Skip to main content
Log in

Control of the precipitation of TiN inclusions in gear steels

  • Published:
International Journal of Minerals, Metallurgy, and Materials Aims and scope Submit manuscript

Abstract

In the 20CrMnTi steel production process, the nitrogen content increased by 19 × 10−6 and 29 × 10−6, respectively, during ladle furnace (LF) refining and during the casting process from ladle to tundish. The protective casting is the key to decrease the N content. The results of thermodynamic calculations and a growth kinetics investigation show that TiN formation occurs only when the solidification fraction is greater than 0.533 under the controlled conditions used in this study for the manufacture of 20CrMnTi steel; the radius of TiN particles decreases as the Ti and N contents decrease and as the cooling rate increases. Furthermore, the theory of austenite grains controlled by second-phase particles was analyzed. The elemental analysis results showed that the Ti content was controlled at 0.04wt%–0.06wt% and the N content decreased to 0.005wt%, which satisfy the requirements for grain refinement but can also effectively prevent the precipitation of TiN inclusions in 20CrMnTi steel.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. T. Uesugi, Production of high-carbon chromium bearing steel in vertical type continuous caster, Trans. Iron Steel Inst. Jpn., 26(1986), No.7, p. 614.

    Article  Google Scholar 

  2. M. Q. Yu, Z.Z. Wang, M.H. Xu, and X.J. Chen, Refining process of superclean bearing steel, Iron Steel, 41(2009), No.9, p. 26.

    Google Scholar 

  3. M. W. Zhou and H. Yu, Effects of precipitates and inclusions on the fracture toughness of hot rolling X70 pipeline steel plates, Int. J. Miner. Metall. Mater., 19(2012), No.9, p.805.

    Article  Google Scholar 

  4. J. Y. Cogne, B. Heritier, and J. Monnot, Cleanness and fatigue life of bearing steel, [in] Clean Steel 3rd Proceedings of Conference, Balatonfured, Hungary, 1986, p. 26.

    Google Scholar 

  5. J. Fu, J. Zhu, L. Di, F.S. Tong, D.L. Liu, and Y.L. Wang, Study on the precipitation behavior of TiN in the microalloyed steels, Acta. Metall. Sin., 36(2000), No.8, p. 801.

    Google Scholar 

  6. D. G. Zhou, J. Fu, X.C. Chen, and J. Li, Precipitation behavior of TiN in bearing steel, J. Mater. Sci. Technol., 19(2003), No.2, p. 184.

    Article  Google Scholar 

  7. X. N. Yang, G.G. Cheng, M.L. Wang, Y.L. Li, Y.G. Wang, and P. Zhao, Precipitation and growth of titanium nitride during solidification of clean steel, J. Univ. Sci. Technol. Beijing, 10(2003), No.5, p. 24.

    Google Scholar 

  8. J. J. Park, Y.S. Jeong, I.K. Hong, W.Y. Cha, D.S. Kim, and Y.Y. Lee, Thermodynamics of TiN formation in Fe-Cr melts, ISIJ Int., 45(2005), No.8, p. 1106.

    Article  Google Scholar 

  9. H. Y. Liu, H.L. Wang, L. Li, J.Q. Zheng, Y.H. Li, and X.Y. Zeng, Investigation of Ti inclusions in wire cord steel, Ironmaking Steelmaking, 38(2011), No.1, p. 53.

    Article  Google Scholar 

  10. Y. Maehara, K. Yasumoto, H. Tomono, T. Nagamichi, and Y. Ohmori, Surface cracking mechanism of continuously cast low carbon low alloy steel slabs, Mater. Sci. Technol., 6(1990), No.9, p. 793.

    Article  Google Scholar 

  11. Y. N. Wang, Y.P. Bao, M. Wang, and L.C. Zhang, Precipitation and control of BN inclusions in 42CrMo steel and their effect on machinability, Int. J. Miner. Metall. Mater., 20(2013), No.9, p. 842.

    Article  Google Scholar 

  12. W. J. Liu, S. Yue, and J.J. Jonas, Characterization of Ti carbosulfide precipitation in Ti microalloyed steels, Matall. Trans. A, 20(1989), No.10, p. 1907.

    Article  Google Scholar 

  13. H. Goto, K.I. Miyazawa, K.I. Yamaguchi, S. Ogibayashi, and K. Tanaka, Effect of cooling rate on oxide precipitation during solidification of low carbon steels, ISIJ Int., 34(1994), No.5, p. 414.

    Article  Google Scholar 

  14. P. Maugis and M. Gouné, Kinetics of vanadium carbonitride precipitation in steel: a computer model, Acta Mater., 53(2005), No.12, p. 3359.

    Article  Google Scholar 

  15. H. Goto, K.I. Miyazawa, W. Yamada, and K. Tanaka, Effect of cooling rate on composition of oxides precipitated during solidification of steels, ISIJ Int., 35(1995), No.6, p. 708.

    Article  Google Scholar 

  16. T. Gladman, The Physical Metallurgy of Microalloyed Steels, The Institute of Materials, London, 1997, p. 136.

    Google Scholar 

  17. K. J. Irvine, F.B. Pickering, and T. Gladman, Grain refined C-Mn steel, J. Iron Steel Inst., 25(1967), No.2, p. 161.

    Google Scholar 

  18. K. Narita, Physical chemistry of the groups IVa(Ti, Zr), Va(V, Nb, Ta) and the rare earth elements in steel, Trans. ISIJ, 15(1975), No. 2, p. 145.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yan-ping Bao.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ma, Wj., Bao, Yp., Zhao, Lh. et al. Control of the precipitation of TiN inclusions in gear steels. Int J Miner Metall Mater 21, 234–239 (2014). https://doi.org/10.1007/s12613-014-0900-2

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12613-014-0900-2

Keywords

Navigation