Abstract
In this study, the recovery of ruthenium from spent bath solutions via cementation reaction with zinc powder was investigated. Studied parameters included the quantity of zinc, reaction temperature, reaction time and sodium chloride additions to understand their effects on the reaction. Tests were performed in a temperature controlled water-bath with temperatures between 20 and 70 °C at atmospheric pressure. Furthermore, in order to determine activation energy of cementation reaction, several mathematical kinetic models were used and the activation energy, which was calculated from best fit, was found to be 12.48 kJ/mol. Addition of sodium chloride to the solution greatly accelerated the cementation reaction, in that, more the addition of sodium chloride, the better was the precipitation efficiency. In the absence of sodium chloride at 25 °C a percentage of ruthenium recovery was below 75% whereas 1000 mg sodium chloride addition at 65 °C ensured a percentage of ruthenium recovery more than 95%. This corresponded to more than about 28% increase.
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References
Swain P, Mallika C, Srinivasan R, Mudali U K, and Natarajan R, J Radioanal Nucl Chem 298 (2013) 781.
Rao C R K, and Trivedi D C, Coordin Chem Rev 249 (2005) 613.
Hunt L, and Lever F, Platin Met Rev 13 (1969) 126.
Jones T, Met Finish 99 (2001) 121.
Benguerel E, Demopoulos G, and Harris G, Hydrometallurgy 40 (1996) 135.
Xiao Z, and Laplante A, Miner Eng 17 (2004) 961.
Habashi F, Hydrometallurgy 79 (2005) 15.
Jackson E, Miner Eng 9 (1996) 469.
Panigrahi S, Dash T, Nathsarma K C, and Sarangi K, Sep Sci Technol 49 (2014) 545.
Qadeer R, Colloids Surf Physicochem Eng Aspects 293 (2007) 217.
Colica G, Caparrotta S, and De Philippis R, Appl Microbiol Biotechnol 95 (2012) 381.
Mimura H, Ohta H, Akiba K, and Onodera Y, J Nucl Sci Technol 39 (2002) 655.
Zachariasen H, and Beamish F, Anal Chem 34 (1962) 964.
Younesi S R, Alimadadi H, Alamdari E K, and Marashi S P H, Hydrometallurgy 84 (2006) 155.
Ryzhov A G, and Sushchev A V, Tsvetnye Metally 11 (1985) 25.
Zeytuncu B, Morcali M H, Celik O H, and Yucel O, Investigation of Optimum Cementation Conditions of Ruthenium with Experimental Design in EPD Congress 2013, Wiley, New York (2013).
Aktas S, Hydrometallurgy 106 (2011) 71.
Aktas S, Int J Miner Process 114 (2012) 100.
Aktas S, Can Metall Q 47 (2008) 37.
Aktas S, and Morcali M H, Miner Metall Process 28 (2011) 198.
Aktas S, Morcali M H, and Yucel O, Can Metall Q 49 (2010) 147.
Habashi F, Principles of Extractive Metallurgy, Vol. 1, CRC Press, Boca Raton (1969).
Levenspiel O, Chemical Reaction Engineering, Vol. 2, Wiley, New York (1972).
Petrucci R H, Herring F G, and Madura J D, General Chemistry: Principles and Modern Applications, Prentice Hall, Canada (2010).
Acknowledgements
The authors thank Marmara University for supporting the BAPKO project No: FEN-A-150513-0165 and FEN-E-080415-0110. The authors would also like to thank MC 365 laboratory persons at Marmara University for useful and helpful comments to improve the quality of the present work.
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Aktas, S., Morcali, M.H., Aksu, K. et al. Recovery of Ruthenium Via Zinc in the Presence of Accelerator. Trans Indian Inst Met 71, 697–703 (2018). https://doi.org/10.1007/s12666-017-1202-y
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DOI: https://doi.org/10.1007/s12666-017-1202-y