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Bimetallic Sulfide/Sulfur Doped T3C2Tx MXene Nanocomposites as High-performance Anode Materials for Sodium-ion Batteries

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Chemical Research in Chinese Universities Aims and scope

Abstract

The application of transition metal dichalcogenides(TMDs) as anode materials in sodium-ion batteries (SIBs) has been hindered by low conductivity and poor cyclability. Herein, we report the synthesis of CoxFe1−xS2 bimetallic sulfide/sulfur-doped Ti3C2 MXene nanocomposites(CoxFe1−xS2@S-Ti3C2) by a facile co-precipitation process and thermal-sulfurization reaction. The interconnected 3D frameworks consisting of MXene nanosheets can effectively buffer the volume change and enhance the charge transfer. In particular, sulfur-doped MXene nanosheets provide rich active sites for sodium storage and restrain sulfur loss during charging/discharging processes, leading the increase of specific capacity and cycling the stability of anode materials. As a result, CoxFe1−xS2@S-Ti3C2 anodes exhibited high capacity, high rate capability and long cycle life(399 m·Ah/g at 5 A/g with an 94% capacity retention after 600 cycles).

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Authors and Affiliations

  1. College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing, 210006, P. R. China

    Rui Zang & Peng Li

  2. Centre of Clean Energy Technology, Faculty of Science, University of Technology, Sydney, NSW, 2007, Australia

    Guoxiu Wang

Authors
  1. Rui Zang
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  2. Peng Li
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  3. Guoxiu Wang
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Corresponding author

Correspondence to Guoxiu Wang.

Additional information

Supported by the National Natural Science Foundation of China(No.21573110) and the Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD), China.

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40242_2020_120_MOESM1_ESM.pdf

Bimetallic Sulfide/Sulfur Doped T3C2Tx MXene Nanocomposites as High-performance Anode Materials for Sodium-ion Batteries

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Zang, R., Li, P. & Wang, G. Bimetallic Sulfide/Sulfur Doped T3C2Tx MXene Nanocomposites as High-performance Anode Materials for Sodium-ion Batteries. Chem. Res. Chin. Univ. 36, 431–438 (2020). https://doi.org/10.1007/s40242-020-0120-4

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  • DOI: https://doi.org/10.1007/s40242-020-0120-4

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