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A mononuclear, mixed (salicylato) (nicotinamide) complex of Zn(II) with penta- and hexa-coordination sites: a novel framework structure

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Abstract

The title compound, diaqua(bissalicylato-κO)(bisnicotinamide-κN)zinc(II)][bis(triaqua (monosalicylato-κO)(mononicotinamide-κN)zinc(II)salicylate, includes three Zn(II) ions, four nicotinamide ligands, six salicylate ligands and eight coordinated aqua ligands in the asymmetric unit in complex structure. The geometry around one of the Zn(II) ions is a slightly distorted octahedron, of which the equatorial plane is formed by two carboxylate oxygens and two aqua oxygens, while the axial positions are occupied by two pyridyl nitrogen atoms. The other Zn(II) ions adopt fivefold coordinations with one carboxylate oxygen atom from salicylate ligand, one N atom from nicotinamide ligand and three oxygen atoms from aqua ligands. In addition, there are two salicylate anions in the unit cell that are not coordinated. They provide charge balance as counter-ions in the complex framework.

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Acknowledgments

The authors wish to acknowledge the Faculty of Arts and Sciences, Ondokuz Mayıs University, Turkey, for the use of the Stoe IPDS-II diffractometer (purchased from Grant No. F279 of the University Research Fund).

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Arts and Sciences, Hitit University, 19000, Çorum, Turkey

    Dursun Ali Köse

  2. Department of Chemistry, Faculty of Sciences, Hacettepe University, 06532, Ankara, Turkey

    Ahmet Nedim Ay

  3. Department of Physics, Faculty of Arts and Sciences, Ondokuz Mayis University, Kurupelit, 55139, Samsun, Turkey

    Onur Şahin & Orhan Büyükgüngör

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  1. Dursun Ali Köse
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  2. Ahmet Nedim Ay
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  3. Onur Şahin
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  4. Orhan Büyükgüngör
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Correspondence to Dursun Ali Köse.

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Köse, D.A., Ay, A.N., Şahin, O. et al. A mononuclear, mixed (salicylato) (nicotinamide) complex of Zn(II) with penta- and hexa-coordination sites: a novel framework structure. J IRAN CHEM SOC 9, 591–597 (2012). https://doi.org/10.1007/s13738-012-0072-9

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