Abstract
The hematite mineralization under investigation is located 11 km NE of Sarical (Yavu) village of the Yildizeli town (Sivas Province) in central Turkey. The region is within the Central Anatolian Thrust Zone and is comprised of metamorphic units, ophiolitic rocks and overlying Tertiary volcanic and volcanosedimentary rocks in addition to Neogene terrestrial deposits. The mineralization occurs as lenticular or bedded bodies and is composed chiefly of hematite and a lesser amount of goethite. Quartz, calcite, and dolomite are the gangue minerals. Kaolinite and zeolite are the common alteration products. In this study, geochemical and mineralogical investigations were carried out using an X-ray diffractometer analysis (XRD), Raman spectroscopy, and scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDX). The V/(V + Ni) ratio increases in parallel to the detritic contribution, and when this ratio is less than 0.60, deposition conditions are said to be anoxic. Considering the V/(V + Ni) ratio and Ceanom values of the studied samples, we suggest that the environment is both oxic and anoxic in character. The overall assessment of the field observations, mineral paragenesis, major, trace, and rare earth element (REE) data indicates that the Sarical hematite mineralization is of a hydrothermal-sedimentary type.
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References
Adachi M, Yamamoto K, Sugisaki R (1986) Hydrothermal cherts and associated siliceous rocks from the northern Pacific: their geological significance as indication of ocean ridge activity. Sediment Geol 47:125–148
Alpaslan M (1993) Yildizeli yoresi (Sivas batisi) metamorfitlerinin petrolojik incelemesi. C. U Doktora tezi p 359 (unpublished; in Turkish).
Baykal F, Erentoz C (1966) 1:500.000 olcekli Turkiye Jeoloji Haritası (Sivas): MTA Yayini 116, Ankara-Turkiye (in Turkish)
Bhattacharya HN, Chakraborty I, Ghosh KK (2007) Geochemistry of some banded iron-formation of the Archean supra crustals, Jharkhand-Orissa region. J Earth Syst Sci 116(3):245–259
Bingol E (1989) 1:2.000.000 olcekli Turkiye Jeoloji Haritasi (Sivas): MTA Yayını, Ankara-Turkiye (unpublished; in Turkish)
Byrne RH, Sholkovitz ER (1996) Marine chemistry and geochemistry of the lanthanides. In: Gschneider Jr., K.A., Eyring, I., (eds.), Handbook on the physics and chemistry of rare earths. Elsevier 23:497–592
CerikciogIu B (1997) Yildizeli-Akdagmadeni arasindaki (Yavu cevresi) volkanik ve volkanosedimanter kayaclarin mineralojik -petrografik ve jeokimyasal incelemesi. C.U. Fen Bil. Enst. Yuksek Lisans Tezi p 121 (unpublished; in Turkish)
Chen D, Qing H, Yan X, Li H (2006) Hydrothermal venting and basin evolution (Devonian, South China): constraints from rare earth element geochemistry of chert. Sediment Geol 183:203–216
Choi JH, Hariya Y (1992) Geochemistry and depositional environment of Mn oxide deposits in the Tokora Belt, Northeastern Hokkaido, Japan. Econ Geol 87:12–24
Constantopoulos J (1988) Fluid inclusion and REE geochemistry of fluorite from south-central Idaho. Econ Geol 83:626–636
Crerar DA, Namson J, Chyi MS, Williams L, Feigenson MD (1982) Manganiferous cherts of the Franciscan assemblage: I. General geology, ancient and modern analoques and implications for hydrothermal convenction at oceanic spreading centers. Econ Geol 77:519–540
Delian F (1994) Geological and Geochemical Research of the Manganese ore Bed. Beijing: Weather Publishing Press
Ercanli E (1997) Yavu (Yildizeli-Sivas) yoresinde Orta Anadolu bindirme kusaginin tektonostratigrafisi ve deformasyon bicimi, C.U. Fen Bil. Enst. Yuksek Lisans Tezi, p 58 (unpublished; in Turkish)
