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Evaluating the ability of Iranian natural zeolite to remove lead from polluted groundwater in Fashafuye plain

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Abstract

The removal efficiency of lead from groundwater in Fashafuye Plain was investigated by two types of Iranian zeolites (type A and B) in batch-mode experiments. Surface properties, structure, and composition of both zeolites were analyzed and it was found that both were clinoptilolite but type B contained impurities such as gypsum and halite. Electron beam methods showed that zeolite type B had a more porous structure and a larger mean pore diameter. Because of the variation in pH in the Fashafuye plain for the both zeolites, batch experiments were conducted in pH = 6, 7, and 8, with the highest removal efficiency for A and B being approximately 82.3 and 84.2%, respectively, at pH 6 and 298 K within 90 min. The Freundlich model predicted metal ion adsorption behavior accurately and illustrated that multilayer lead adsorption appeared on the inhomogeneous surface of clinoptilolites. The pseudo-2nd-order equation is the best-fitting kinetic model for both zeolites, implying that chemisorption might be involved in the adsorption process. The thermodynamic equilibrium coefficients were calculated, indicating that lead adsorption on the clinoptilolites was endothermic and spontaneous. Adsorbent selectivity for lead was also investigated by adding them to the polluted groundwater from two sites in the Fashafuye plain, with the results revealing that zeolite type B had a higher uptake efficiency than type A.

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References

  • Abdullah N, Yusof N, Lau W, Jaafar J, Ismail A (2019) Recent trends of heavy metal removal from water/wastewater by membrane technologies. J Ind Eng Chem 76:17–38

    Article  CAS  Google Scholar 

  • Aghel B, Mohadesi M, Gouran A, Razmegir M (2020) Use of modified Iranian clinoptilolite zeolite for cadmium and lead removal from oil refinery wastewater. Int J Environ Sci Technol 17:1239–1250

    Article  CAS  Google Scholar 

  • Azarudeen RS, Riswan Ahamed MA, Subha R, Burkanudeen AR (2015) Heavy and toxic metal ion removal by a novel polymeric ion-exchanger: synthesis, characterization, kinetics and equilibrium studies. J Chem Technol Biotechnol 90:2170–2179

    Article  CAS  Google Scholar 

  • Bae YS, Yazaydın AO, Snurr RQ (2010) Evaluation of the BET method for determining surface areas of MOFs and zeolites that contain ultra-micropores. Langmuir 26:5475–5483

    Article  CAS  Google Scholar 

  • Bashambu L, Singh R, Verma J (2021) Metal/metal oxide nanocomposite membranes for water purification. Mater Today: Proc 44:538–545

    CAS  Google Scholar 

  • Bayramoğlu G, Arica MY (2008) Adsorption of Cr (VI) onto PEI immobilized acrylate-based magnetic beads: isotherms, kinetics and thermodynamics study. Chem Eng J 139:20–28

    Article  Google Scholar 

  • Behin J, Ghadamnan E, Kazemian H (2019) Recent advances in natural zeolites sciences and technologies in Iran. Clay Miner 54:131–144

    Article  CAS  Google Scholar 

  • Berber-Mendoza M, Leyva-Ramos R, Alonso-Davila P, Fuentes-Rubio L, Guerrero-Coronado R (2006) Comparison of isotherms for the ion exchange of Pb (II) from aqueous solution onto homoionic clinoptilolite. J Colloid Interface Sci 301:40–45

    Article  CAS  Google Scholar 

  • Bezzina JP, Robshaw T, Dawson R, Ogden MD (2020) Single metal isotherm study of the ion exchange removal of Cu (II), Fe (II), Pb (II) and Zn (II) from synthetic acetic acid leachate. Chem Eng J 394:124862

    Article  CAS  Google Scholar 

  • Blanchard G, Maunaye M, Martin G (1984) Removal of heavy metals from waters by means of natural zeolites. Water Res 18:1501–1507

