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Three 2 D copper(II)/cadmium(II) coordination polymers based on semi-rigid/flexible bis-pyridyl-bis-amide ligands and 5-aminoisophthalate: Syntheses, structures and properties

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Abstract

Three new transition metal coordination polymers [Cu(3-bpcb)0.5(5-AIP)] ⋅2H2O (1), [Cd(3-bpc b)0.5(5-AIP)(H2O)] ⋅H 2O (2) and [Cd(3-bpsa)0.5(5-AIP)(H2O)] ⋅2H2O (3) have been hydrothermally synthesized by self-assembly of 5-aminoisophthalic acid (5-H2AIP), semi-rigid or flexible bis-pyridyl-bis-amide ligands [3-bpcb = N N ′-bis(3-pyridinecarboxamide)-1,4-benzene, 3-bpsa = N,N ′-bis(3-pyridyl)succinamide], and copper chloride or cadmium nitrate. X-ray diffraction analysis reveals that compounds 1 and 2 possess similar 2 D double-layered structures with (3,4)-connected (63)(65⋅8) topology, while compound 3 displays a 2 D layer with {62.10}{6} topology. The adjacent layers of 1–3 are finally extended into 3 D supramolecular frameworks by hydrogen bonding interactions. The bis-pyridyl-bis-amide ligands with different flexibilities play an important role in the construction of final topological structures for the title compounds. Further, the electrochemical behavior of the compound 1 and the fluorescent and photocatalytic properties of compounds 1–3 have been investigated.

Three new copper(II)/cadmium(II) coordination polymers have been hydrothermally synthesized by self-assembly of 5-H2AIP, semi-rigid or flexible bis-pyridyl-bis-amide ligands and copper chloride or cadmium nitrate. The electrochemical behavior, the fluorescent and photocatalytic properties of the compounds have been investigated.

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Acknowledgements

The supports of the National Natural Science Foundation of China (No. 21471021), New Century Excellent Talents in University (NCET-09-0853), and Program of Innovative Research Team in University of Liaoning Province (LT2012020) are gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Bohai University, Jinzhou, 121000, P. R. China

    HONGYAN LIN, MAO LE, JIAN LUAN, XIULI WANG & GUOCHENG LIU

  2. Department of Applied Chemistry, China Agricultural University, Beijing, 100193, P. R. China

    HUIZHE LU

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  1. HONGYAN LIN
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  2. HUIZHE LU
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  3. MAO LE
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Corresponding author

Correspondence to XIULI WANG.

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Supplementary Information

Crystallographic data for the structures reported in the paper have been deposited in the Cambridge Crystallographic Data Center with CCDC reference numbers CCDC 949958 for 1, 949959 for 2 and 1024049 for 3. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif. The tables of selected bond lengths and angles, the related hydrogen bonding geometries of compounds 1–3, as well as additional figures are available at www.ias.ac.in/chemsci.

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LIN, H., LU, H., LE, M. et al. Three 2 D copper(II)/cadmium(II) coordination polymers based on semi-rigid/flexible bis-pyridyl-bis-amide ligands and 5-aminoisophthalate: Syntheses, structures and properties. J Chem Sci 127, 1275–1285 (2015). https://doi.org/10.1007/s12039-015-0882-2

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