Abstract
In this paper, we will study the effect of soil engineering properties’ relationship on metal degradation of two series of brass alloys (brass devices). These two types of brass are an α-brass and α + β one. This work aims to specifying the best alloys which are recommended to be used in Azrou soil medium. This research paper was applied by using electrochemical impedance spectroscopy methods, polarization curves, scanning electron microscopy (SEM), and X-ray spectrometry microanalysis measurements. It was found that EC5 is the most resistant alloy between the three α-brasses and EC6 which is the most resistant alloy among the four α + β brasses in this soil type. The different alloy surfaces were examined by SEM, whereas the chemical composition was determined by EDAX analysis. Moreover, we have studied the role and effects of synergy on various additional elements which exist in different brasses and they are responsible for increasing the corrosion resistance.
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Gerwin W, Baumhauer W (2000) Effect of soil parameters on the corrosion of archaeological metal finds. Geoderma 96:63–80
Papadopoulou O, Vassiliou P, Grassini S, Angelini E, Gouda V (2016) Soil-induced corrosion of ancient Roman brass-case study. Mater Corros 67:160–169
Tylecote RF (1979) The effect of soil conditions on the long-term corrosion of buried tin-bronzes and copper. J Archaesol Sci 6:345–368
Neff D, Dillmann P, Bellot-Gurlet L, Beranger G (2005) Corrosion of iron archaeological artefacts in soil: characterisation of the corrosion system. Corros Sci 47:515–535
Assouli B(2002) Etude par émission acoustique associée aux méthodes électrochimiques de la corrosion et de la protection de l’alliage cuivre-zinc (60/40) en milieu neutre et alcalin. Thesis, INPT
Pechering HW (1983) Characteristic features of alloy polarization curves. Corrosi Sci 23:1107–1120
Nicholas D (1994) Dezincification of brass in potable waters, UWRAA, Research Report No. 84
Zou JY, Wang DH, Qiu WC (1997) Solid-state diffusion during the selective dissolution of brass: chronoamperometry and positron annihilation study. Electrochim Acta 42:1733
Bowers JE, Oseland PWR, Davies GC (1978) Development of a Hot-stamping brass resistant to dezincification. Br Corros J 13:177
Bengough GD, May R (1924) Seventh report to the corrosion research committee of the Institute of Metals. J Instrum Met 32:81
Toivanen RO, Hirvonen J, Lindroos VK (1985) Dezincification of boron implanted brass. Nucl Instrum Methods Phys Res B 7:200
Fiaud C, Bensarsa S, Demesy I, Tzinmann M (1987) Inhibiting properties of phosphines against zinc corrosion in acidic media. Br Corros J 22:109
Beccaria AM, Poggi G, Capannelli G (1989) The effect on the behavior of α-brasses in sea water of the addition of Al and Sn. Corros Prev Control 10:169
Hansen M, Anderko K, Salzberg HW (1958) Constitution of binary alloys. J Electrochem Soc 105:260C–261C
Ogilvie I (1982) Recent developments in the production of dezincification resistant brass. Corros Coat S Afr 9:9–13
Bonneau M, Souchier B (1979) Constituants et propriétés du sol, Centre de pédologie biologique
I S O (1991) Soil Quali@ -Terminology - Soil data structuration, AFNOR-Paris
Barbalat M, Lanarde L, Caron D, Meyerb M, Vittonato J, Castillon F, Fontaine S, Refait Ph Ph (2012) Electrochemical study of the corrosion rate of carbon steel in soil: evolution with time and determination of residual corrosion rates under cathodic protection. Corros Sci 55:246–253
Stern M, Geary AL (1957) Discussion of electrochemical polarization, 1. A theoretical Analysis of the shape of polarization curves. J Electrochem Soc 104:56–63
Bouckamp BA (1993) Users manual equivalent circuit, ver. 4.51, faculty of chem. Tech., Universidad of Twente, The Netherlands
Vazquez VM, Sánchez SR, Calvo EJ, Schiffrin DJ (1994) The electrochemical reduction of oxygen on polycrystalline copper in borax buffer. J Electroanal Chem 374:189–197
Cere S, Vazquez M, Sanchez SR, Schiffrin DJ (2001) Surface redox catalysis and reduction kinetics of oxygen on copper–nickel alloys. J Electroanal Chem 505:118–124
