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Ionogel-Based Ionic Liquid Coating for Solid-Phase Microextraction of Organophosphorus Pesticides from Wine and Juice Samples

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Abstract

In this work, a novel fiber coating was prepared by using a hybrid material of silica-based ionogels and ionic liquid 1-hexadecyl-3-methylimidazolium bis(trifuluoromethylsulfonyl)imide ([C16MIM][NTf2]). Instead of chemical bonding to sol-gel matrix, high loadings of [C16MIM][NTf2] was confined into the network of silica-based ionogels and thus, the extraction efficiency was significantly improved. The prepared fiber was used for solid-phase microextraction (SPME) of four organophosphorus pesticides (OPPs) from wine and juice samples prior to gas chromatography coupled with flame photometric detection. Under the optimized conditions, the proposed method results in good linearity (R 2 > 0.9991), with low method detection limits (MDLs, S/N = 3) and method quantification limits (MQLs, S/N = 10) in the range of 0.57–4.13 and 1.89–13.76 ng L−1, respectively. The precisions of the method were assessed with repeatability and reproducibility of RSD% ˂28 and ˂23%, respectively. The spiked recoveries of OPPs from wine and juice samples were in the range of 54 ± 5–118 ± 20 and 56 ± 14–109±12%, at two different concentration levels. The expanded uncertainties at 1 μg L−1 were below 20% for target OPPs in all selected samples.

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Authors and Affiliations

  1. Department of Material and Chemical Engineering, Collaborative Innovation Center of Environmental Pollution Control and Ecological Restoration, Zhengzhou University of Light Industry, Zhengzhou, 450001, Hennan, People’s Republic of China

    Long Pang, Peijie Yang, Xiaoling Lu, Jingwen Xiao, Hongzhong Zhang & Jihong Zhao

  2. Department of Medicine, Huanghe Science and Technology College, Zhengzhou, 450063, Henan, People’s Republic of China

    Rong Pang

  3. College of Chemical Engineering, Zhengzhou University, Zhengzhou, 450001, Henan, People’s Republic of China

    Shunyi Li

Authors
  1. Long Pang
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  2. Peijie Yang
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  3. Rong Pang
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  4. Xiaoling Lu
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  5. Jingwen Xiao
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  6. Shunyi Li
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  7. Hongzhong Zhang
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  8. Jihong Zhao
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Corresponding authors

Correspondence to Long Pang or Shunyi Li.

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Funding

This study was supported by the Open foundation Major Science and Technology Program for Water Pollution Control and Treatment (2015ZX07204002003) and the Collaborative Innovation Center of Environmental Pollution Control and Ecological Restoration, Henan Province (XTCX010).

Conflict of Interest

Long Pang declares that he has no conflict of interest. Peijie Yang declares that he has no conflict of interest. Rong Pang declares that he has no conflict of interest. Xiaoling Lu declares that he has no conflict of interest. Jingwen Xiao declares that he has no conflict of interest. Shunyi Li declares that he has no conflict of interest. Hongzhong Zhang declares that he has no conflict of interest. Jihong Zhao declares that he has no conflict of interest.

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This article does not contain any studies with human participants performed by any of the authors.

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Pang, L., Yang, P., Pang, R. et al. Ionogel-Based Ionic Liquid Coating for Solid-Phase Microextraction of Organophosphorus Pesticides from Wine and Juice Samples. Food Anal. Methods 11, 270–281 (2018). https://doi.org/10.1007/s12161-017-0997-9

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  • DOI: https://doi.org/10.1007/s12161-017-0997-9

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