Abstract
Jordan is a country rich in clays of different origins. Clays of industrial importance are found in different stratigraphic units from Paleozoic to Cenozoic. The most potential clay minerals for industrial use are kaolinite, bentonite, and palygorskite. Other minerals as volkonskoite, illite/smectite, and smectite/kaolinite (black mud of the Dead Sea) are also common. The occurrence, nature, character, and economic importance of the different clay minerals in addition to problematic clays are given in this review. A recently novel geopolymerization process was developed to produce building materials (geopolymers) using Jordanian kaolinite. The products could be used as low-cost construction materials for green housing. They are characterized by high strength, high heat resistance, low production cost, low energy consumption, and low CO2 emissions. Volkonskoite areas (Cr-rich smectite) of Jordan can serve as natural analogues of a cementitious repository. Smectites are the most safety-critical components of the engineered barrier system for the disposal concepts developed for many types of radioactive waste (radwaste).
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References
Abdel-Fattah A, Khoury H (2001) Textural, mineralogical, and geochemical characterization of the Dead Sea black mud and its relation to the mud’s curative properties. Freiberg Forschungshefte C494:35–52
Abu Ajamieh M, Bender F, Eicher R (1988) Natural resources in Jordan. Natural Resources Authority, Amman 224p
Abu Dayyeh B (1993) Geology, mineralogy, geochemistry and industrial applications of the clay deposits from wadi Musa-Petra area, S. Jordan. Unpublished M.Sc.thesis University of Jordan,Amman.
Abu Halimah K (1993) Mineraloy, chemistry and industrial studies of Al-Yamaniyya clay deposits in Aqaba area. Unpublished M.Sc. thesis, The University of Jordan, Amman.
Al Delami M (1992) Distribution and characterization of the upper Jurassic of Arda area and its industrial importance. Unpublished M.Sc. thesis, The University of Jordan, Amman.
Al Momani T (2000) Characterization, industrial utilization and environmental impact of the Hiswa clay deposits, south Jordan, Unpublished Ph. D. thesis, the University of Jordan, Amman.
Al Omariv Y (1995) Mineralogical and engineering properties of clayey beds at failure areas along Irbid-Jerash-Amman-Dead Sea high ways. Unpublished M.Sc. thesis, The University of Jordan, Amman.
Al’ali J (1993) Exploration for bentonite and other minerals in Azraq depression. Natural Resources Authority,Amman, 4 volumes, 215p.
Al’ali J (1996) Bentonite in Jordan (In Arabic). Natural Resources Authority, Amman 91p
Al-Ajarmeh N, Khoury H (2018) Apatite-rich pyrometamorphic rocks from Suweileh area, Jordan. Arab J Geosci 11:520. https://doi.org/10.1007/s12517-018-3874-y
Alawi M, Najjar A, Khoury H (2013) Analytical method development for the screening and determination of dioxins in clay matrices. www. clean-journal.com. Clean Soil Air Water 41:1–7
Alawi M, Najjar A, Khoury H (2015) Levels of polychlorinated dibenzodioxins/dibenzofurans in Jordanian clay. Clean Soil Air Water 43(4):592–594. https://doi.org/10.1002/clen.201400240 41, 1-7
Aldabsheh I, Khoury H, Rahier H, Wastiel J (2015) Dissolution behavior of Jordanian clay-rich materials in alkaline solutions for alkali activation purpose. Part I’. Appl Clay Sci 115:238–247
Al-Homoud A, Khoury H, Al-Omari Y (1996) Mineralogical and engineering properties of problematic expansive clayey beds causing landslides. Bull Int Assoc Eng Geol 54:35–53 Paris
Al-Thawabeia R, Khoury H, Hodali H (2015) Synthesis of zeolite 4A via acid–base activation of metakaolinite and its use for water hardness treatment. Desalin Water Treat 56(40):947–952. https://doi.org/10.1080/19443994.2014.941413
Al-Zghoul K (1997) Genesis of palygorskite and the evolution of Esh-Shidyia basin, southern Jordan. Unpublished M.Sc. thesis, The University of Jordan. Amman.
Anon O (1958) Bleaching tests. A.O.C.S. official method Cc Ba 52, America Oil Chemistry society, 2p
Bain D (ed) (2009) Bentonite. Elements. An international magazine of Mineralogy, Geochemistry, and Petrology, Vol. 5 (2) 136p. ISSN 1811-5209
Baker H (1993) Adsorption properties of lead on some Jordanian clay deposits. Unpublished M. Sc. thesis, The University of Jordan, Amman, 164p.
Bayook A (1992) Batn El-Ghoul clay deposits as a potential source for aluminum Unpublished M.Sc. thesis The University of Jordan, Amman.
