that the synthetic heterocyclic compounds containing atoms with high electronegativity like nitrogen, sulphur, oxygen or phosphorous are very effective in preventing the corrosion of metals. In recent years, a trend is developed for analysing the compounds containing 1,2,4-triazole moiety for the corrosion inhibition of metals, as triazole nucleus containing three nitrogen atoms in a single ring. In this article, it is aimed to review the usefulness of 1,2,4-triazole derivatives for the corrosion inhibition of different metals and alloys in acid/base medium.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Sharma J, Ahmad S, Alam MS (2012) Bioactive triazoles: a potential review. J Chem Pharm Res 4:5157–5164

    Google Scholar 

  2. Peyton LR, Gallagher S, Hashemzadeh M (2015) Triazole antifungals: a review. Drugs Today (Barc) 51:705–718

    Google Scholar 

  3. Fox PG, Bradley PA (1980) 1: 2: 4-triazole as a corrosion inhibitor for copper. Corros Sci 20:643–649

    Article  Google Scholar 

  4. Jiang L, Lan Y, He Y, Li Y, Li Y, Luo J (2014) 1,2,4-Triazole as a corrosion inhibitor in copper chemical mechanical polishing. Thin Solid Films 556:395–404

    Article  Google Scholar 

  5. Lesar A, Milošev I (2009) Density functional study of the corrosion inhibition properties of 1,2,4-triazole and its amino derivatives. Chem Phys Lett 483:198–203

    Article  Google Scholar 

  6. Ramesh S, Rajeswari S, Maruthamuthu S (2004) Corrosion inhibition of copper by new triazole phosphonate derivatives. Appl Surf Sci 229:214–225

    Article  Google Scholar 

  7. Yu J, Jiang L, Gan F (2010) Inhibition of copper corrosion in deionized water by 3-amino-5-mercapto-1,2,4-triazole. J Chin Soc Corros Prot 30:21–24

    Google Scholar 

  8. Yu J, Gan F, Jiang L (2008) Inhibition effect of 3-amino-5-mercapto-1,2,4-triazole on copper corrosion. Corrosion 64:900–904

    Article  Google Scholar 

  9. Walker R (1975) Triazole, benzotriazole and naphthotriazole as corrosion inhibitors for copper. Corrosion 31:97–100

    Article  Google Scholar 

  10. Soumoue A, El Ibrahimi B, El Issami S, Bazzi L (2014) Some triazolic compounds as corrosion inhibitors for copper in sulphuric acid. Int J Sci Res 3:349–354

    Google Scholar 

  11. Tang YM, Chen Y, Yang WZ, Yin XS, Wang JT (2010) 3,5-Bis(2-thienyl)-4-amino-1,2,4-triazole as a corrosion inhibitor for copper in acidic media. Anti-Corros Methods Mater 57:227–233

    Article  Google Scholar 

  12. Chen Y, Tang Y, Yang W, Liu Y, Wang J (2009) Inhibition of 3,5-bis(2-thienyl)-4-amino-1,2,4-triazole on copper in HCl media. Corros Sci Prot Technol 21:406–409

    Google Scholar 

  13. Zarrouk A, Hammouti B, Al-Deyab SS, Salghi R, Zarrok H, Jama C, Bentiss F (2012) Corrosion inhibition performance of 3,5-diamino-1,2,4-triazole for protection of copper in nitric acid solution. Int J Electrochem Sci 7:5997–6011

    Google Scholar 

  14. Lalitha A, Ramesh S, Rajeswari S (2005) Surface protection of carbon steel by hexanesulphonic acid-zinc ion system. Electrochim Acta 51:47–55

    Article  Google Scholar 

  15. Hassan HH, Abdelghani E, Amin MA (2007) Inhibition of mild steel corrosion in hydrochloric acid solution by triazole derivatives -Part I. Electrochim Acta 52:6359–6364

    Article  Google Scholar 

  16. Awad MK, Mustafa MR, Elnga MMA (2010) Computational simulation of the molecular structure of some triazoles as inhibitors for the corrosion of metal surface. J Mol Struct (Thoechem) 959:66–74

