Skip to main content
Log in

Effect of Strontium and Magnesium Additions on the Microstructure and Mechanical Properties of Al–12Si Alloys

  • Published:
Metals and Materials International Aims and scope Submit manuscript

Abstract

In this study, a binary Al–12Si, eight ternary Al–12Si–Sr, and six quaternary Al–12Si–0.1Sr–(0.2–1)Mg alloys were produced by permanent mold casting. It was observed that microstructure of the binary alloy consisted of the phases of aluminum rich α grains (dendrites), primary silicon, plate like β and eutectic Al–Si containing needle like silicon particles. The ternary alloys have fine and globular (modified) eutectic silicon particles and higher volume fraction of α (Al) dendrites than binary alloys. They also contained Al4Sr phase after 0.02 wt% Sr, in addition to the phases in the binary alloy. This phase got coarse when the strontium ratio exceeded 0.1%. It was observed that the plate like β phase seen in the binary alloys transformed into the fibrous form δ phase in the ternary alloys. Magnesium addition resulted in transformation of δ phase into script like π phase, and the formation of lamellar like Mg2Si phase when the ratio of it in the quaternary alloys reached the 0.6 wt%. The lamellar like form of Mg2Si phase changed to Chinese-script type after the 0.6 wt% Mg. The results showed that hardness, yield and tensile strength of the Al–12Si–Sr alloys increased with increasing strontium content up to 0.1 wt%. The results also showed that hardness of the quaternary alloys increased with increasing magnesium content, while yield and tensile strength increased only up to 0.6 wt% Mg.

Graphic Abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14
Fig. 15

Similar content being viewed by others

References

  1. S.K. Shaha, F. Czerwinski, W. Kasprzak, J. Friedman, D.L. Chen, Int. J. Fatigue 70, 383–394 (2015)

    CAS  Google Scholar 

  2. A.M.A. Mohamed, F.H. Samuel, S. Al Kahtani, Mater. Sci. Eng. A-Struct. 577, 64–72 (2013)

    CAS  Google Scholar 

  3. M. Tebib, A.M. Samuel, F. Ajersch, X.G. Chen, Mater. Charact. 89, 112–123 (2014)

    CAS  Google Scholar 

  4. C.Y. Jeong, Mater. Trans. 54(4), 588–594 (2013)

    CAS  Google Scholar 

  5. K.G. Basavakumar, P.G. Mukunda, M. Chakraborty, Int. J. Mater. Res. 99(8), 900–906 (2008)

    CAS  Google Scholar 

  6. J.Y. Hwang, H.W. Doty, M.J. Kaufman, Mater. Sci. Eng. A-Struct. 488(1–2), 496–504 (2008)

    Google Scholar 

  7. A.K. Dahle, K. Nogita, S.D. McDonald, C. Dinnis, L. Lu, Mater. Sci. Eng. A-Struct. 413–414, 243–248 (2005)

    Google Scholar 

  8. Y.H. Cho, H.-C. Lee, K.H. Oh, A.K. Dahle, Mater. Sci. Eng. A-Struct. 39(10), 2435–2448 (2008)

    Google Scholar 

  9. M. De Giovanni, J.A. Kaduk, P. Srirangam, JOM 71(1), 426–434 (2019)

    Google Scholar 

  10. M. Zarif, B. Mckay, P. Schumacher, Metall. Mater. Trans. A 42(6), 1684–1691 (2011)

    CAS  Google Scholar 

  11. H. Liao, W. Huang, Q. Wang, F. Jia, J. Mater. Sci. Technol. 30(2), 146–153 (2014)

    CAS  Google Scholar 

  12. H.S. Kang, W.Y. Yoon, K.H. Kim, M.H. Kim, Y.P. Yoon, Mater. Sci. Eng. A-Struct. 404(1–2), 117–123 (2005)

    Google Scholar 

  13. S. Ji, D. Watson, Z. Fan, M. White, Mater. Sci. Eng. A-Struct. 556, 824–833 (2012)

    CAS  Google Scholar 

  14. K. Wang, H.Y. Jiang, Q.D. Wang, W.J. Ding, Mater. Sci. Eng. A-Struct. 666, 264–268 (2016)

    CAS  Google Scholar 

  15. I. Alfonso, C. Maldonado, G. Gonzalez, A. Bedolla, J. Mater. Sci. 41(7), 1945–1952 (2006)

    CAS  Google Scholar 

  16. C.H. Caceres, A. Blake, Phys. Status Solidi. 194(1), 147–158 (2002)

    CAS  Google Scholar 

  17. S. Nafisi, D. Emadi, R. Ghomashchi, Mater. Sci. Technol. 24(6), 718–724 (2008)

    CAS  Google Scholar 

  18. Q.G. Wang, C.J. Davidson, J. Mater. Sci. 36(3), 739–750 (2001)

    CAS  Google Scholar 

  19. C.H. Caceres, C.J. Davidson, J.R. Griffiths, Q.G. Wang, Metall. Mater. Trans. A 30(10), 2611–2618 (1999)

    Google Scholar 

  20. S. Haro-Rodríguez, R.E. Goytia-Reyes, D.K. Dwivedi, V.H. Baltazar-Hernández, H. Flores-Zúñiga, M.J. Pérez-López, Mater. Des. 32(4), 1865–1871 (2011)