Brigatti et al. 2011, Brigatti M, Mottana A (eds) (2011) EMU Notes in Mineralogy. Mineral Soc Great Britain and Ireland, London 11:1–71. https://doi.org/10.1180/EMU-notes.11.1
Brigatti MF, Malferrari D, Laurora A, Elmi C (2011) Structure and mineralogy of layer silicates: recent perspectives and new trends. In: Layered mineral structures and their application in advanced technologies.
Brindley G, Brown G (1984) Crystal structures of clay minerals and their X-ray identification. Mineralogical Society, Great Britain
Brindley GW, Pedro G (1972) Report of the AIPEA Nomenclature Committee. AIPEA Newsl 7:8–13
Callen R (1984) Clays of the palygorskite sepiolite group: depositional environment, age and distribution. In: Singer A (ed) Development in sedimentology, 37, 1984, Pages 1-3.https://doi.org/10.1016/S0070-4571(08)70027-X
Castellini E, Bortolotti C, Bernini F, Ranieri A (2013) Enhancing biocatalysis: the case of cytochrome c unfolded immobilized on kaolinite. ChemCatChem 5:1765–1768
Davidovits J (1991) Geopolymers: inorganic polymeric new materials. J Therm Anal 37:1633–1656
Dwairi I, Sallam M (1994) Evaluation of bentonitic clay of Azraq for foundry sand uses. 1st Jordanian Mining Conference, Amman
El-Eswed B, Yousef R, Alshaaer M, Khalili F, Khoury H (2009) Alkali solid-state conversion of kaolin and zeolite to effective adsorbents for removal of lead from aqueous solution. Desalination Publications, European Desalination Society, Via Antica Arischia 8:1–7
Esaifan M, Rahier H, Barhoum A, Khoury H, Hourani M, Wastiels J (2015) Development of inorganic polymer by alkali-activation of untreated kaoliniticclay: reaction stoichiometry, strength and dimensional stability. Construction and Building Materials (JCBM), 91,. Elsevier, pp 251–259. https://doi.org/10.1016/j.conbuildmat.2015.04.034
Esaifan M, Khoury H, Aldabsheh I, Rahier H, Hourani M, Wastiels J (2016) Hydrated lime/potassium carbonate as alkaline activating mixture produce kaolinitic clay based inorganic polymer. Appl Clay Sci 126:278–286. https://doi.org/10.1016/j.clay.2016.03.026
Esaifan M, Hourani M, Khoury H, Rahier H, Wastiels J (2017) Synthesis of hydroxysodalite zeolite by alkali-activation of basalt powder rich in calc-plagioclase. Adv Powder Technol 28(2):473–480. https://doi.org/10.1016/j.apt.2016.11.002
Faraj B (1988 Palygorskite and its possible economic value in Azraq basin, Jordan. Unpublished Internal Report, Natural Resources Authority Amman, 13p.
Faraj B (1989) Clay minerals diagenesis and vitrinite reflectance analysis in HZ-4 well, Azraq basin, Unpublished M.Sc. thesis, The University of Jordan, Amman. Jordan, 179p.
Gougazeh M (1991) Geology, mineralogy, geochemistry and evaluation of kaolinite and silica sand of white sandstone in south Jordan for industrial applications. Unpublished M.Sc. thesis, Yarmouk University, Irbid.
Grathoff G, Khoury H (2010) A long-term natural analogue for radioactive waste repositories: mineralogy and chemistry of a volkonskoite (Cr-rich smectite) in travertine deposits from central Jordan. SEA- CSSG- CMS. Trilateral Meeting on clays, Madrid
Haddadin M (1974) Possibilities of bentonite in Jordan. Internal Report. Natural Resources Authority, Amman, 24p
Heivilin, F.G. & Murray, H.H. (1994) Clays. Hormites: palygorskite (attapulgite) and sepiolite. ln: Carr, D.D., ed., lndustrial Minerais and Rocks, 6th Ed., Littleton, CO, Society for Mining, Metallurgy, and Exploration, pp. 249-254
Ibrahim K, Abdel Hamid G (1990) Al-Yamaniyya clay deposits. Internal Report. Natural Resources Authority, Amman
Jasser D (1978) Investigation of Azraq clays. Internal Report. Natural Resources Authority, Amman 18p
Joudeh R (1991) Stabilization of silty clayey soil in Jordan. Unpublished M.Sc. thesis, The University of Jordan, Amman.
Kemp S (1995) Initial laboratory characterization of clay-bearing rocks from Jordan. British Geological Survey Technical. Technical Report No.WG/ 1379. International Geology Series BGS Technical Cooperation in Jordan, International Division.
