Abstract
Metacarbonate deposit occurring in Emiworo area, northcentral Nigeria are low grade marble associated with Proterozoic basement complex rocks. Integrated inorganic geochemical, physical and thermal characteristics of the samples were investigated with the aim of revealing their economic viability. The phase characteristics of the metacarbonate show that dolomite is the dominant phase with calcite and phlogopite as minor phases, while silicates, graphites and pyrites constitute the accessories. Reactivity of the quicklime measured after calcination at different temperatures revealed that only the quicklime produced in 1 hour at 950°C and 1000°C was found to be reactive. Physical properties and comparative data show that the Emiworo marble displays lower water absorption and higher compressive strength, loss on ignition and bulk specific gravity, compared to other metacarbonate rocks occurring in other parts of Nigeria and elsewhere. These attributes makes the deposit suitable for many conventional industrial applications.
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References
Abdullateef, J.O., Elueze, A., and Ahmed II, J. (2014) Geochemistry and economic potential of marble from Obajana, north central, Nigeria. Advan. Appld. Sci. Res., v.5, no.3, pp.146–151.
Akinola, O.O. and Olaolorun, O.A. (2012) Lithogeochemistry and industrial appraisal of Igbetti marble, South Western Nigeria: African Jour. Sci., Tech., Innovat. Develop., v.4 (2), pp. 173–187.
Anani, A. (1984) Applications of dolomite: Indian Minerals, no.205, p.45.
ASTMC97–02 (2005) Standard Test Method for Absorption and Build Specific Gravity of Dimension Stone, Annual Book of ASTM Standard: ASTM Internat., v.04 (1), pp. 82–102.
Beruto, D., Vecchiattini, R., and Giordani, M. (2003) Solid products and ratelimiting step in the thermal half decomposition of natural dolomite in a CO2 (g) atmosphere: Thermochimica Acta, v.405 (2), pp. 183–194.
Bilgin, N., Yeprem, H. A., Arslan, S., Bilgin, A., Günay, E., and Maroglu, M., (2012) Use of waste marble powder in brick industry: Construction and Building Materials, v.29, pp.449–457.
Blanco, A., D’Elia, M., Licchelli, D., Orofino, V. and Fonti, S. (2005) The infrared spectroscopy of biotic and abiotic minerals: its relevance to Mars studies: Mem. della Soc. Astron. Italiana Supplem., v.6, pp.72.
Boynton, R. (1980) Chemistry and Technology of Lime and Limestone. Wiley Interscience Publ., London.
Caby, R. (1989) Precambrian terranes of Benin-Nigeria and northeast Brazil and the Late Proterozoic south Atlantic fit. Geol. Soc. Amer. Spec. Papers, v.230, pp.145–158.
Davou, D., and Ashano, E. (2009) The geochemical chararateristics of the marble deposits east of Federal Capital Territory (FCT), Nigeria. Global Jour. Geol. Sci., v.7 (2), pp. 189–198.
Elueze, A., and Okunlola, O. (2003) Petrochemical and Petrogenetic Characteristics of Metasedimentary rocks of Lokoja-Jakura Schist Belt, Central Nigeria in Elueze A.A. Jour. Min. Geol., v.39 (1), pp. 21–27.
Emefurieta, W., and Ekuajemi, V. (1995) Lime Products and Economic Aspects of Igbeti, Ososo and Jakura Marble Deposit in SW-Nigeria. Jour. Min. Geol., v.31 (1), pp. 79–89.
Emofurieta, W., Imeokparia, E., and Ayuk, M. (1995) Geochemistry of marbles and calc-silicate rocks in the Igarra schist belt, south-west Nigeria: African Jour. Sci. Tech., Series B, Science, v.7 (2), pp. 17–26.
Ephraim, B.E. (2011) Compositional appraisal and quality implications of a metacarbonate deposit occurring in parts of southeastern Nigeria Presoja sestave in njenega vpliva na kakovost metakarbonatne kamnine iz nahajališèa v jugovzhodni Nigeriji: RMZ–Materials and Geoenvironment, v.58 (4), pp. 405–420.
Fall, W., Allan, S., and Shulman, H. (2011) Rapid limestone calcination using MicrowaveAssist Technology, In: Proc. 35rd Internat. Conf. & Exposition on Advanced Ceramics and Composites ICACC-S8–023-2011.
Ferré, E., Gleizes, G., and Caby, R. (2002) Obliquely convergent tectonics and granite emplacement in the Trans-Saharan belt of Eastern Nigeria: a synthesis. Precambrian Res., v.114 (3), pp. 199–219.
Fitches, W., Ajibade, A., Egbuniwe, I., Holt, R. and Wright, J. (1985) Late Proterozoic schist belts and plutonism in NW Nigeria: Jour. Geol. Soc., v. 142(2), pp.319–337.
