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A DEMS Study of the Reduction of CO2, CO, and HCHO Pre-Adsorbed on Cu Electrodes: Empirical Inferences on the CO2RR Mechanism

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References

  1. Y. Hori, Mod Asp. Electrochem. 42, 89 (2008)

    CAS  Google Scholar 

  2. Y. Hori, H. Wakebe, T. Tsukamoto, O. Koga, Electrochim. Acta 39, 1833 (1994)

    Article  CAS  Google Scholar 

  3. K.P. Kuhl, T. Hatsukade, E.R. Cave, D.N. Abram, J. Kibsgaard, T.F. Jaramillo, J. Am. Chem. Soc. 136, 14107 (2014)

    Article  CAS  Google Scholar 

  4. K.P. Kuhl, E.R. Cave, D.N. Abram, T.F. Jaramillo, Energy Environ. Sci. 5, 7050 (2012)

    Article  CAS  Google Scholar 

  5. M. Gattrell, N. Gupta, A. Co, J. Electroanal. Chem. 594, 1 (2006)

    Article  CAS  Google Scholar 

  6. K.J.P. Schouten, Y. Kwon, C.J.M. van der Ham, Z. Qin, M.T.M. Koper, Chem. Sci. 2, 1902 (2011)

    Article  CAS  Google Scholar 

  7. C.W. Li, M.W. Kanan, J. Am. Chem. Soc. 134, 7231 (2012)

    Article  CAS  Google Scholar 

  8. F. Calle-Vallejo, M.T.M. Koper, Angew. Chem. 125, 7423 (2013)

    Article  Google Scholar 

  9. K.J.P. Schouten, E.P. Gallent, M.T.M. Koper, J. Electroanal. Chem. 716, 53 (2014)

    Article  CAS  Google Scholar 

  10. J.H. Baricuatro, C.B. Ehlers, K.D. Cummins, M.P. Soriaga, J.L. Stickney, Y.-G. Kim, J. Electroanal. Chem. 716, 101 (2014)

    Article  CAS  Google Scholar 

  11. Y.-G. Kim, M.P. Soriaga, J. Electroanal. Chem. 734, 7 (2014)

    Article  CAS  Google Scholar 

  12. Y.-G. Kim, J. H. Baricuatro, A. Javier, J. M. Gregoire, M. P. Soriaga, Langmuir, In press (2014).

  13. K.J.P. Schouten, Z. Qin, E.P. Gallent, M.T.M. Koper, J. Am. Chem. Soc. 134, 9864 (2012)

    Article  CAS  Google Scholar 

  14. H. Baltruschat, in Interfacial electrochemistry, ed. by A. Wieckowski (Marcel Dekker, New York, 1999), p. 577

    Google Scholar 

  15. H. Baltruschat, J. Am. Soc. Mass Spectrom. 15, 1693 (2004)

    Article  CAS  Google Scholar 

  16. J. Sanabria-Chinchilla, M.P. Soriaga, R. Bussar, H. Baltruschat, J. Appl. Electrochem. 36, 1253 (2006)

    Article  CAS  Google Scholar 

  17. J. Sanabria-Chinchilla, J.H. Baricuatro, M.P. Soriaga, F. Hernandez, H. Baltruschat, J. Coll. Interf. Sci. 314, 152 (2007)

    Article  CAS  Google Scholar 

  18. J. Sanabria-Chinchilla, Y.-G. Kim, X. Chen, D. Li, H. Baltruschat, M.P. Soriaga, Mod. Asp. Electrochem 44, 275 (2010)

    Google Scholar 

  19. R. Crovetto, J. Phys. Chem. Ref. Data 20, 575 (1991)

    Article  CAS  Google Scholar 

  20. S. Vollmer, G. Witte, C. Woll, Catal. Lett. 77, 97 (2001)

    Article  CAS  Google Scholar 

  21. R.A. Hadden, H.D. Vandervell, K.C. Waugh, G. Webb, Catal. Lett. 1, 27 (1988)

    Article  CAS  Google Scholar 

  22. J.R.B. Gomes, J.A.N.F. Gomes, F. Illas, J. Mol. Catal. A 170, 187 (2001)

    Article  CAS  Google Scholar 

  23. A. Forni, G. Wiesenekker, E.J. Baerends, G.F. Tantardini, Int. J. Quantum Chem. 52, 1067 (1994)

    Article  CAS  Google Scholar 

  24. A.A. Peterson, F. Abild-Pedersen, F. Studt, J. Rossmeisl, J.K. Norskov, Energy Environ. Sci. 3, 1311 (2010)

    Article  CAS  Google Scholar 

  25. A.A. Peterson, J.K. Norskov, J. Phys. Chem. Lett. 3, 251 (2012)

    Article  CAS  Google Scholar 

  26. X. Nie, M.R. Esopi, M.J. Janik, A. Asthagiri, Angew. Chem. Int. Ed. 52, 2459 (2013)

    Article  CAS  Google Scholar 

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Acknowledgments

This material is based upon work performed by the Joint Center for Artificial Photosynthesis, a DOE Energy Innovation Hub, supported through the Office of Science of the US Department of Energy under Award No. DE-SC0004993.

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Authors and Affiliations

  1. Division of Chemistry and Chemical Engineering, Joint Center for Artificial Photosynthesis, California Institute of Technology, Pasadena, CA, 91125, USA

    Alnald Javier, Brian Chmielowiec, Jean Sanabria-Chinchilla, Youn-Geun Kim, Jack H. Baricuatro & Manuel P. Soriaga

  2. Department of Chemistry, Texas A&M University, College Station, TX, 77843, USA

    Manuel P. Soriaga

Authors
  1. Alnald Javier
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  2. Brian Chmielowiec
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  3. Jean Sanabria-Chinchilla
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  4. Youn-Geun Kim
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  5. Jack H. Baricuatro
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  6. Manuel P. Soriaga
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Correspondence to Manuel P. Soriaga.

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Javier, A., Chmielowiec, B., Sanabria-Chinchilla, J. et al. A DEMS Study of the Reduction of CO2, CO, and HCHO Pre-Adsorbed on Cu Electrodes: Empirical Inferences on the CO2RR Mechanism. Electrocatalysis 6, 127–131 (2015). https://doi.org/10.1007/s12678-015-0246-1

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