Kendall T (1996) Industrial clays. M.J. O'Driscoll (Editor), Industrial Minerals, BPC Wheatons. Metal Bulletin; 2nd edition. ISBN-10: 190066304X.ISBN-13: 978-1900663045
Khoury H (1975) Microscopic examination of Mahis clay deposits. Dirasat 2:91–107
Khoury H (1980) Mineralogy and origin of Azraq clay deposits. Dirasat 7:21–31
Khoury H (1981) The kaolin deposits of Mahis area, Jordan. Dirasat 8:69–84
Khoury H (1986) Depositional environment and diagenesis of the lower part of the Kurnub Sandstone Formatio, Mahis area, Jordan. Sediment Geol 49:129–141
Khoury H (1987) Alunite from Jordan. N Jb Miner Mh 9:426–432 Stuttgart
Khoury H (2002) Clays and clay minerals in Jordan. Publications of the Deanship of Academic Research. The University of Jordan, Amman
Khoury H (2006) Industrial rocks and minerals in Jordan. Publications of Publications of the Deanship of Academic Research. The University of Jordan, Amman
Khoury H (2012) Long-term analogue of carbonation in travertine from Uleimat Quarries. Central Jordan Environ Earth Sci 65:1909–1916
Khoury H (2014). Geochemistry of surficial uranium deposits from central Jordan. The Jordan Journal of Earth and Environmental Sciences (JJEES). Volume 6, (Special Publication, Number 3), 11–22. ISSN 1995–6681
Khoury H (2015) Uranium minerals of Central Jordan (2015). Appl Earth Sci (Trans Inst Min Metall B) 124(2):104–128
Khoury H (2018) Economic potentials of industrial rocks and minerals in the Azraq basin, NE Jordan. Arab J Geosci 1:72. https://doi.org/10.1007/s12517-018-3423-8
Khoury H, Abu Jayyab A (1995) Research note on the mineral volkonskoite: four new localities in central Jordan. Dirasat 22(1):189–198
Khoury H, and Al-Zoubi A (2014) Origin and characteristics of Cr-smectite from Suweileh area, Jordan. Appl Clay Sci, 90: 43–52.
Khoury H, Eberl D (1979) Bubble-wall shards altered to montmorillonite. Clay Clay Miner 27:291–292
Khoury H, Eberl D (1981) Montmorillonite from the Amargosa Desert, southern Nevada, USA. N Jb Miner Abh 141:134–141
Khoury H, El-Sakka W (1986) Mineralogical and industrial characterization of Batn El-Ghoul clay deposits, southern Jordan. Appl Clay Sci 1:321–260
Khoury H, Ibrahim K (1986) Ghor-Kabid clay deposits of Jordan. Dirasat 8:249–260
Khoury H, Nassir S (1982a) A discussion on the origin of Daba–Siwaqa marble. Dirasat 9:55–56
Khoury H, Nassir S (1982b) High temperature mineralization in Maqarin area, Jordan. N Jb Miner Abh 144:187–213
Khoury H, Qa’adanM(2003) Diatomite and the diatomaceous earth. Publications of the Deanship of Academic Research. The University of Jordan, Amman 112p
Khoury H, Mackenzie R, Russel J, Tait J (1984) An iron free volkonskoite. Clay Miner 19:43–57
Khoury H, Hawari Z, El-Suradi S (1988) Clay minerals associated with Jordanian phosphates and their possible industrial utilization. Appl Clay Sci 3:111–121
Khoury H, Salameh E, Clark I (2014) Mineralogy and origin of surficial uranium deposits hosted in travertine and calcrete from central Jordan. Appl Geochem 43:49–65
Khoury H, Sokol E, Clark I (2015) Calcium uranium oxides from central Jordan: associations, chemistry, and alteration products. Can Mineral 53:61–82. https://doi.org/10.3749/canmin.1400071
Khoury H, Salameh E, Clark ID, Fritz R, Bajjali W, Miolodwski A, Cave M, Alexander W (1992) A ntural analog of high pH waters from the Maqarin area of northern Jordan 1: Introduction to the site. Journal of Geochemical Exploration 46:117–132
Machado G, Groszewicz P, Castro A, Wypych F, Wypych S (2012) Catalysts for heterogeneous oxidation reaction based on metalloporphyrins immobilized on kaolinite modified with triethanolamine. J Colloid Interface Sci 374:278–286
MacKenzie R (1970) Differential thermal analysis 1, vol 1970. Academic Press, London
Malak H (1995) Mineralogical and industrial characterization of Ein El-Baida clay deposits, Azraq basin. Unpublished M. Sc. thesis, The University of Jordan, Amman.