    Article  Google Scholar 

  17. Sherif ESM, Erasmus RM, Comins JD (2007) Effects of 3-amino-1,2,4-triazole on the inhibition of copper corrosion in acidic chloride solutions. J Colloid Interface Sci 311:144–151

    Article  Google Scholar 

  18. Sherif ESM, Erasmus RM, Comins JD (2007) Corrosion of copper in aerated acidic pickling solutions and its inhibition by 3-amino-1,2,4-triazole-5-thiol. J Colloid Interface Sci 306:96–104

    Article  Google Scholar 

  19. Sudheer Quraishi MA (2013) Electrochemical and theoretical investigation of triazole derivatives on corrosion inhibition behavior of copper in hydrochloric acid medium. Corros Sci 70:161–169

    Article  Google Scholar 

  20. Demissie EG, Kassa SB, Woyessa GW (2014) Quantum chemical study on corrosion inhibition efficiency of 4-amino-5-mercapto-1,2,4-triazole derivatives for copper in HCl solution. Int J Sci Eng Res 5:304–312

    Google Scholar 

  21. El-Shayeb A, El-Warraky HA, Sherif EM (2004) Pitting corrosion of copper in chloride solution. Anti-Corros Methods Mater 51:52–61

    Article  Google Scholar 

  22. Sherif ESM, El Shamy AM, Ramla MM, El Nazhawy AOH (2007) 5-(Phenyl)-4H-1,2,4-triazole-3-thiol as a corrosion inhibitor for copper in 3.5% NaCl solutions. Mater Chem Phys 102:231–239

    Article  Google Scholar 

  23. Sherif ESM, Erasmus RM, Comins JD (2007) Corrosion of copper in aerated synthetic sea water solutions and its inhibition by 3-amino-1,2,4-triazole. J Colloid Interface Sci 309:470–477

    Article  Google Scholar 

  24. Xu QJ, Li CX, Zhou GD, Zhu LJ, Lin CJ (2009) Copper corrosion inhibition and adsorption behavior of 3-amino-1,2,4-triazole. Acta Phys Chim Sin 225:86–90

    Google Scholar 

  25. Khiati Z, Othman AA, Sanchez-Moreno M, Bernard MC, Joiret S, Sutter EMM, Vivier V (2011) Corrosion inhibition of copper in neutral chloride media by a novel derivative of 1,2,4-triazole. Corros Sci 53:3092–3099

    Article  Google Scholar 

  26. Al Maofari A, Ezznaydy G, Idouli Y, Guédira F, Zaydoun S, Labjar N, Hajjaji SE (2014) Inhibitive action of 3,4′-bi-1,2,4-triazole on the corrosion of copper in NaCl 3% solution. J Mater Environ Sci 5:2081–2085

    Google Scholar 

  27. Chieb T, Belmokre K, Benmessaoud M, Drissi SEH, Hajjaji N, Srhiri A (2011) The inhibitive effect of 3-methyl 4-amino 1,2,4 triazole on the corrosion of copper-nickel 70–30 in NaCl 3% solution. Mater Sci Appl 2:1260–1267

    Google Scholar 

  28. Rahmouni K, Hajjaji N, Keddam M, Srhiri A, Takenouti H (2007) The inhibiting effect of 3-methyl 1,2,4-triazole 5-thione on corrosion of copper in 3% NaCl in presence of sulphide. Electrochim Acta 52:7519–7528

    Article  Google Scholar 

  29. Allam NK (2007) Thermodynamic and quantum chemistry characterization of the adsorption of triazole derivatives during Muntz corrosion in acidic and neutral solutions. Appl Surf Sci 253:4570–4577

    Article  Google Scholar 

  30. Berchmans LJ, Sivan V, Iyer SVK (2006) Studies on triazole derivatives as inhibitors for the corrosion of muntz metal in acidic and neutral solutions. Mater Chem Phys 98:395–400