    Google Scholar 

  21. D. Kevorkov, M. Medraj, M. Aljarrah, J. Li, E. Essadiqi, P. Chartrand, C. Fuerst, J. Metall. 2014, 1–6 (2014)

    Google Scholar 

  22. X. Cao, J. Campbell, Mater. Trans. 47(5), 1303–1312 (2006)

    CAS  Google Scholar 

  23. W. Khalifa, F.H. Samuel, J.E. Gruzleski, Metall. Mater. Trans. A 34(13), 807–825 (2003)

    Google Scholar 

  24. B. Markoli, S. Spaič, F. Zupanič, Aluminium 80, 84–88 (2004)

    CAS  Google Scholar 

  25. S. Kores, M. Vončina, B. Kosec, J. Medved, Metalurgija 51(2), 216–220 (2012)

    CAS  Google Scholar 

  26. E. Samuel, A.M. Samuel, H.W. Doty, S. Valtierra, F.H. Samuel, Int. Cast. Met. J. 27(2), 107–114 (2014)

    CAS  Google Scholar 

  27. Y.L. Liu, S.B. Kang, H.W. Kim, Mater. Lett. 41(6), 267–272 (1999)

    CAS  Google Scholar 

  28. W. Jiang, X. Xu, Y. Zhao, Z. Wang, C. Wu, D. Pan, Z. Meng, Mater. Sci. Eng. A-Struct. 721, 263–273 (2018)

    CAS  Google Scholar 

  29. M. Tahta, M. Emamy, X. Cao, J. Campbell, in Materials Science Research Trends, ed. by L. V. Olivante (Nova Science Publishers, Inc, New York, 2008), p. 251

  30. P. Srirangam, S. Chattopadhyay, A. Bhattacharya, S. Nag, J. Kaduk, S. Shankar, R. Banerjee, T. Shibata, Acta Mater. 65, 185–193 (2014)

    CAS  Google Scholar 

  31. ASM International Handbook Committee, Alloy Phase Diagrams (ASM International, Materials Park, 2018)

    Google Scholar 

  32. C. Xu, F. Wang, H. Mudassar, C. Wang, S. Hanada, W. Xiao, C. Ma, J. Mater. Eng. Perform. 26(4), 1605–1613 (2017)

    CAS  Google Scholar 

  33. H. Liao, Y. Sun, G. Sun, Mater. Sci. Eng. A-Struct. 335(1–2), 62–66 (2002)

    Google Scholar 

  34. J. Campbell, M. Tiryakioğlu, Mater. Sci. Technol. 26(3), 262–268 (2010)

    CAS  Google Scholar 

  35. K. Nogita, S.D. McDonald, A.K. Dahle, Mater. Trans. 44(4), 692–695 (2003)

    CAS  Google Scholar 

  36. L. Liu, A.M. Samuel, F.H. Samuel, H.W. Doty, S. Valtierra, J. Mater. Sci. 39(1), 215–224 (2004)

    CAS  Google Scholar 

  37. A. Kósa, Z. Gácsi, J. Dúl, Mater. Sci. Eng. 37(2), 43–50 (2012)

    Google Scholar 

  38. E. Tan, B. Ögel, Turkish J. Eng. Env. Sci. 31(1), 53–60 (2007)

    CAS  Google Scholar 

  39. Y. Kaygısız, Dicle Üniversitesi Mühendislik Dergisi 8(4), 723–731 (2017)

    Google Scholar 

  40. M. Alipour, M. Azarbarmas, F. Heydari, M. Hoghoughi, M. Alidoost, M. Emamy, Mater. Des. 38, 64–73 (2012)

    CAS  Google Scholar 

  41. T. Savaşkan, A.P. Hekimoğlu, Mater. Sci. Eng. A-Struct. 603, 52–57 (2014)

    Google Scholar 

  42. S.G. Shabestari, Mater. Sci. Eng. A-Struct. 383(2), 289–298 (2004)

    Google Scholar 

  43. K.A. Abuhasel, M.F. Ibrahim, E.M. Elgallad, F.H. Samuel, Mater. Des. 91, 388–397 (2016)

    CAS  Google Scholar 

  44. Z. Wu, W.A. Curtin, Nature 526(7571), 62–67 (2015)

    CAS  Google Scholar 

  45. G.H. Zhang, J.X. Zhang, B.C. Li, W. Cai, Prog. Nat. Sci. Mater. 21, 380–385 (2011)

    Google Scholar 

  46. C.H. Caceres, J.R. Griffiths, Acta Mater. 44(1), 25–33 (1996)

    CAS  Google Scholar 

  47. M.G. Mueller, M. Fornabaio, G. Zagar, A. Mortensen, Acta Mater. 105, 165–175 (2016)

    CAS  Google Scholar 

  48. C.L. Xu, H.Y. Wang, F. Qiu, Y.F. Yang, Q.C. Jiang, Mater. Sci. Eng. A-Struct. 417(1–2), 275–280 (2006)

    Google Scholar 

Download references

Acknowledgements

This work was supported by Research Fund of the Recep Tayyip Erdoğan University. Project No. FYL-2016-685.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Ali Paşa Hekimoğlu.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Hekimoğlu, A.P., Çalış, M. & Ayata, G. Effect of Strontium and Magnesium Additions on the Microstructure and Mechanical Properties of Al–12Si Alloys. Met. Mater. Int. 25, 1488–1499 (2019). https://doi.org/10.1007/s12540-019-00429-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12540-019-00429-6

Keywords

Navigation