Abstract
The title compound, diaqua(bissalicylato-κO)(bisnicotinamide-κN)zinc(II)][bis(triaqua (monosalicylato-κO)(mononicotinamide-κN)zinc(II)salicylate, includes three Zn(II) ions, four nicotinamide ligands, six salicylate ligands and eight coordinated aqua ligands in the asymmetric unit in complex structure. The geometry around one of the Zn(II) ions is a slightly distorted octahedron, of which the equatorial plane is formed by two carboxylate oxygens and two aqua oxygens, while the axial positions are occupied by two pyridyl nitrogen atoms. The other Zn(II) ions adopt fivefold coordinations with one carboxylate oxygen atom from salicylate ligand, one N atom from nicotinamide ligand and three oxygen atoms from aqua ligands. In addition, there are two salicylate anions in the unit cell that are not coordinated. They provide charge balance as counter-ions in the complex framework.
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J.R.J. Sorenson, V. Kishore, A. Pezeshk, L.W. Oberley, S.W.C. Leuthauser, T.D. Oberley, Inorg. Chim. Acta 91, 285 (1984)
G. Cavigiolio, L. Benedetto, E. Boccaleri, D. Colangelo, I. Viano, D. Osella, Inorg. Chim. Acta 305(1), 61 (2000)
U. Bruehlmann, E. Hayon, J. Am. Chem. Soc. 96(19), 6169 (1974)
J.R.J. Sorensen, in Metal Ions in Biological Systems, vol. 14, ed. by H. Sigel (Marcel Dekker), New York, 1982, p.77
C.A. Rice-Evans, N.J. Miller, G. Paganga, Free Radical Biol. Med. 20, 933 (1996)
A. Hossaini, J.J. Larsen, J.C. Larsen, Food Chem. Toxicol. 38, 319 (2000)
D.A. Köse, B. Zümreoglu-Karan, C. Unaleroğlu, O. Şahin, O. Büyükgüngör, J. Coord. Chem. 18, 2125 (2006)
B.L. Vallee, D.S. Auld, Biochemistry 24, 5647 (1990)
E. Kimura, T. Koike, Adv. Inorg. Chem. 44, 229 (1997)
W. Kaim, B. Schwederski, Bioinorganic Chemistry: Inorganic Elements in the Chemistry of Life (Wiley, Chichester, 1994)
E.J. van Hoogdalem, J. Eur. Acad. Dermatol. Venereol 11, 13 (1998)
E. De Clercq, Metal-based drugs 4, 173 (1997)
O. Yamamoto, Int. J. Inorg. Mater. 3, 643 (2001)
Y.H. Cho, S.J. Lee, J.Y. Lee, S.W. Kim, Ch.B. Lee, W.Y. Lee, M.S. Yoon, Int. J. Antimicrob. Agents 19, 576 (2002)
S.C. Cunnane, Zinc: Clinical and Biochemical Significance (CRC Press, Boca Raton, 1988)
C.L. Feucht, B.S. Allen, D.K. Chalker, J. Am. Acad. Dermatol. 3, 483 (1980)
H. Icbudak, Z. Heren, D.A. Köse, H. Necefoğlu, J. Therm. Anal. Cal. 76, 837 (2004)
D.A. Köse, H. Necefoğlu, J. Therm. Anal. Cal. 93(2), 509 (2008)
D.A. Köse, A. Kaya, H. Necefoğlu, Russ. J. Coord. Chem. 33(6), 422 (2007)
D.A. Köse, H. İçbudak, H. Necefoğlu, Hacettepe J. Biol. Chem. 35(2), 123 (2007)
T. Hökelek, H. Necefoğlu, Acta Cryst. E58, m121 (2002)
W. Wolodkiewicz, W. Bryska, Polish J. Chem. 71(1–3), 16 (1997)
V. Zeleñák, Z. Vargová, K. Györyová, Spectrochimica Acta A66, 262 (2007)
A. Erxleben, Coord. Chem. Rev. 246, 203 (2003)
H. Necefoglu, W. Clegg, A.J. Scott, Acta Cryst. E57, m465 (2001)
K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds (Wiley and Sons, New York, 1978)
D.A. Köse, H. Necefoğlu, H. Icbudak, J. Coord. Chem. 61(21), 3508 (2008)
D.A. Köse, B. Zümreoglu-Karan, O. Şahin, O. Büyükgüngör, J. Mol. Struct. 789, 147 (2006)
V. Zeleñák, M. Sabo, W. Massa, P. Lewellyn, Inorg. Chim. Acta 357, 2049 (2004)
D.A. Köse, G. Gökçe, S. Gökçe, İ. Uzun, J. Therm. Anal. Cal. 95(1), 247 (2009)
G.M. Sheldrick, Acta Cryst. A64, 112 (2008)
L.J. Farrugia, J. Appl. Cryst. 32, 837 (1999)
A.L. Spek, J. Appl. Cryst. 36, 7 (2003)
J. Bernstein, R.E. Davis, L. Shimoni, N.L. Chang, Angew. Chem. Int. Ed. Engl. 34, 1555 (1995)
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The authors wish to acknowledge the Faculty of Arts and Sciences, Ondokuz Mayıs University, Turkey, for the use of the Stoe IPDS-II diffractometer (purchased from Grant No. F279 of the University Research Fund).
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Köse, D.A., Ay, A.N., Şahin, O. et al. A mononuclear, mixed (salicylato) (nicotinamide) complex of Zn(II) with penta- and hexa-coordination sites: a novel framework structure. J IRAN CHEM SOC 9, 591–597 (2012). https://doi.org/10.1007/s13738-012-0072-9
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DOI: https://doi.org/10.1007/s13738-012-0072-9