    Article  Google Scholar 

  31. El Issami S, Bazzi L, Mihit M, Hilali M, Salghi R, Ait Addi E (2005) Corrosion inhibition of 70Cu–30Zn alloy in 0.5 M HNO3 by 3-amino-1,2,4-triazole. J Phy IV France 123:307–311

    Article  Google Scholar 

  32. Xu QJ, Wan ZY, Yin RH, Zhu LJ, Cao WM, Zhou GD, Lin CJ (2008) Inhibition action of the self-assembled monolayers of 3-amino-1,2,4-triazole on brass. Acta Phys Chim Sin 24:115–120

    Article  Google Scholar 

  33. Chebabe D, Dermaj A, Erramli H, Hajjaji N (2014) Corrosion inhibition of bronze alloy B66 by 4-amino-3-methyl-1,2,4-triazole-5-thione in 3 per cent NaCl solution. Anti-Corros Methods Mater 61:281–286

    Article  Google Scholar 

  34. Dermaj A, Hajjaji N, Joiret S, Rahmouni K, Srhiri A, Takenouti H, Vivier V (2007) Electrochemical and spectroscopic evidences of corrosion inhibition of bronze by a triazole derivative. Electrochim Acta 52:4654–4662

    Article  Google Scholar 

  35. Pan YC, Wen Y, Zhang R, Wang YY, Zhang ZR, Yang HF (2012) Electrochemical and SERS spectroscopic investigations of 4-methyl-4H-1,2,4-triazole-3-thiol monolayers self-assembled on copper surface. Appl Surf Sci 258:3956–3961

    Article  Google Scholar 

  36. Rao BVA, Reddy MN, Sreedhar B (2014) Self-assembled 1-octadecyl-1H-1,2,4-triazole films on copper for corrosion protection. Prog Org Coat 77:202–212

    Article  Google Scholar 

  37. Finšgar M (2013) EQCM and XPS analysis of 1,2,4-triazole and 3-amino-1,2,4-triazole as copper corrosion inhibitors in chloride solution. Corros Sci 77:350–359

    Article  Google Scholar 

  38. Rajkumar G, Sethuraman MG (2014) Corrosion protection ability of self-assembled monolayer of 3-amino-5-mercapto-1,2,4-triazole on copper electrode. Thin Solid Films 562:32–36

    Article  Google Scholar 

  39. Finšgar M, Jackson J (2014) Application of corrosion inhibitors for steels in acidic media for the oil and gas industry: a review. Corros Sci 86:17–41

    Article  Google Scholar 

  40. Chigondo M, Chigondo F (2016) Recent natural corrosion inhibitors for mild steel: an overview. J Chem. doi:10.1155/2016/6208937

    Google Scholar 

  41. Raja PB, Ismail M, Ghoreishiamiri S, Mirza J, Ismail MC, Kakooei S, Rahim AA (2016) Reviews on corrosion inhibitors: a short view. Chem Eng Commun 203:1145–1156

    Article  Google Scholar 

  42. Ju H, Ding L, Sun C, Chen JJ (2015) Quantum chemical study on the corrosion inhibition of some oxadiazoles. Adv Mater Sci Eng. doi:10.1155/2015/519606

    Google Scholar 

  43. Vinutha MR, Venkatesha TV (2016) Review on mechanistic action of inhibitors on steel corrosion in acidic media. Port Electrochim Acta 34:157–18444

    Article  Google Scholar 

  44. Dwivedi D, Lepková K, Becker T (2017) Carbon steel corrosion: a review of key surface properties and characterization methods. RSC Adv 7:4580–4610. doi:10.1039/C6RA25094G

    Article  Google Scholar 

  45. Bentiss F, Bouanis M, Mernari B, Traisnel M, Vezin H, Lagrenée M (2007) Understanding the adsorption of 4H-1,2,4-triazole derivatives on mild steel surface in molar hydrochloric acid. Appl Surf Sci 253:3696–3704