Millot G (1970) Geology of clays (trans. W. R. Farran and H. Paquent). Springer, Verlag
Mulla D, Low P, Roth C (1985) Measerment of the specific area of clays by internal reflectance. Clay Clay Miner 33(5):391–396
Nassir S, Khoury H (1982) Mineralogy, petrology, and origin of Daba-Siwaqa marble, Jordan. Dirasat 9:107–130
Nawar M, Shawabkeh K, Khoury H (1993) Effect of feeding farm animals with Jordanian clay deposits containing montmorillomite Zaqazig Jour. Agric Res 20(2A):651–667
Nickel E, Gartrell B (1993) Secondary Minerals of Ashburton Downs Western Australia. Mineral Rec 24(3):203–218
Odom I (1984) Smectitic clay minerals properties and uses. Philos Trans R Soc Lond A 311:39–409
Pettijohn F (1983) Sedimentary Rocks, 3rd edn. Harper Collins 526p
Powell J (1989) Stratigraphy and sedimentation of the Phanerozoic rocks in central and south Jordan. Part A: Ram and Khreim Group. Bull. 11A. Natural Resources Authority, Amman
Qa’adan M (1992) Mineralogy and origin of the recent deposits in the Azraq Depression . Unpublished M. Sc. thesis, The University of Jordan, Amman.
Rahier H, Slaty F, Aldabsheh I, Alshaaer M, Khoury H, Esaifan M, Wastiels J (2010) Use of local raw materials for construction purposes. Adv Sci Technol 69:152–155 Trans Tech Publications, Switzerland. https://doi.org/10.4028/www.scientific.net/AST.69.152
Rahier H, Esaifan M, Wastiels J, Slaty F, Aldabsheh I, Khoury H (2011) Alkali activation of kaolinite for production of bricks and tiles. Non-Tradit Cement Concr IV:162–170 eds. Vlastimil Bilek, Zbynek Kersner
Ranieri A, Bernini F, Bortolotti C, Castellini E (2012) The Met80Ala point mutation enhances the peroxidase activity of immobilized cytochrome c. Catal Sci Technol 2:2206–2210
Rettig S, Marinenko J, Khoury H, Jones B (1983) Comparison of rapid methods for chemical analysis of milligram samples of ultrafine clays. Clay Clay Miner 36:440–446
Rieder M, Cavazzini G, Yu D'y et al (1999) Nomenclature of the micas. Mineral Mag (1999) 63(2):267–279
Saleh S (2001) Determination of the pollution levels in the curing mud of the Dead Sea with heavy metals by ASS. Unpublished M.Sc. thesis, The University of Jordan, Amman.
Sallam M (1993) Industrial evaluation of clays in Jordan with special reference to bentonite for their uses in foundry sand and drilling mud. Unpublished M. Sc. thesis, University of Yarmouk, Irbid, 175p.
Segad M, Jönsson B, Akesson T, Cabane B (2010) Ca/Na Montmorillonite: Structure, Forces and Swelling Properties. Langmuir 26(8):5782–5790
Shadfan H, Dixon J (1984) Occurrence of palygorskite in the soil and rocks of the Jordan valley In development in sedimentology, Ed. A. Singer, 137, 187- 198.
Shamali, K (1966) Zur kenntis der Boden des Jordan grabens unter besonderer Berichtigung der Tonmineralien. Ph. D. thesis, Justus – Leibzig Universitat.
Sims C (1999) Prices and Data 1999. Pensord press, Gwent, 206 pp
Slaty F, Khoury H, Wastiels J, Rahier H (2013) Characterization of alkali activated kaolinitic clay. Appl Clay Sci 75–76:120–125
Slaty F, Khoury H, Wastiels J, Rahier H (2015) Durability of alkali activated cement produced from kaolinitic clay. Appl Clay Sci 104:229–237. https://doi.org/10.1016/j.clay.2014.11.037
Van Olphen H, Fripiat J (1979) Data Handbook for clay materials and other non – metallic minerals. Pergamon Press, Oxford, 346p
Vazquez-Duhalt R (1999) Cytochrome c as biocatalyst. J Mol Catal B Enzym 7:241–249
Wiersma J (1970) Provenance, genesis, and paleogeographical implications of microminerals occurring in sedimentary rocks of the Jordan valley area. Publicaties van Het fysisch – Geografisch en Bodem – Kundig Laboratorium van de universiteit van Amsterdam, nr. 15.
Yousef R, El-Eswed B, Alshaaer M, Khalili F, Khoury H (2009) The influence of using Jordanian zeolitic tuff on the adsorption, physical, and mechanical properties of geopolymers products. J Hazard Mater 165(1-3):15 379-387
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Thanks are given to Alexander von Humboldt Foundation, Germany (AvH), and The University of Jordan for their continuous support of the author’s research at the Department of Geology. The manuscript benefited much from the thoughtful review and valuable comments by anonymous reviewers, as well as the helpful suggestions of Emanuela Schingaro, Associate Editor of the Arabian Journal of Geosciences.
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Khoury, H.N. Review of clays and clay minerals in Jordan. Arab J Geosci 12, 706 (2019). https://doi.org/10.1007/s12517-019-4882-2
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DOI: https://doi.org/10.1007/s12517-019-4882-2