Gunasekaran, S., and Anbalagan, G. (2007) Spectroscopic study of phase transitions in dolomite mineral: Jour. Raman Spectros., v.38 (7), pp. 846–852.
Harben, P., and Kuzvart, M. (1996) Carbonate Rocks: Marble. A Global Geology: Industrial Minerals Inform. Ltd., Metal Bulletin PLC, London.
Harrison, D. (1993) Industrial minerals laboratory manual: Limestones. UK. BGS, 111p.
Hazell, J. (1958) The Jakura marble, Kabba Province. Rec. Geol. Surv. Nigeria, v.1956, pp.38–45.
Howse, A. E. (1994) Industrial potential of the silver mountain marble deposit, western Newfoundland: Current Research, Newfoundland Department of Mines and Energy, Geological Survey Bruvch, Report, pp.94–91.
Klein, C., Dutrow, B., and Dana, J.D. (2002) Manual of Mineral Science, Wiley New York.
Leiss, B., and Weiss, T. (2000) Fabric anisotropy and its influence on physical weathering of different types of Carrara marbles: Jour. Struct. Geol., v.22 (11), p. 1737–1745.
Moropoulou, A., Bakolas, A., and Aggelakopoulou, E. (2001) The effects of limestone characteristics and calcination temperature to the reactivity of the quicklime: Cement and Concrete Res., v.31 (4), pp. 633–639.
Oates, J.A. (2008) Lime and limestone: chemistry and technology, production and uses, John Wiley & Sons.
Obaje, N. G. (2009) Geology and mineral resources of Nigeria, Springer Science & Business Media.
Obara, B., and Koušníková, A. (2007) Utilisation of the image analysis method for the detection of the morphological anisotropy of calcite grains in marble: Computational Geosciences, v.11 (4), pp. 275–281.
Ofulume, A., Orazulike, D., and Haruna, I., 2009, An assessment of the calcination characteristics of the mfamosing limestone for quality commercial lime production: Global Jour. Geol. Sci., v.7 (2), pp. 177–180.
Okonkwo, C. T., and Ganev, V.Y. (2015) Geochemistry and geochronology of orthogneisses in Bode Saadu area, southwestern Nigeria and their implications for the Palaeoproterozoic evolution of the area. Jour. African Earth Sci., v.109, pp.131–142.
Okunlola, O. (2001) Geological and compositional investigation of Precambrian marble Bodies and associated rocks in the Burum and Jakura areas, Nigeria: Unpublished Ph. D. Thesis, University of Ibadan, 251p.
Onimisi, M., Obaje, N., and Daniel, A. (2013) Field geologic occurrence and petrographic characteristics of precambrian marble body in Itobe area, Central Nigeria: Advan. Appld. Sci. Res., v.4 (5), pp. 58–71.
Potgieter, J. P. S., De Wall D. (2003) An empirical study of factors influencing lime slaking Part II: lime constituents and water composition: Water South Africa, no.29, pp.157–160.
Potgieter, J. H.P.S., Moja SS, Mulaba-Bfubiandi A. (2002) The standard reactivity test as a measurement of lime’s quality. Jour. South African Inst. of Mining and Metallurgy, no.102, pp.67–69.
Qadhi, T.M. (2008) Testing Jabal Farasan marble deposit for multiple industrial applications: Arabian Jour. Sci. Engg., v.33 (1), pp. 79–98.
Rahaman, M., Emofurieta, W., and Caen-Vachette, M. (1983) The potassicgranites of the Igbeti area: further evidence of the polycyclic evolution of the Pan-African belt in southwestern Nigeria. Precambrian Res., v.22 (1), pp. 75–92.
Ramezanianpour, A.A., Ghiasvand, E., Nickseresht, I., Mahdikhani, M. and Moodi, F. (2009) Influence of various amounts of limestone powder on performance of Portland limestone cement concretes: Cement and Concrete Composites, v.31 (10), pp. 715–720.
Siegesmund, S., Ullemeyer, K., Weiss, T., and Tschegg, E. (2000) Physical weathering of marbles caused by anisotropic thermal expansion: Internat. Jour. Earth Sci., v.89 (1), pp. 170–182.
Turner, D. (1983) Upper Proterozoic schist belts in the Nigerian sector of the Pan-African province of West Africa: Precambrian Res., v.21, pp.55–79.
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Jimoh, O.A., Ariffin, K.S., Hussin, H.B. et al. Compositional appraisal and quality implication of Emiworo metacarbonate deposit in Central Nigeria. J Geol Soc India 89, 413–418 (2017). https://doi.org/10.1007/s12594-017-0623-x
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DOI: https://doi.org/10.1007/s12594-017-0623-x