    Article  Google Scholar 

  46. Bentiss F, Traisnel M, Gengembre L, Lagrenée M (2000) Inhibition of acidic corrosion of mild steel by 3,5-diphenyl-4H-1,2,4-triazole. Appl Surf Sci 161:0169–4332

    Article  Google Scholar 

  47. Lagrenée M, Mernari B, Bouanis M, Traisnel M, Bentiss F (2002) Study of the mechanism and inhibiting efficiency of 3,5-bis(4-methylthiophenyl)-4H-1,2,4-triazole on mild steel corrosion in acidic media. Corros Sci 44:573–588

    Article  Google Scholar 

  48. Bentiss F, Jama C, Mernari B, El Attari H, El Kadi L, Lebrini M, Traisnel M, Lagrenée M (2009) Corrosion control of mild steel using 3,5-bis(4-methoxyphenyl)-4-amino-1,2,4-triazole in normal hydrochloric acid medium. Corros Sci 51:1628–1635

    Article  Google Scholar 

  49. Kumar MS, Loganathan S, Kumar A, Sreekanth A (2012) Anticorrosion potential of 4-amino-3-methyl-1,2,4-triazole-5-thione derivatives (SAMTT and DBAMTT) on mild Steel in hydrochloric acid solution. Ind Eng Chem Res 51:5408–5418

    Article  Google Scholar 

  50. Chaitra TK, Mohana KNS, Tandon HC (2015) Thermodynamic, electrochemical and quantum chemical evaluation of some triazole Schiff bases as mild steel corrosion inhibitors in acid media. J Mol Liq 211:1026–1038

    Article  Google Scholar 

  51. Ansari KR, Quraishi MA, Singh A (2014) Schiff’s base of pyridyl substituted triazoles as new and effective corrosion inhibitors for mild steel in hydrochloric acid solution. Corros Sci 79:5–15

    Article  Google Scholar 

  52. John S, Joseph A (2012) Electro analytical, surface morphological and theoretical studies on the corrosion inhibition behavior of different 1,2,4-triazole precursors on mild steel in 1 M hydrochloric acid. Mater Chem Phys 133:1083–1091

    Article  Google Scholar 

  53. Xu F, Duan J, Zhang S, Hou B (2008) The inhibition of mild steel corrosion in 1 M hydrochloric acid solutions by triazole derivative. Mater Lett 62:4072–4074

    Article  Google Scholar 

  54. Garcίa-Ochoa E, Genesca J (2003) Understanding the inhibiting properties of 3-amino-1,2,4-triazole from fractal analysis. Surf Coat Technol 184:322–330

    Article  Google Scholar 

  55. Cruz J, Garcia-Ochoa E, Castro M (2003) Experimental and theoretical study of the 3-amino-1,2,4-triazole and 2-aminothiazole: corrosion inhibitors in carbon steel. J Electrochem Soc 150:B26–B35

    Article  Google Scholar 

  56. Hassan HH, Abdelghani E, Amin MA (2007) Inhibition of mild steel corrosion in hydrochloric acid solution by triazole derivatives: part I. Polarization and EIS studies. Electrochim Acta 52:6359–6366

    Article  Google Scholar 

  57. Hassan HH (2007) Inhibition of mild steel corrosion in hydrochloric acid solution by triazole derivatives: part II: time and temperature effects and thermodynamic treatments. Electrochim Acta 53:1722–1730

    Article  Google Scholar 

  58. Mert BD, Mert ME, Kardaş G, Yazıcı B (2011) Experimental and theoretical investigation of 3-amino-1,2,4-triazole-5-thiol as a corrosion inhibitor for carbon steel in HCl medium. Corros Sci 53:4265–4272

    Article  Google Scholar 

  59. Wang HL, Fan HB, Zheng JS (2003) Corrosion inhibition of mild steel in hydrochloric acid solution by a mercapto-triazole compound. Mater Chem Phys 77:655–661