Evensen MN, Hamilton P, O’Nions RK (1978) Rare-earth abundances in chondritic meteorites. Geochim Cosmochim Acta 42:1199–1212
Fernandez A, Moro MC (1998) Origin and depositional environment of Ordovician stratiform iron mineralization from Zamora (NW Iberian Peninsula). Mineralium Deposita 33:606
Fleet AJ, Henderson P, Kempe DRC (1976) Rare earth element and related chemistry of some drilled southern indean ocean basalts and volcanogenic sediments. Journal of Geophysical Research 81: doi:10.1029/JB08li023p04257. ISNN: 0148–0227
Fitzgerald CE, Gillis KM (2006) Hydrothermal manganese oxide deposits from Baby Bare seamount in the Northeast Pacific Ocean. Mar Geol 225:145–156
Ghaderi M, Palin M, Sylvester P, Campbell I (2006) Composition and source of hydrothermal fluids in gold deposits of the Kalgoorlie-Norseman region of Western Australia inferred from rare earth element systematics in scheelite. Research School of Earth Sciences, The Australian National University, Canberra, ACT 0200, Australia
Gokten E (1993) Yildizeli (Sivas) guneyinde Akdag metamorfitleri ve ortu kayalarinin stratigrafisi ve tektonigi. TKJ Bul 36:83–93(in Turkish)
Hein JR, Schulz MS, Kang JK (1990) Insular and submarine ferromanganese mineralization of the Tonga-Lau region. Mar Min 9:305–354
Hein JR, Marjorie SS, Gein LM (1992) Central Pacific cobalt rich ferromanganese crusts. Historical perspective and regional variability. In: Keating BH, Balton BR (eds) Geology and offshore mineral resources of the central Pacific basin, circum-Pacific council for energy and mineral resources. Earth science series, New York Springer, p. 14
Hein JR, Kochinsky A, Halbach P, Manheim FT, Bau M, Kang JK, Lubick N (1997) Iron and manganese oxide mineralization in the Pacific. In: Nicholson, K., Hein, J.R., Buhn, B., Dasgupta, S. (Eds.), Manganese mineralization: geochemistry and mineralogy of Terrestrial and Marine deposits, Geological Society of London Special Publication 119: 123–138
Henderson P (1984) Rare earth element geochemistry. Devolopments in Geochemistry. Elsevier, Amsterdam, pp. 317–347
Hu X, Wang YL, Schmitt RA (1988) Geochemistry of sediments on the Rio Grande Rise and the redox evolution of the South Atlantic Ocean. Gechimica et Cosmochimica Acta 52:201–207
Jiancheng X, Xiaoyong Y, Jianguo D (2006) Geochemical characteristics of sedimentary manganese deposit of Guichi, Anhui Province. China J Rare Earths 24:374–380
Jiang NY, Jia RF, Wang ZY, Qi D, Yu Z, He Y (1994) Permian palaeogeography and geochemical environment in Lower Yangtze Region, China. Petroleum Industry Press, Beijing, p. 206
Jiang SY, Palmer MR, Yeats CJ (2002) Chemical and boron isotopic compositions of tourmaline from the Archean Big Bell and Mount Gibson gold deposits, Murchison Province, Yilgarn Craton, Western Australia. Chem Geol 188:229–247
Kalkan E, (1997) Sivas Tersiyer Havzasinin Kuzey Kenarinin Circir-Hamzaseyh Koyleri (Sivas KB) Arasindaki Kesiminin Jeolojik Ozellikleri. C.U. Fen Bil. Enst. Yuksek Lisans Tezi, 87 sayfa (unpublished; in Turkish)
Karakus A, Yavuz B, Koc S (2010) Mineralogy and major-trace element geochemistry of the Haymana manganese mineralizations, Ankara, Turkey. Geochem Int 48(10):1014–1027
Khan RMK, Naqvi SM (1996) Geology, geochemistry and genesis of BIF of Kushtagi schist belt, Archean Dharwar Craton, India. Mineral Deposita 31:123–133
Kocbulut F (1998) Orta Anadolu Bindirme Kusaginin Alicik-Kızıllı (Akdagmadeni-Yildizeli) Yoresindeki Jeolojik Ozellikleri. 1998, Yuksek Lisans Tezi, C.U. Fen Bil. Enst. (unpublished; in Turkish)
