Abstract
The magnetic properties of Cu2+, Cr3+, and Mn2+ ions in the newly reported 12- and 15-membered macrocyclic complexes are analysed by a theoretical approach. The calculated magnetic moment and magnetic anisotropy for various situations, especially for Cu(II) ion, suggest that the magnetic properties may lead to a better interpretation about the geometry. It is also suggested that the zero-field splitting Hamiltonian may be used for magnetic properties of some metal ions, which have orbital singlet ground term in these complexes.
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Bayri, A., Karakaplan, M. Theoretical approach to the magnetic properties of Mn(II), Cr(III), and Cu(II) complexes in the newly reported 12- and 15-membered macrocyclic ligands. Pramana - J Phys 69, 301–306 (2007). https://doi.org/10.1007/s12043-007-0130-5
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DOI: https://doi.org/10.1007/s12043-007-0130-5
Keywords
- Magnetization
- magnetic susceptibility
- spin-orbit coupling
- zero-field splitting
- macrocyclic complexes
- covalancy factor