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Hydrothermal synthesis and electrochemical properties of a coordination polymer based on dinuclear (Pyrazinyl tetrazolate) Copper(II) cations and β-Octamolybdate Anions

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Abstract

A hybrid compound (H2bbi)[Cu2(pzta)2(H2O)2][ β-Mo8O26] (1) (pztaH = 5-(2-pyrazinyl) tetrazolate, bbi = 1,1’-(1,4-butanediyl)bis(imidazole), has been hydrothermally synthesized and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. In 1, the β-Mo8 clusters link dinuclear copper (II) complexes as bidentate connectors to form inorganic-organic chains. These chains and the [H2bbi]2+ counter-cations are fused together forming layers via hydrogen bonding interactions. The electrochemical properties of 1 were studied. The results indicate that 1 has an electrocatalytic activity towards the reduction of iodate ascribed to the Mo-centers.

A new hybrid compound based on dinuclear copper complex has been synthesized, and its electrochemical properties were studied, which indicate that it has a good electrocatalytic activity toward reduction of iodate.

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Acknowledgements

This work was financially supported by the NSF of China (21371041, 51572063), innovative research team of green chemical technology in university of Heilongjiang Province, China (2014TD007), and the science and technology innovation foundation of Harbin (2014RFXXJ076).

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Authors and Affiliations

  1. Key Laboratory of Green Chemical Engineering and Technology, College of Heilongjiang Province, College of Chemical and Environmental Engineering, Harbin, University of Science and Technology, Harbin, 150040, China

    SHAOBIN LI, LI ZHANG, HUIYUAN MA & HAIJUN PANG

  2. College of Materials Science and Engineering, Qiqihar University, Qiqihar, 161006, China

    SHAOBIN LI

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  1. SHAOBIN LI
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  2. LI ZHANG
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  3. HUIYUAN MA
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  4. HAIJUN PANG
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Correspondence to HUIYUAN MA or HAIJUN PANG.

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Supplementary Information (SI)

CIF file containing complete information on the structure was deposited with CCDC deposition number 992478, which is available free upon request from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif. The table of selected bond lengths and angles and the IR spectrum of compound 1 are given in supplementary information available at www.ias.ac.in/chemsci.

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LI, S., ZHANG, L., MA, H. et al. Hydrothermal synthesis and electrochemical properties of a coordination polymer based on dinuclear (Pyrazinyl tetrazolate) Copper(II) cations and β-Octamolybdate Anions. J Chem Sci 128, 825–830 (2016). https://doi.org/10.1007/s12039-016-1076-2

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  • DOI: https://doi.org/10.1007/s12039-016-1076-2

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