Kurtman F (1973) Sivas-Hafik-Zara ve Imranlı Bolgesinin jeolojik ve tektonik yapısı. MTA Dergisi 80:1–33(in Turkish)
Kuscu I, Yılmazer E, Demirela G (2002) A new Fe-oxide-Cu-Au (Olympic Dam Type) perspective to skarn type iron oxide mineralization in Sivas-Divrigi region. Geol Bull Turkey 45(2):33–47
Marynowski L, Zatoń M, Rakociński M, Filipiak P, Kurkiewicz S, Pearce TJ (2012) Deciphering the upper Famennian Hangenberg Black Shale depositional environments based on multi-proxy record. Palaeogeogr. Palaeoclimatol Palaeoecol 347:66–86
Mishra PP, Mohapatra BK, Singh PP (2007) Constrasting REE signatures on manganese ores of iron ore group in north Orissa, India. J Rare Earths 25:749–758
Mohapatra BK, Mishra PP, Singh PP, Rajeev (2009) Manganese ore deposits in Koira-Noamundi province of iron ore group, north Orissa, India: in the light of geochemical signature. Chemie Der Erde Geochem 69:377–394
Monnin C, Wheat CG, Dupre B, Elderfield H, Mottl MJ (2001) Barium geochemistry in sediment pore waters and formation waters of the oceanic crust on the eastern flank of the Juan de Fuca Ridge (ODP Leg 168). Geochem Geophys Geosyst 2:1–19
Nicholson K (1992) Genetic types of manganese oxide deposits in Scotland: indicators of paleo-ocean spreading rate and a Devonian geochemical mobility boundary. Econ Geol 87:1301–1309
Oksuz N (2011a) Geochemical characteristics of the Eymir (Sorgun-Yozgat) manganese deposit. J Rare Earths 29:287–295
Oksuz N (2011b) Geochemistry and the origin of manganese mineralizations in Derbent (Yozgat) region. Bull Earth Sci Appl Res Cent Hacettepe Univ 32(3):213–234(in Turkish)
Owen AW, Armstrong HA, Floyd JD (1999) Rare earth elements in chert clasts as provenance indicators in the Ordovician and Silurian of the Southern Uplands of Scotland. Sediment Geol 124:185–195
Ozcan A, Erkan A, Keskin E, Oral A, Ozer S, Sumengen M, Tekeli O (1980) Kuzey Anadolu Fayı-Kırsehir Masifi arasının temel jeolojisi. Ankara, MTA Rapor no: 6722 (unpublished; in Turkish)
Peng QM, Palmer MR (2002) The Paleoproterozoic Mg and Mg-Fe borate deposits of Liaoning and Jilin Provinces, northeast China. Econ Geol 97:93–108
Pettijohn FG (1975) Sedimentary rocks, 3rd edn. Harper&Row, New York, p 628
Poisson A (1986) Anatolian micro-continents in the Eastern Mediterranean context: the neo-Tehysian oceanic troughs. Sci. De la Terre Mem 47:311–328
Ruhlin DE, Owen RM (1986) The rare earth element geochemistry of hydrothermal sediments from the East Pacific Rise: examination of a seawater scavenging mechanism. Gechimica et Cosmochimica Acta 50:393–400
Sabatino N, Neri R, Bellanca A, Jenkyns HC, Masetti D, Scopelliti G (2011) Petrography and high-resolution geochemical records of Lower Jurassic manganese-rich deposits from Monte Mangart, Julian Alps. Palaeogeogr. Paleoclimatol. Palaeoecol. 299:97–109
Salem IA, Ibrahim ME, Monsef MAE (2012) Mineralogy, geochemistry, and origin of hydrothermal manganese veins at Wadi Malik. Southern Eastern Desert, Egypt Arabian Journal of Geosciences 5:385–406
Sasmaz A, Turkyilmaz B, Ozturk N, Yavuz F, Kumral M (2014) Geologyandgeochemistryof MiddleEocene maden complex ferromanganese deposits from Elazig-Malatya region. Eastern, Turkey Ore Geology Reviews 56:352–372
Shah MT, Khan A (1999) Geochemistry and origin of Mn-deposits in Waziristan ophiolite complex, North Waziristan, Pakistan. Mineral Deposita 34:697–704
Shields GA, Webb GE (2004) Has the REE composition of seawater changed over geological time? Chem Geol 204:103–107