    Article  CAS  Google Scholar 

  • Breck D, Sieves ZM (1974) Structure chemistry and use. Wiley, New York

    Google Scholar 

  • Bulut Y, Tez Z (2007) Adsorption studies on ground shells of hazelnut and almond. J Hazard Mater 149:35–41

    Article  CAS  Google Scholar 

  • DEMIRTAŞ, İ., BAKıRDERE, S. & ATAMAN, O. Y. (2015) Lead determination at ng/mL level by flame atomic absorption spectrometry using a tantalum coated slotted quartz tube atom trap. Talanta 138:218–224

    Article  Google Scholar 

  • Dursun S, Pala A (2007) Lead pollution removal from water using a natural zeolite. J Int Environ Appl Sci 7:11–19

    Google Scholar 

  • ELBOUGHDIRI, N. (2020) The use of natural zeolite to remove heavy metals Cu (II), Pb (II) and Cd (II), from industrial wastewater. Cogent Eng 7:1782623

    Article  Google Scholar 

  • Fetter CW, Boving T, Kreamer D (2017) Contaminant hydrogeology. Waveland Press

  • Fleck N, Amli H, Dhanak V, Ahmed W (2021) Characterization techniques in energy generation and storage. Emerging nanotechnologies for renewable energy. Elsevier

    Google Scholar 

  • Fosso-Kankeu E, Mulaba-Bafubiandi A, Mamba B, Barnard T (2011) Prediction of metal-adsorption behaviour in the remediation of water contamination using indigenous microorganisms. J Environ Manage 92:2786–2793.

    Article  CAS  Google Scholar 

  • Fosso-Kankeu E, Waanders FB, Steyn FW (2017) Removal of Cr (VI) and Zn (II) from an aqueous solution using an organic-inorganic composite of bentonite-biochar-hematite. Desalination and Water Treatment 59:144–153.

    Article  Google Scholar 

  • FREUNDLICH, H. (1907) Über die adsorption in lösungen. Z Phys Chem 57:385–470

    Article  Google Scholar 

  • Goel J, Kadirvelu K, Rajagopal C, Garg VK (2005) Removal of lead (II) by adsorption using treated granular activated carbon: batch and column studies. J Hazard Mater 125:211–220

    Article  CAS  Google Scholar 

  • Greenlee LF, Lawler DF, Freeman BD, Marrot B, Moulin P (2009) Reverse osmosis desalination: water sources, technology, and today’s challenges. Water Res 43:2317–2348

    Article  CAS  Google Scholar 

  • Gunay A, Arslankaya E, Tosun I (2007) Lead removal from aqueous solution by natural and pretreated clinoptilolite: adsorption equilibrium and kinetics. J Hazard Mater 146:362–371

    Article  Google Scholar 

  • Gupta VK, Ali I (2004) Removal of lead and chromium from wastewater using bagasse fly ash—a sugar industry waste. J Colloid Interface Sci 271:321–328

    Article  CAS  Google Scholar 

  • Hamidpour M, Kalbasi M, Afyuni M, Shariatmadari H, Furrer G (2011) Sorption of lead on Iranian bentonite and zeolite: kinetics and isotherms. Environ Earth Sci 62:559–568

    Article  CAS  Google Scholar 

  • Hayashi A, Akimoto K, Tomoda T, Kii M (2013) Global evaluation of the effects of agriculture and water management adaptations on the water-stressed population. Mitig Adapt Strat Glob Change 18:591–618

    Article  Google Scholar 

  • Heidarian MH, Nakhaei M, Vatanpour V, Rezaei K (2023) Evaluation of using clinoptilolite as a filter in drinking water wells for removal of lead (small-scale physical sand box model). J Water Process Eng 52:103558

    Article  Google Scholar 

  • Ho Y-S, McKay G (1999) Pseudo-second order model for sorption processes. Process Biochem 34:451–465