    Article  Google Scholar 

  60. Mehdi BE, Mernari B, Traisnel M, Bentiss F, Lagrenée M (2003) Synthesis and comparative study of the inhibitive effect of some new triazole derivatives towards corrosion of mild steel in hydrochloric acid solution. Mater Chem Phys 77:489–496

    Article  Google Scholar 

  61. Bentiss F, Traisnel M, Gengembre L, Lagrenée M (1999) A new triazole derivative as inhibitor of the acid corrosion of mild steel: electrochemical studies, weight loss determination, SEM and XPS. Appl Surf Sci 152:237–249

    Article  Google Scholar 

  62. Bentiss F, Lagrenee M, Traisnel M, Hornez JC (1999) The corrosion inhibition of mild steel in acidic media by a new triazole derivative. Corros Sci 41:789–803

    Article  Google Scholar 

  63. Mernari B, El Attari H, Traisnel M, Bentiss F, Lagrenee M (1998) Inhibiting effects of 3,5-bis(n-pyridyl)-4-amino-1,2,4-triazoles on the corrosion for mild steel in 1 M HCl medium. Corros Sci 40:391–399

    Article  Google Scholar 

  64. Ouici HB, Benali O, Guendouzi A (2014) Corrosion inhibition of mild steel in acidic media using newly synthesized heterocyclic organic molecules: correlation between inhibition efficiency and chemical structure. AIP Conf Proc. doi:10.1063/1.4914277

    Google Scholar 

  65. Ansari KR, Yadav DK, Ebenso EE, Quraishi MA (2012) Novel and effective pyridyl substituted 1, 2, 4-triazole as corrosion inhibitor for mild steel in acid solution. Int J Electrochem Sci 7:4780–4799

    Google Scholar 

  66. Quraishi MA, Jamal D (2000) Fatty acid triazoles: novel corrosion inhibitors for oil well steel (N-80) and mild steel. JAOCS 77:1107–1111

    Google Scholar 

  67. Quraishi MA, Jamal D (2001) Corrosion inhibition of N-80 steel and mild steel in 15% boiling hydrochloric acid by a triazole compound—SAHMT. Mater Chem Phys 68:283–287

    Article  Google Scholar 

  68. Qiu LG, Xie AJ, Shen YH (2005) A novel triazole-based cationic gemini surfactant: synthesis and effect on corrosion inhibition of carbon steel in hydrochloric acid. Mater Chem Phys 91:269–273

    Article  Google Scholar 

  69. Tourabi M, Nohair K, Traisnel M, Jama C, Bentiss F (2013) Electrochemical and XPS studies of the corrosion inhibition of carbon steel in hydrochloric acid pickling solutions by 3,5-bis(2-thienylmethyl)-4-amino-1,2,4-triazole. Corros Sci 75:123–133

    Article  Google Scholar 

  70. Salghi R, Ebn Touhami M, Al-Deyab SS, Zarrouk A, Zarrok H, Oudda H, Hammouti B (2013) Investigation of 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole as corrosion Inhibitor for C38 steel in hydrochloric acid medium. GU J Sci 26:21–29

    Google Scholar 

  71. Abd-Elaal AA, Aiad I, Shaban SM, Tawfik SM, Sayed A (2014) Synthesis and evaluation of some triazole derivatives as corrosion inhibitors and biocides. J Surfact Deterg 17:483–491

    Article  Google Scholar 

  72. El Hajjaji S, Lgamri A, Aziane D, Guenbour A, Essassi EM, Akssira M, Bachir AB (2000) Synthesis and evaluation of the inhibitor effect of a new class of triazole compounds. Prog Org Coat 38:207–212

    Article  Google Scholar 

  73. Hegazy MA, Abd El Rehim SS, Badawi AM, Ahmed MY (2015) Studying the corrosion inhibition of carbon steel in hydrochloric acid solution by 1-dodecyl-methyl-1H-benzo[d][1, 2,3]triazole-1-ium bromide. RSC Adv 5:49070–49079

