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Silica Nanoparticles with Proton Donor and Proton Acceptor Groups: Synthesis and Aggregation

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Abstract

The effects of precursor structure and polycondensation conditions on the properties of hybrid nanoparticles synthesized from organo-trimethoxysilanes were studied. Hybrid nanoparticles containing groups capable of forming hydrogen bonds were synthesized from functional derivatives of 3-aminopropyltrimethoxysilane. For the synthesis of phenylurea-functionalized organosilica nanoparticles different approaches to nanoparticle preparation were used. It was shown that the nature of the functional groups (proton-donor or proton-acceptor) affects the aggregation of silica nanoparticles. Also, the difference in behavior of nanoparticles prepared using surface modification and polycondensation was demonstrated for different pH, ionic strength and solvent polarity. As a result, by changing the pH of the solutions, it is possible to shift the aggregation pattern of these nanoparticles, such as the size of the initially formed aggregates.

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Authors and Affiliations

  1. A. M. Butlerov Chemical Institute, Kazan (Volga Region) Federal University, 420008, Kazan, Kremlevskaya 18, Russian Federation

    Vladimir V. Gorbachuk, Luidmila S. Yakimova, Olga A. Mostovaya, Igor S. Antipin, Alexandr I. Konovalov & Ivan I. Stoikov

  2. Zavoisky Physical−Technical Institute, 420029, Kazan, Sibirsky Tract, 10/7, Russian Federation

    Dmitry A. Bizyaev & Anastas A. Bukharaev

  3. Department of Chemistry, University of Utah, Salt Lake City, UT, 84112, USA

    Ilya Zharov

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  1. Vladimir V. Gorbachuk
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  2. Luidmila S. Yakimova
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  3. Olga A. Mostovaya
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  4. Dmitry A. Bizyaev
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  5. Anastas A. Bukharaev
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  6. Igor S. Antipin
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  7. Alexandr I. Konovalov
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  8. Ilya Zharov
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  9. Ivan I. Stoikov
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Correspondence to Ilya Zharov or Ivan I. Stoikov.

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Gorbachuk, V.V., Yakimova, L.S., Mostovaya, O.A. et al. Silica Nanoparticles with Proton Donor and Proton Acceptor Groups: Synthesis and Aggregation. Silicon 3, 5–12 (2011). https://doi.org/10.1007/s12633-011-9077-8

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  • DOI: https://doi.org/10.1007/s12633-011-9077-8

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