    Article  CAS  Google Scholar 

  • Ho Y, McKay G (1998) A comparison of chemisorption kinetic models applied to pollutant removal on various sorbents. Process Saf Environ Prot 76:332–340

    Article  CAS  Google Scholar 

  • Irandoost M, Pezeshki-Modaress M, Javanbakht V (2019) Removal of lead from aqueous solution with nanofibrous nanocomposite of polycaprolactone adsorbent modified by nanoclay and nanozeolite. J Water Process Eng 32:100981

    Article  Google Scholar 

  • Kalebić B, Pavlović J, Dikić J, Rečnik A, Gyergyek S, Škoro N, Rajić N (2021) Use of natural clinoptilolite in the preparation of an efficient adsorbent for ciprofloxacin removal from aqueous media. Minerals 11:518

    Article  Google Scholar 

  • Khalfa L, Sdiri A, Bagane M, Cervera ML (2021) A calcined clay fixed bed adsorption studies for the removal of heavy metals from aqueous solutions. J Clean Prod 278:123935

    Article  CAS  Google Scholar 

  • Khalil A, Hashaikeh R, Hilal N (2021) 3D printed zeolite-Y for removing heavy metals from water. J Water Process Eng 42:102187

    Article  Google Scholar 

  • Khosravi MJ, Hosseini SM, Vatanpour V (2022) Performance improvement of PES membrane decorated by Mil-125 (Ti)/chitosan nanocomposite for removal of organic pollutants and heavy metal. Chemosphere 290:133335

    Article  CAS  Google Scholar 

  • Kumar V, Dwivedi S, Oh S (2022) A critical review on lead removal from industrial wastewater: recent advances and future outlook. J Water Process Eng 45:102518

    Article  Google Scholar 

  • Lam S, Nguyen-Viet H, Tuyet-Hanh TT, Nguyen-Mai H, Harper S (2015) Evidence for public health risks of wastewater and excreta management practices in Southeast Asia: a scoping review. Int J Environ Res Public Health 12:12863–12885

    Article  CAS  Google Scholar 

  • Langmuir I (1918) The adsorption of gases on plane surfaces of glass, mica and platinum. J Am Chem Soc 40:1361–1403

    Article  Google Scholar 

  • LI, P. (2020) To make the water safer. Expo Health 12:337–342

    Article  Google Scholar 

  • Li P, Karunanidhi D, Subramani T, Srinivasamoorthy K (2021) Sources and consequences of groundwater contamination. Arch Environ Contam Toxicol 80:1–10

    Article  Google Scholar 

  • Mahdavi Far R, Van Der Bruggen B, Verliefde A, Cornelissen E (2022) A review of zeolite materials used in membranes for water purification: history, applications, challenges and future trends. J Chem Technol Biotechnol 97:575–596

    Article  CAS  Google Scholar 

  • Mazloomi F, Jalali M (2016) Ammonium removal from aqueous solutions by natural Iranian zeolite in the presence of organic acids, cations and anions. J Environ Chem Eng 4:240–249

    Article  CAS  Google Scholar 

  • Mcbain JW (1932) The sorption of gases and vapours by solids. G. Routledge

  • McKay G, Blair H, Gardner J (1982) Adsorption of dyes on chitin. I. Equilibrium studies. J Appl Polym Sci 27:3043–3057

    Article  CAS  Google Scholar 

  • Medvidović NV, Perić J, Trgo M (2006) Column performance in lead removal from aqueous solutions by fixed bed of natural zeolite–clinoptilolite. Sep Purif Technol 49:237–244

    Article  Google Scholar 

  • Moazeni M, Parastar S, Mahdavi M, Ebrahimi A (2020) Evaluation efficiency of Iranian natural zeolites and synthetic resin to removal of lead ions from aqueous solutions. Appl Water Sci 10:1–9

