Skip to main content
Log in

Effects of Ho, Mn co-doping on ferroelectric fatigue of BiFeO3 thin films

  • Published:
Electronic Materials Letters Aims and scope Submit manuscript

Abstract

Ho, Mn, and Ho, Mn co-doped BiFeO3 thin films were deposited on Pt (100)/Ti/SiO2/Si substrates using solution gelation. The ferroelectric fatigue properties were clearly improved after doping with Ho and Mn. The doped BiFeO3 thin film displayed more strongly increased ferroelectric, leakage current, and fatigue properties compared with the pure BiFeO3 thin film. Thus, the improved performance of the BiFeO3 thin films depends on the structural transformation and reduced oxygen vacancy concentration. The present work provides a feasible approach to enhance the ferroelectric and fatigue properties of BiFeO3-based thin films.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J. Wang, J. B. Neaton, H. Zheng, V. Nagarajan, S. B. Ogale, B. Liu, D. Viehland, V. Vaithyanathan, D. G. Schlom, U. V. Waghmare, N. A. Spaldin, K. M. Rabe, M. Wuttig, and R. Ramesh, Science 299, 1719 (2003).

    Article  Google Scholar 

  2. D. C. Arnold, K. S. Knight, F. D. Morrison, and P. Lightfoot, Phys. Rev. Lett. 102, 027602 (2009).

    Article  Google Scholar 

  3. C. Ederer and N. A. Spaldin, Phys. Rev. B 71, 060401 (2005).

    Article  Google Scholar 

  4. W. Eerenstein, F. D. Morrison, J. Dho, M. G. Blamire, J. F. Scott, and N. D. Mathur, Science 307, 1203 (2005).

    Article  Google Scholar 

  5. W. Eerenstein, N. D. Mathur, and J. F. Scott, Nature 442, 759 (2006).

    Article  Google Scholar 

  6. D. Lebeugle, A. Mougin, M. Viret, D. Colson, and L. Ranno, Phys. Rev. Lett. 103, 257601 (2009).

    Article  Google Scholar 

  7. D. Lee, S. M. Yang, T. H. Kim, B. C. Jeon, Y. S. Kim, J. G. Yoon, H. N. Lee, S. H. Baek, C. B. Eom, and T. W. Noh, Adv. Mater. 24, 402 (2012).

    Article  Google Scholar 

  8. M. S. Bernardo, T. Jardiel, M. Peiteado, F. J. Mompean, M. A. Garcia, M. Villegas, and A. C. Caballero, Chem. Mater. 25, 1533 (2013).

    Article  Google Scholar 

  9. H. Ke, W. Wang, Y. B. Wang, Y. B. Xu, D. C. Jia, Z. Lu, and Y. Zhou, J. Alloys Compd. 509, 2192 (2011).

    Article  Google Scholar 

  10. F. Yan, M. O. Lai, L. Lu, and T. J. Zhu, J. Phys. Chem. C 114, 6994 (2010).

    Article  Google Scholar 

  11. Q. Ke, X. Lou, Y. Wang, and J. Wang, Phys. Rev. B 82, 024102 (2010).

    Article  Google Scholar 

  12. Z. Hu, M. Li, Y. Yu, J. Liu, L. Pei, J. Wang, X. L. Liu, B. F. Yu, and X. Z. Zhao, Solid State Commun. 150, 1088 (2010).

    Article  Google Scholar 

  13. G. L. Yuan, S. W. Or, H. L. W. Chan, and Z. G. Liu, J. Appl. Phys. 101, 024106 (2007).

    Article  Google Scholar 

  14. D. P. Dutta, B. P. Mandal, M. D. Mukadam, S. M. Yusuf, and A. K. Tyagi, Dalton Trans. 43, 7838 (2014).

    Article  Google Scholar 

  15. H. W. Jang, S. H. Baek, D. Ortiz, C. M. Folkman, C. B. Eom, Y. H. Chu, P. Shafer, R. Ramesh, V. Vaithyanathan and D. G. Schlom, Appl. Phys. Lett. 92, 062910 (2008).

    Article  Google Scholar 

  16. H. Naganuma, J. Miura, and S. Okamura, Appl. Phys. Lett. 93, 052901 (2008).

    Article  Google Scholar 

  17. K. Takahashi and M. Tonouchi, J. Magn. Magn. Mater. 310, 1174 (2007).

    Article  Google Scholar 

  18. Y. T. Li, H. G. Zhang, Q. Li, H. Liu, X. G Dong, W. W. Mao, C. L. Dong, S. L. Liu, X. A. Li, and S. Q. Wei, Mater. Lett. 87, 117 (2012).

    Article  Google Scholar 

  19. D. Rajasree, K. G. Gopal, and M. Kalyan, J. Appl. Phys. 111, 104115 (2012).

    Article  Google Scholar 

  20. M. K. Singh, H. M. Jang, S. Ryu, and M. H. Jo, Appl. Phys. Lett. 88, 042907 (2006).

    Article  Google Scholar 

  21. C. Beekman, A. A. Reijnders, Y. S. Oh, S. W. Cheong, and K. S. Burch, Phys. Rev. B 86, 020403 (2012).

    Article  Google Scholar 

  22. P. Hermet, M. Goffinet, J. Kreisel, and P. Ghosez, Phys. Rev. B 75, 220102 (2007).

    Article  Google Scholar 

  23. H. Fukumura, H. Harima, K. Kisoda, M. Tamada, Y. Noguchi, and M. Miyayama, J. Magn. Magn. Mater. 310, 367 (2007).

    Article  Google Scholar 

  24. A. Z. Simões, L. S. Cavalcante, F. Moura, E. Longo, and J. A. Varela, J. Alloys Compd. 509, 5326 (2011).

    Article  Google Scholar 

  25. H. Yang, Y. Q. Wang, H. Wang, and Q. X. Jia, Appl. Phys. Lett. 96, 012909 (2010).

    Article  Google Scholar 

  26. C. M. Raghavan, D. Do, J. W. Kim, W. J. Kim, and S. S. Kim, J. Am. Ceram. Soc. 95, 1933 (2012).

    Article  Google Scholar 

  27. W. Schottky, Naturwiss 26, 843 (1938).

    Article  Google Scholar 

  28. G. W. Pabst, L. W. Martin, Y. H. Chu, and R. Ramesh, Appl. Phys. Lett. 90, 072902 (2007).

    Article  Google Scholar 

  29. S. H. Lim, M. Murakami, J. H. Yang, S. Y. Young, J. Hattrick-Simpers, M. Wuttig, L. G. Salamanca-Riba, and I. Takeuchi, Appl. Phys. Lett. 92, 012918 (2008).

    Article  Google Scholar 

  30. H. Yang, Y. Q. Wang, H. Wang, and Q. X. Jia, Appl. Phys. Lett. 96, 012909 (2010).

    Article  Google Scholar 

  31. Y. Shuai, S. Zhou, D. Burger, M. Helm, and H. Schmidt, J. Appl. Phys. 109, 124117 (2011).

    Article  Google Scholar 

  32. J. G. Wu, G. Q. Kang, H. J. Liu, and J. Wang, Appl. Phys. Lett. 94, 172906 (2009).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Shifeng Zhao.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chen, J., Xing, W., Yun, Q. et al. Effects of Ho, Mn co-doping on ferroelectric fatigue of BiFeO3 thin films. Electron. Mater. Lett. 11, 601–608 (2015). https://doi.org/10.1007/s13391-015-5047-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13391-015-5047-4

Keywords

Navigation