Metikoš-Huković M, Skugor I, Grubač Z, Babic R (2010) Complexities of corrosion behavior of copper–nickel alloys under liquid impingement conditions in saline water. Electrochim Acta 55:3123–3129
Kear G, Barker BD, Stokes KR, Walsh FC (2004) Flow influenced electrochemical corrosion of nickel aluminium bronze–Part I. Cathodic polarization. J Appl Electrochem 34:1235–1240
Sury P, Otswald HR (1972) On the corrosion behaviour of individual phases present in aluminium bronzes. Corros Sci 12:77–80
Kear G, Barker BD, Stokes KR, Walsh FC (2004) Flow influenced electrochemical corrosion of nickel aluminium bronze–Part II. Anodic polarization and derivation of the mixed potential. J Appl Electrochem 34:1241–1248
Procaccini R, Ceré S, Vázquez M (2009) Oxygen reduction on Cu–Zn alloys. J Appl Electrochem 39:177–184
Chen B, Liang C, Fu D, Ren D (2005) Corrosion behavior of Cu and the Cu–Zn–Al shape memory alloy in simulated uterine fluid. Contraception 72:221–224
Fink FW (1939) The dezincification of alpha brass with special reference to arsenic. Trans Electrochem Soc 75:441–448
Bevolo AJ, Baikerikar KG, Hansen RS (1984) An Auger/SEM study of the corrosion of β-brass alloyed with tin. J Vac Sci Technol A 2:784–786
Sohn S, Kang T (2002) The effects of tin and nickel on the corrosion behavior of 60Cu–40Zn alloys. J Alloys Compd 335:281–289
Mazille H, Dabosi F, Beranger G, Baroux B (1994) Corrosion localisée. Editions de Physique, Paris, p 380
Chiavari C, Colledan A, Frignani A, Brunoro G (2006) Corrosion evaluation of traditional and new bronzes for artistic casting. Mater Chem Phys 95:252–259
Amar H, Benzakour J, Derja A, Villemin D, Moreau B, Braisaz TJ (2006) Piperidin-1-yl-phosphonic acid and (4-phosphono-piperazin-1-yl) phosphonic acid: a new class of iron corrosion inhibitors in sodium chloride 3% media. Appl Surf Sci 252:6162–6172
Jorcin JB (2007) Spectroscopie d’impédance électrochimique locale : caractérisation de la de lamination des peintures et de la corrosion des alliages Al–Cu, Thesis, INPT
Barcia OE, D’Elia E, Frateur I, Mattos OR, Pébère N, Tribollet B (2002) Application of the impedance model of de Levie for the characterization of porous electrodes. Electrochim Acta 47:2109–2116
Fiaud C (1995) Proceedings of the 8th European symposium on corrosion inhibitors (8 SEIC). Ann Univ Ferrara NS Sez V 10(Suppl N):929
Ammeloot F, Fiaud C, Sutter EMM (1999) Characterization of the oxide layers on a Cu–13Sn alloy in a NaCl aqueous solution without and with 0.1 M benzotriazole. Electrochemical and photo electrochemical contributions. Electrochim Acta 44:2549–2558
Ismail KM, Badawy WA (2000) Electrochemical and XPS investigations of cobalt in KOH solutions. J Appl Electrochem 30:1303–1311
Karpagavalli R, Balasubramaniam R (2007) Development of novel brasses to resist dezincification. Corros Sci 49(3):963–979
Davies DD, MIM (1993) A note on the dezincification of brass and the inhibiting effect of elemental additions, Dip App Chem, 260 Madison Avenue New York, 10016
Smathers DB (1990) A 15 superconductors. In: Metals handbook, 10th edn, vol 2. ASM International, p 1060–1076
Hitzig J, Titz J, Juettner K, Lorenz WJ, Schmidt E (1984) Frequency response analysis of the Ag/Ag+ system: a partially active electrode approach. Electrochim Acta 29:287–296
Hassairi H, Bousselmi L, Triki E, Ingo GM (2007) Assessment of the interphase behaviour of two bronze alloys in archaeological soil. Mater Corros 58:121–128
Bin H, Pengju H, Chunhui L, Xiaohong B (2015) Effect of soil particle size on the corrosion behavior of natural gas pipeline. Eng Fail Anal 58:19–30
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Authors are gratefully acknowledges National office of water and electricity (ONEE), Rabat, Morocco for the financial assistance and facilitation of our study.
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Galai, M., Ouassir, J., Ebn Touhami, M. et al. α-Brass and (α + β) Brass Degradation Processes in Azrou Soil Medium Used in Plumbing Devices. J Bio Tribo Corros 3, 30 (2017). https://doi.org/10.1007/s40735-017-0087-y
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DOI: https://doi.org/10.1007/s40735-017-0087-y