    Article  Google Scholar 

  • Mohammed AA, Selman HM (2018) Liquid surfactant membrane for lead separation from aqueous solution: Studies on emulsion stability and extraction efficiency. J Environ Chem Eng 6:6923–6930

    Article  CAS  Google Scholar 

  • Moore MR (1988) Haematological effects of lead. Sci Total Environ 71:419–431

    Article  Google Scholar 

  • Muharrem I, Ince OK (2017) An overview of adsorption technique for heavy metal removal from water/wastewater: a critical review. Int J Pure Appl Sci 3:10–19

    Article  Google Scholar 

  • Mumpton FA (2018) Mineralogy and geology of natural zeolites. Walter de Gruyter GmbH & Co KG

  • Nakhaei M, Dadgar MA, Amiri V (2016) Geochemical processes analysis and evaluation of groundwater quality in Hamadan Province, Western Iran. Arab J Geosci 9:1–13

    Article  CAS  Google Scholar 

  • Nakhaei M, Heidarian MH, Vatanpour V, Rezaei K (2023) Evaluation the feasibility of using clinoptilolite as a gravel pack in water wells for removal of lead from contaminated groundwater. Environ Sci Pollut Res 30:4653–4668

    Article  CAS  Google Scholar 

  • Newbury* DE, Ritchie NW (2013) Is scanning electron microscopy/energy dispersive X‐ray spectrometry (SEM/EDS) quantitative? Scanning 35:141–168

  • Orumwense FF (1996) Removal of lead from water by adsorption on a kaolinitic clay. J Chem Technol Biotechnol: Int Res Process, Environ Clean Technol 65:363–369

    Article  Google Scholar 

  • Panda L, Jena SK, Rath SS, Misra PK (2020) Heavy metal removal from water by adsorption using a low-cost geopolymer. Environ Sci Pollut Res 27:24284–24298

    Article  CAS  Google Scholar 

  • Pandey S, Fosso-Kankeu E, Spiro M, Waanders F, Kumar N, Ray SS, Kim J, Kang M (2020) Equilibrium, kinetic, and thermodynamic studies of lead ion adsorption from mine wastewater onto MoS2-clinoptilolite composite. Mater Today Chem 18:100376

    Article  CAS  Google Scholar 

  • Pandey S, Ramontja J (2016) Guar gum-grafted poly (acrylonitrile)-templated silica xerogel: nanoengineered material for lead ion removal. J Analyt Sci Technol 7:1–15

    CAS  Google Scholar 

  • Panek R, Wdowin M, Franus W (2014) The use of scanning electron microscopy to identify zeolite minerals. In: International multidisciplinary microscopy congress. Springer, pp 45–50

  • Peng H, Guo J (2020) Removal of chromium from wastewater by membrane filtration, chemical precipitation, ion exchange, adsorption electrocoagulation, electrochemical reduction, electrodialysis, electrodeionization, photocatalysis and nanotechnology: a review. Environ Chem Lett 18:2055–2068

    Article  CAS  Google Scholar 

  • Rodríguez-Iznaga I, Shelyapina MG, Petranovskii V (2022) Ion exchange in natural clinoptilolite: aspects related to its structure and applications. Minerals 12:1628

    Article  Google Scholar 

  • Saravanan A, Kumar PS, Yaashikaa P, Karishma S, Jeevanantham S, Swetha S (2021) Mixed biosorbent of agro waste and bacterial biomass for the separation of Pb (II) ions from water system. Chemosphere 277:130236

    Article  CAS  Google Scholar 

  • Sharifipour F, Hojati S, Landi, A, Faz Cano A (2015) Kinetics and thermodynamics of lead adsorption from aqueous solutions onto Iranian sepiolite and zeolite. Int J Environ Res 9:1001–1010

    CAS  Google Scholar 

  • Tahoon MA, Siddeeg SM, Salem Alsaiari N, Mnif W, Ben Rebah F (2020) Effective heavy metals removal from water using nanomaterials: A review. Processes 8:645