    Article  Google Scholar 

  74. El Attari H, El Bribri A, Mhaidra L, Bentiss F, Siniti M (2015) Synthesis and anticorrosion for carbon steel of 4-amino-3,5 bis (4-hydroxy-3-methoxy)-1,2,4-triazole in hydrochloric acid solution. Am J Eng Res 4:44–51

    Google Scholar 

  75. Tao Z, Zhang S, Li W, Hou B (2009) Corrosion inhibition of mild steel in acidic solution by some oxo-triazole derivatives. Corros Sci 51:2588–2595

    Article  Google Scholar 

  76. Zhang S, Tao Z, Liao S, Wu F (2010) Substitutional adsorption isotherms and corrosion inhibitive properties of some oxadiazol-triazole derivative in acidic solution. Corros Sci 52:3126–3132

    Article  Google Scholar 

  77. Quraishi MA, Sharma HK (2003) 4-Amino-3-butyl-5-mercapto-1,2,4-triazole: a new corrosion inhibitor for mild steel in sulphuric acid. Mater Chem Phys 78:18–21

    Article  Google Scholar 

  78. Liu X, Chen S, Zhai H, Shen L, Zhou J, Wu L (2007) The study of self-assembled films of triazole on iron electrodes using electrochemical methods, XPS, SEM and molecular simulation. Electrochem Commun 9:813–819

    Article  Google Scholar 

  79. Hazazi OA, Fawzy A, Awad M (2014) Synergistic effect of halides on the corrosion inhibition of mild steel in H2SO4 by a triazole derivative: kinetics and thermodynamic studies. Int J Electrochem Sci 9:4086–4103

    Google Scholar 

  80. Lebrini M, Traisnel M, Lagrenée M, Mernari B, Bentiss F (2008) Inhibitive properties, adsorption and a theoretical study of 3,5-bis(n-pyridyl)-4-amino-1,2,4-triazoles as corrosion inhibitors for mild steel in perchloric acid. Corros Sci 50:473–479

    Article  Google Scholar 

  81. Wang L, Zhu MJ, Yang FC, Gao CW (2012) Study of a triazole derivative as corrosion inhibitor for mild steel in phosphoric acid solution. Int J Corros 2012:573964

    Article  Google Scholar 

  82. El Belghiti M, Karzazi Y, Dafali A, Hammouti B, Bentiss F, Obot IB, Bahadur I, Ebenso EE (2016) Experimental, quantum chemical and Monte Carlo simulation studies of 3,5-disubstituted-4-amino-1,2,4-triazoles as corrosion inhibitors on mild steel in acidic medium. J Mol Liq 218:281–293

    Article  Google Scholar 

  83. Wang L (2006) Inhibition of mild steel corrosion in phosphoric acid solution by triazole derivatives. Corros Sci 48:608–616

    Article  Google Scholar 

  84. Belghiti ME, Karzazi Y, Dafali A, Obot IB, Ebenso EE, Emran KM, Bahadur I, Hammouti B, Bentiss F (2016) Anti-corrosive properties of 4-amino-3,5-bis(disubstituted)-1,2,4-triazole derivatives on mild steel corrosion in 2 M H3PO4 solution: experimental and theoretical studies. J Mol Liq 216:874–886

    Article  Google Scholar 

  85. Pour-Ali S, Kiani-Rashid A, Babakhani A (2016) Improved corrosion inhibition of 3-amino-1,2,4-triazole on mild steel electrode in HCl solution using surface nanocrystallization. Int J Mater Res 107:1031–1040

    Article  Google Scholar 

  86. Xu F, Hou B (2009) Triazole derivatives as corrosion inhibitors for mild steel in hydrochloric acid solution. Acta Metall Sin (Engl Lett) 22:247–254

    Article  Google Scholar 

  87. Ramesh S, Rajeswari S (2004) Corrosion inhibition of mild steel in neutral aqueous solution by new triazole derivatives. Electrochim Acta 49:811–820

    Article  Google Scholar 

  88. Amitha Rani BE, Basu BBJ (2012) Green inhibitors for corrosion protection of metals and alloys: an overview. Int J Corros. doi:10.1155/2012/380217