Singh P, Rajamani V (2001) REE geochemistry of recent clastic sediments from the Kaveri floodplains, southern India: Implications to source weathering and sedimentary processes.Geochimica et Cosmochimica Acta 65(18):3093–3108
Spier CA, Oliveira SMB, Sial AN, Rios FJ (2007) Geochemistry and genesis of the banded iron formations of the Caue Formation. Quadrilatero Ferrifero, Minas Gerais, Brazil. Precambrian Res 152:170–206
Tatar Y (1982) Yildizeli (Sivas) kuzeyindeki Camlıbel daglarının tektonik yapısı. KTU. Yerbilimleri Dergisi 88:56–73(in Turkish)
Tatar O, Temiz H, Gursoy H, Guezou JC (2004) Orta ve Kuzey Anadolu Miyosen-Kuvaterner Volkanizması isiginda Avrasya-Anadolu Levhalarının Carpısması. Tubitak YDABCAG 198Y092 nolu Proje, 55 sayfa, Ankara
Toth JR (1980) Deposition of submarine crusts rich in manganese and iron. Geol Soc Am Bull 91:44–54
Unlu T, Stendal H (1986) Geochemistryand element correlation of iron deposits in theDivrigi region, Central Anatolia, Turkey. Geol Eng 28:5–19
Unlu T, Stendal H (1991) Rock geochemistry of an iron ore field in theDivrigi region, Central Anatolia Turkey. A new exploration model for iron ores in Turkey. J Geochem Exploration 40(1–3):281–290
Unlu T, Stendal H, Makovicy E, Sayili S (1995) Genesis of the Divrigi iron ore deposit, Sivas, Central Anatolia. Turkey-An Ore Microscopy Study Mineral Res Expl Bull 117:17–28
Usui A, Someya M (1997) Distribution and composition of marine hydrogenetic and hydrothermal manganese deposits in the Northwest Pacific. In: Nicholson, K., Hein, J.R., Buhn, B., Dasgupta, S. (Eds.), Manganese mineralization: geochemistry and mineralogy of terrestrial and marine deposits, Geological Society of London Special Publication119: 177–198
Von Stackelberg (1997) Growth history of manganese nodules and crusts of the Peru Basin. Geological Society, Special Publications, London 119:153
Xu Bao S, Yang Zhou H, Tong Peng X, Wu Ji F, Qiang Yao H (2008) Geochemistry of REE and ytrrium in hyrothermal fluids from the Endeavour segment, Juan de Fuca Ridge. Geochem J 42:359–370
Yalcin H, Bozkaya O (2003) Sivas Batısındaki (Yildizeli-Akdagmadeni) Hidrotermal Kaolin ve I-S Olusumlarının Mineralojisi ve Jeokimyası. Turkiye Jeoloji Bulteni 46(2):1–23(in Turkish)
Yilmaz A, Uysal S, Bedi Y, Esref A, Yusufoglu H, Havzoglu T, Aydın N (1997) 1:100 000 olcekli acınsama nitelikli Turkiye Jeoloji Haritaları No. 46 Sivas-F22 Paftası MTA Jeoloji Etudleri Dairesi, Ankara, 14 S Geological Bulletin of Turkey 46(2) August 2003 (in Turkish)
Yilmaz A, Ozer S (1984) Kuzey Anadolu bindirme Kusagi’nin Akdagmadeni (Yozgat) ile Karacayir (Sivas) arasındaki bolumunun temel jeoloji incelemesi ve tersiyer havzasının yapısal evrimi. Ketin Sempozyumu:163–174(in Turkish)
Zarasvandi A, Lentz D, Rezai M, Pourkaseb H (2013) Genesis of the Nasirabad manganese occurrence, Fars province, Iran: geochemical evidences. Chem Erde 73:495–508
Acknowledgments
This study was supported by Bozok University (grant no. MMF/A80). The authors are thankful to Prof. Yusuf K. Kadıoglu and Cumhur O. Kılıc, Ankara University Geological Engineering Department, for the Raman spectroscopy analysis. This revised version has greatly benefited from insightful, constructive comments from Prof. Dr. Abdullah M. Al-Amri and other kind, anonymous reviewers.
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Oksuz, N., Kocak, I. Geochemical evidence for the genesis of the Sarical-Yavu hematite mineralizations (Sivas, Central Turkey). Arab J Geosci 9, 479 (2016). https://doi.org/10.1007/s12517-016-2432-8
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DOI: https://doi.org/10.1007/s12517-016-2432-8