    Article  CAS  Google Scholar 

  • Taka AL, Fosso-Kankeu E, Pillay K, Mbianda XY (2018) Removal of cobalt and lead ions from wastewater samples using an insoluble nanosponge biopolymer composite: adsorption isotherm, kinetic, thermodynamic, and regeneration studies. Environ Sci Pollut Res 25:21752–21767

    Article  CAS  Google Scholar 

  • Thabede PM, Shooto ND, Naidoo EB (2020) Removal of methylene blue dye and lead ions from aqueous solution using activated carbon from black cumin seeds. S Afr J Chem Eng 33:39–50

    Google Scholar 

  • Tran TK, Leu HJ, Chiu KF, Lin CY (2017) Electrochemical treatment of heavy metal-containing wastewater with the removal of COD and heavy metal ions. J Chin Chem Soc 64:493–502

    Article  CAS  Google Scholar 

  • Vatanpour V, Salehi E, Sahebjamee N, Ashrafi M (2020) Novel chitosan/polyvinyl alcohol thin membrane adsorbents modified with detonation nanodiamonds: preparation, characterization, and adsorption performance. Arab J Chem 13:1731–1740

    Article  CAS  Google Scholar 

  • Vukojević Medvidović N, Perić J, Trgo M, Nuić I, Ugrina M (2013) Design of fixed bed column for lead removal on natural zeolite based on batch studies. Chem Biochem Eng Q 27:21–28

    Google Scholar 

  • Wang L, Wang X, Li J, Feng X, Wang Y (2017) Silica aerogel-supported hydrozincite and carbonate-intercalated hydrotalcite for high-efficiency removal of Pb (II) ions by precipitation transformation reactions. Nanoscale Res Lett 12:1–10

    Article  Google Scholar 

  • WHO (2021) A global overview of national regulations and standards for drinking-water quality, Second edition, Water, Sanitation, Hygiene and Health. World Health Organization, Switzerland, 109 pages.

  • Wu J, Zhang Y, Zhou H (2020) Groundwater chemistry and groundwater quality index incorporating health risk weighting in Dingbian County, Ordos Basin of Northwest China. Geochemistry 80:125607

    Article  CAS  Google Scholar 

  • Yang X, Yang S, Yang S, Hu J, Tan X, Wang X (2011) Effect of pH, ionic strength and temperature on sorption of Pb (II) on NKF-6 zeolite studied by batch technique. Chem Eng J 168:86–93

    Article  CAS  Google Scholar 

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Acknowledgements

This research was part of a PhD thesis conducted at Kharazmi University, Iran, and the financial support was received from Vice-Presidency for Science and Technology, Islamic Republic of Iran.

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Authors and Affiliations

  1. Department of Applied Geology, Faculty of Earth Sciences, Kharazmi University, Tehran, Iran

    M. H. Heidarian, M. Nakhaei & K. Rezaei

  2. Department of Applied Chemistry, Faculty of Chemistry, Kharazmi University, P.O. Box, Tehran, 15719-14911, Iran

    V. Vatanpour

  3. Water Research Center, Kharazmi University, Tehran, Iran

    M. Nakhaei

  4. Department of Environmental Engineering, Istanbul Technical University, 34469, Maslak, Istanbul, Turkey

    V. Vatanpour

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  1. M. H. Heidarian
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All authors contributed to the study conception and design. Material preparation, data collection, and analysis were performed by them. The first draft of the manuscript was written by them, and they commented on previous versions of the manuscript. All authors read and approved the final manuscript.

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Correspondence to M. H. Heidarian.

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Heidarian, M.H., Nakhaei, M., Vatanpour, V. et al. Evaluating the ability of Iranian natural zeolite to remove lead from polluted groundwater in Fashafuye plain. Int. J. Environ. Sci. Technol. 20, 6747–6760 (2023). https://doi.org/10.1007/s13762-023-04905-w

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