    Google Scholar 

  89. Xhanari K, Finsgar M (2016) Organic corrosion inhibitors for aluminium and its alloys in acid solutions: a review. RSC Adv 6:62833–62857

    Article  Google Scholar 

  90. Zheludkevich ML, Yasakau KA, Poznyak SK, Ferreira MGS (2005) Triazole and thiazole derivatives as corrosion inhibitors for AA2024 aluminium alloy. Corros Sci 47:3368–3383

    Article  Google Scholar 

  91. Sherif ESM (2013) Electrochemical investigations on the corrosion inhibition of aluminum by 3-amino-1,2,4-triazole-5-thiol in naturally aerated stagnant seawater. J Ind Eng Chem 19:1884–1889

    Article  Google Scholar 

  92. Zhu L, Yang WZ (2013) Corrosion inhibition performance of a triazole inhibitor for 5052 aluminum alloy in hydrochloric acid solution. J Mater Prot 2013:06

    Google Scholar 

  93. Qafsaoui W, Takenouti H (2010) Corrosion protection of 2024-T3 aluminium alloy by electro-polymerized 3-amino 1,2,4-triazole in sulphate solution containing chloride. Corros Sci 52:3667–3676

    Article  Google Scholar 

  94. Pinto GM, Nazaretha R, Shetty AN, Nayak J (2016) Electrochemical, SEM/EDX study of 3-ethyl-4-amino-5-mercapto-1,2,4-triazole as inhibitor for corrosion of 6061 Al-15 vol. Pct. SiC(p) composite and its base alloy in sulphuric acid medium. J Chem Pharm Res 8:84–106

    Google Scholar 

  95. Reena Kumari PD, Nayak J, Shetty AN (2011) 3-Ethyl-4-amino-5-mercapto-1,2,4-triazole as corrosion inhibitor for 6061-Alloy in sodium hydroxide solution. Port Electrochim 29:445–462

    Article  Google Scholar 

  96. Reena Kumari PD, Nayak J, Shetty AN (2014) Corrosion inhibition of 6061 Al-15 vol. pct. SiC(p) composite in sodium hydroxide solution by 4-amino-5-(4-nitrophenyl)-4H-1,2,4-triazole-3-thiol. Proc Mater Sci 5:181–187

    Article  Google Scholar 

  97. John S, Mohammad Ali K, Joseph A (2011) Electrochemical, surface analytical and quantum chemical studies on Schiff bases of 4-amino-4H-1,2,4-triazole-3,5-dimethanol (ATD) in corrosion protection of aluminium in 1 N HNO3. Bull Mater Sci 34:1245–1256

    Article  Google Scholar 

  98. Shylesha BS, Venkatesha TV, Praveen BM (2011) New electroactive compounds as corrosion inhibitors for zinc in acidic medium. Adv Appl Sci Res 2:333–341

    Google Scholar 

  99. Wippermann K, Schultze JW, Kessel R, Penninger J (1991) The inhibition of zinc corrosion by bisaminotriazole and other triazole derivatives. Corros Sci 32:205–223

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Sri Dharmasthala Manjunatheshwara Institute of Technology, Ujire, Karnataka, 574240, India

    N. Phadke Swathi & Seranthimata Samshuddin

  2. Department of Chemistry, Shree Devi Institute of Technology, Kenjar, Mangalore, Karnataka, 574142, India

    Vijaya D. P. Alva

Authors
  1. N. Phadke Swathi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Vijaya D. P. Alva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Seranthimata Samshuddin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Seranthimata Samshuddin.

Ethics declarations

Conflict of interest

On behalf of all authors, the corresponding author states that there is no conflict of interest.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Phadke Swathi, N., Alva, V.D.P. & Samshuddin, S. A Review on 1,2,4-Triazole Derivatives as Corrosion Inhibitors. J Bio Tribo Corros 3, 42 (2017). https://doi.org/10.1007/s40735-017-0102-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s40735-017-0102-3

Keywords

Search

Navigation